Pressure effect on the order–disorder transformation in L10 FeNi
The ordered phase of the FeNi system is known for its promising magnetic properties that make it a first-class rare-earth free permanent magnet. Mapping out the parameter space controlling the order–disorder transformation is an important step towards finding growth conditions that stabilize the L 1...
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| Published in | Scientific reports Vol. 10; no. 1; p. 14766 |
|---|---|
| Main Authors | , , |
| Format | Journal Article |
| Language | English |
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Nature Publishing Group UK
08.09.2020
Nature Publishing Group |
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| Abstract | The ordered phase of the FeNi system is known for its promising magnetic properties that make it a first-class rare-earth free permanent magnet. Mapping out the parameter space controlling the order–disorder transformation is an important step towards finding growth conditions that stabilize the
L
1
0
phase of FeNi. In this work, we study the magnetic properties and chemical order-disorder transformation in FeNi as a function of lattice expansion by utilizing
ab initio
alloy theory. The largest volume expansion considered here is 29% which corresponds to a pressure of
-
25
GPa. The thermodynamic and magnetic calculations are formulated in terms of a long-range order parameter, which is subsequently used to find the ordering temperature as a function of pressure. We show that negative pressure promotes ordering, meaning that synthetic routes involving an increase of the volume of FeNi are expected to expand the stability field of the
L
1
0
phase. |
|---|---|
| AbstractList | The ordered phase of the FeNi system is known for its promising magnetic properties that make it a first-class rare-earth free permanent magnet. Mapping out the parameter space controlling the order–disorder transformation is an important step towards finding growth conditions that stabilize the L10 phase of FeNi. In this work, we study the magnetic properties and chemical order-disorder transformation in FeNi as a function of lattice expansion by utilizing ab initio alloy theory. The largest volume expansion considered here is 29% which corresponds to a pressure of -25 GPa. The thermodynamic and magnetic calculations are formulated in terms of a long-range order parameter, which is subsequently used to find the ordering temperature as a function of pressure. We show that negative pressure promotes ordering, meaning that synthetic routes involving an increase of the volume of FeNi are expected to expand the stability field of the L10 phase. The ordered phase of the FeNi system is known for its promising magnetic properties that make it a first-class rare-earth free permanent magnet. Mapping out the parameter space controlling the order-disorder transformation is an important step towards finding growth conditions that stabilize the [Formula: see text] phase of FeNi. In this work, we study the magnetic properties and chemical order-disorder transformation in FeNi as a function of lattice expansion by utilizing ab initio alloy theory. The largest volume expansion considered here is 29% which corresponds to a pressure of [Formula: see text] GPa. The thermodynamic and magnetic calculations are formulated in terms of a long-range order parameter, which is subsequently used to find the ordering temperature as a function of pressure. We show that negative pressure promotes ordering, meaning that synthetic routes involving an increase of the volume of FeNi are expected to expand the stability field of the [Formula: see text] phase.The ordered phase of the FeNi system is known for its promising magnetic properties that make it a first-class rare-earth free permanent magnet. Mapping out the parameter space controlling the order-disorder transformation is an important step towards finding growth conditions that stabilize the [Formula: see text] phase of FeNi. In this work, we study the magnetic properties and chemical order-disorder transformation in FeNi as a function of lattice expansion by utilizing ab initio alloy theory. The largest volume expansion considered here is 29% which corresponds to a pressure of [Formula: see text] GPa. The thermodynamic and magnetic calculations are formulated in terms of a long-range order parameter, which is subsequently used to find the ordering temperature as a function of pressure. We show that negative pressure promotes ordering, meaning that synthetic routes involving an increase of the volume of FeNi are expected to expand the stability field of the [Formula: see text] phase. The ordered phase of the FeNi system is known for its promising magnetic properties that make it a first-class rare-earth free permanent magnet. Mapping out the parameter space controlling the order–disorder transformation is an important step towards finding growth conditions that stabilize the \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$L1_0$$\end{document} L 1 0 phase of FeNi. In this work, we study the magnetic properties and chemical order-disorder transformation in FeNi as a function of lattice expansion by utilizing ab initio alloy theory. The largest volume expansion considered here is 29% which corresponds to a pressure of \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$${-25}$$\end{document} - 25 GPa. The thermodynamic and magnetic calculations are formulated in terms of a long-range order parameter, which is subsequently used to find the ordering temperature as a function of pressure. We show that negative pressure promotes ordering, meaning that synthetic routes involving an increase of the volume of FeNi are expected to expand the stability field of the \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$L1_0$$\end{document} L 1 0 phase. The ordered phase of the FeNi system is known for its promising magnetic properties that make it a first-class rare-earth free permanent magnet. Mapping out the parameter space controlling the order–disorder transformation is an important step towards finding growth conditions that stabilize the $$L1_0$$ L 1 0 phase of FeNi. In this work, we study the magnetic properties and chemical order-disorder transformation in FeNi as a function of lattice expansion by utilizing ab initio alloy theory. The largest volume expansion considered here is 29% which corresponds to a pressure of $${-25}$$ - 25 GPa. The thermodynamic and magnetic calculations are formulated in terms of a long-range order parameter, which is subsequently used to find the ordering temperature as a function of pressure. We show that negative pressure promotes ordering, meaning that synthetic routes involving an increase of the volume of FeNi are expected to expand the stability field of the $$L1_0$$ L 1 0 phase. The ordered phase of the FeNi system is known for its promising magnetic properties that make it a first-class rare-earth free permanent magnet. Mapping out the parameter space controlling the order–disorder transformation is an important step towards finding growth conditions that stabilize the L 1 0 phase of FeNi. In this work, we study the magnetic properties and chemical order-disorder transformation in FeNi as a function of lattice expansion by utilizing ab initio alloy theory. The largest volume expansion considered here is 29% which corresponds to a pressure of - 25 GPa. The thermodynamic and magnetic calculations are formulated in terms of a long-range order parameter, which is subsequently used to find the ordering temperature as a function of pressure. We show that negative pressure promotes ordering, meaning that synthetic routes involving an increase of the volume of FeNi are expected to expand the stability field of the L 1 0 phase. |
| ArticleNumber | 14766 |
| Author | Tian, Li-Yun Vitos, Levente Eriksson, Olle |
| Author_xml | – sequence: 1 givenname: Li-Yun surname: Tian fullname: Tian, Li-Yun email: liyunt@kth.se organization: Applied Materials Physics, Department of Materials Science and Engineering, Royal Institute of Technology, Division of Materials Theory, Department of Physics and Astronomy, Uppsala University – sequence: 2 givenname: Olle surname: Eriksson fullname: Eriksson, Olle organization: Division of Materials Theory, Department of Physics and Astronomy, Uppsala University, School of Science and Engineering, Örebro University – sequence: 3 givenname: Levente surname: Vitos fullname: Vitos, Levente organization: Applied Materials Physics, Department of Materials Science and Engineering, Royal Institute of Technology, Division of Materials Theory, Department of Physics and Astronomy, Uppsala University, Research Institute for Solid State Physics and Optics, Wigner Research Center for Physics |
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| Cites_doi | 10.1109/LMAG.2014.2312178 10.1007/BF01293604 10.1016/j.matdes.2016.04.053 10.1103/PhysRevB.90.014402 10.1088/0953-8984/26/6/064213 10.1088/1361-6463/aa5629 10.1109/TMAG.2013.2248139 10.1016/S0927-0256(99)00098-1 10.1103/PhysRevB.71.054402 10.1088/0031-8949/23/3/015 10.1088/0953-8984/20/31/315203 10.1088/0953-8984/26/6/064207 10.1088/0022-3727/47/42/425001 10.1038/s41598-019-44506-7 10.1080/09500839.2014.955546 10.1103/PhysRevB.82.144304 10.1073/pnas.30.9.244 10.1016/j.actamat.2018.07.049 10.1103/PhysRev.156.809 10.1038/s41598-017-13562-2 10.1016/j.jmmm.2014.01.042 10.1016/j.actamat.2016.06.050 10.1016/j.jmmm.2006.10.799 10.1103/PhysRev.71.809 10.1103/PhysRevLett.87.156401 10.1103/PhysRevB.5.2382 |
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| References | Vitos (CR24) 2007 Kojima (CR7) 2014; 47 Wang, Ma, Woo (CR16) 2010; 82 Skomski (CR2) 2013; 49 Albertsen (CR17) 1981; 23 Soven (CR26) 1967; 156 Shima, Okamura, Mitani, Takanashi (CR9) 2007; 310 Edström, Chico, Jakobsson, Bergman, Rusz (CR21) 2014; 90 Frisk, Hase, Svedlindh, Johansson, Andersson (CR6) 2017; 50 Ruban, Katsnelson, Olovsson, Simak, Abrikosov (CR15) 2005; 71 Lewis (CR3) 2014; 26 Vitos, Skriver, Johansson, Kollár (CR22) 2000; 18 Huang (CR20) 2016; 103 Gyorffy (CR27) 1972; 5 Lewis (CR4) 2014; 5 Binder (CR19) 1981; 43 Lee (CR18) 2014; 94 Montes-Arango (CR8) 2016; 116 Tian (CR12) 2019; 9 Kojima (CR1) 2014; 26 Goto (CR10) 2017; 7 Birch (CR14) 1947; 71 Jena, Sanyal, Mookerjee (CR11) 2014; 360 Murnaghan (CR13) 1944; 30 Vitos, Abrikosov, Johansson (CR23) 2001; 87 Skubic, Hellsvik, Nordström, Eriksson (CR25) 2008; 20 Cui (CR5) 2018; 158 B Skubic (71551_CR25) 2008; 20 B Gyorffy (71551_CR27) 1972; 5 A Frisk (71551_CR6) 2017; 50 P Soven (71551_CR26) 1967; 156 AV Ruban (71551_CR15) 2005; 71 L-Y Tian (71551_CR12) 2019; 9 T Kojima (71551_CR1) 2014; 26 LH Lewis (71551_CR3) 2014; 26 H Wang (71551_CR16) 2010; 82 L Vitos (71551_CR23) 2001; 87 L Vitos (71551_CR22) 2000; 18 LH Lewis (71551_CR4) 2014; 5 A Montes-Arango (71551_CR8) 2016; 116 S Lee (71551_CR18) 2014; 94 AP Jena (71551_CR11) 2014; 360 A Edström (71551_CR21) 2014; 90 L Vitos (71551_CR24) 2007 J Albertsen (71551_CR17) 1981; 23 S Huang (71551_CR20) 2016; 103 T Kojima (71551_CR7) 2014; 47 S Goto (71551_CR10) 2017; 7 FD Murnaghan (71551_CR13) 1944; 30 F Birch (71551_CR14) 1947; 71 K Binder (71551_CR19) 1981; 43 R Skomski (71551_CR2) 2013; 49 T Shima (71551_CR9) 2007; 310 J Cui (71551_CR5) 2018; 158 |
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| Title | Pressure effect on the order–disorder transformation in L10 FeNi |
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