Stimuli-Responsive Designer Supramolecular Polymer Gel
This paper reports a stimuli-responsive designer supramolecular polymer gel in dimethylsulphoxide (DMSO)/water (1:2) based on a dipeptide amphiphile and β-cyclodextrin (β-CD) The dipeptide amphiphile contains caproic acid at the N terminus and methyl ester at the C terminus. From X-ray single crysta...
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Published in | Chemistry an international journal Vol. 5; no. 1; pp. 691 - 702 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
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Abstract | This paper reports a stimuli-responsive designer supramolecular polymer gel in dimethylsulphoxide (DMSO)/water (1:2) based on a dipeptide amphiphile and β-cyclodextrin (β-CD) The dipeptide amphiphile contains caproic acid at the N terminus and methyl ester at the C terminus. From X-ray single crystal diffraction, the amphiphile adopts a kink-like conformation. The amphiphile self-assembled to form a parallel sheet-like structure stabilized by multiple intermolecular hydrogen bonds. Moreover, the parallel sheet-like structure is also stabilized by edge-to-edge π–π stacking interactions. In higher-order packing, it forms a corrugated sheet-like structure stabilized by hydrophobic interactions. The dipeptide amphiphile interacts with β-cyclodextrin and forms gel through supramolecular polymer formation in (DMSO)/water (1:2) by a simple heating-cooling cycle. The sol-to-gel transformation is because of a host–guest complex between compound 1 and β-CD and the formation of supramolecular polymer accompanied by microstructure changes from nanofibers to microrods. The gel is temperature responsive with a Tgel of 70 °C. The supramolecular polymer gel is also responsive to stimuli such aspicric acid and HCl. The extensive spectroscopic studies show that the aromatic hydrophobic side chain of compound 1 forms a host–guest complex with β-CD. These results will be helpful for the design of advanced programable eco-friendly functional materials. |
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AbstractList | This paper reports a stimuli-responsive designer supramolecular polymer gel in dimethylsulphoxide (DMSO)/water (1:2) based on a dipeptide amphiphile and β-cyclodextrin (β-CD) The dipeptide amphiphile contains caproic acid at the N terminus and methyl ester at the C terminus. From X-ray single crystal diffraction, the amphiphile adopts a kink-like conformation. The amphiphile self-assembled to form a parallel sheet-like structure stabilized by multiple intermolecular hydrogen bonds. Moreover, the parallel sheet-like structure is also stabilized by edge-to-edge π–π stacking interactions. In higher-order packing, it forms a corrugated sheet-like structure stabilized by hydrophobic interactions. The dipeptide amphiphile interacts with β-cyclodextrin and forms gel through supramolecular polymer formation in (DMSO)/water (1:2) by a simple heating-cooling cycle. The sol-to-gel transformation is because of a host–guest complex between compound 1 and β-CD and the formation of supramolecular polymer accompanied by microstructure changes from nanofibers to microrods. The gel is temperature responsive with a Tgel of 70 °C. The supramolecular polymer gel is also responsive to stimuli such aspicric acid and HCl. The extensive spectroscopic studies show that the aromatic hydrophobic side chain of compound 1 forms a host–guest complex with β-CD. These results will be helpful for the design of advanced programable eco-friendly functional materials. |
Author | Singh, Surajit Roy Chowdhury, Srayoshi Haldar, Debasish Ibukun, Olamilekan Joseph Douzapau, M. |
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SubjectTerms | Corrugated sheet crystal structure Cyclodextrins Functional materials gel Hexanoic acid host–guest complex Hydrogen bonds Hydrophobicity Ions Nanofibers Polymer gels Polymers programmable Rheology Scanning electron microscopy Scientific imaging Self-assembly Single crystals Sol-gel processes Stimuli stimulus-responsive supramolecular Supramolecular compounds Supramolecular polymers |
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