Silicon solar cells: toward the efficiency limits

Photovoltaic (PV) conversion of solar energy starts to give an appreciable contribution to power generation in many countries, with more than 90% of the global PV market relying on solar cells based on crystalline silicon (c-Si). The current efficiency record of c-Si solar cells is 26.7%, against an...

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Published inAdvances in physics: X Vol. 4; no. 1; p. 1548305
Main Authors Andreani, Lucio Claudio, Bozzola, Angelo, Kowalczewski, Piotr, Liscidini, Marco, Redorici, Lisa
Format Journal Article
LanguageEnglish
Published Abingdon Taylor & Francis 01.01.2019
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Abstract Photovoltaic (PV) conversion of solar energy starts to give an appreciable contribution to power generation in many countries, with more than 90% of the global PV market relying on solar cells based on crystalline silicon (c-Si). The current efficiency record of c-Si solar cells is 26.7%, against an intrinsic limit of ~29%. Current research and production trends aim at increasing the efficiency, and reducing the cost, of industrial modules. In this paper, we review the main concepts and theoretical approaches that allow calculating the efficiency limits of c-Si solar cells as a function of silicon thickness. For a given material quality, the optimal thickness is determined by a trade-off between the competing needs of high optical absorption (requiring a thicker absorbing layer) and of efficient carrier collection (best achieved by a thin silicon layer). The efficiency limits can be calculated by solving the transport equations in the assumption of optimal (Lambertian) light trapping, which can be achieved by inserting proper photonic structures in the solar cell architecture. The effects of extrinsic (bulk and surface) recombinations on the conversion efficiency are discussed. We also show how the main conclusions and trends can be described using relatively simple analytic models. Prospects for overcoming the 29% limit by means of silicon/perovskite tandems are briefly discussed.
AbstractList Photovoltaic (PV) conversion of solar energy starts to give an appreciable contribution to power generation in many countries, with more than 90% of the global PV market relying on solar cells based on crystalline silicon (c-Si). The current efficiency record of c-Si solar cells is 26.7%, against an intrinsic limit of ~29%. Current research and production trends aim at increasing the efficiency, and reducing the cost, of industrial modules. In this paper, we review the main concepts and theoretical approaches that allow calculating the efficiency limits of c-Si solar cells as a function of silicon thickness. For a given material quality, the optimal thickness is determined by a trade-off between the competing needs of high optical absorption (requiring a thicker absorbing layer) and of efficient carrier collection (best achieved by a thin silicon layer). The efficiency limits can be calculated by solving the transport equations in the assumption of optimal (Lambertian) light trapping, which can be achieved by inserting proper photonic structures in the solar cell architecture. The effects of extrinsic (bulk and surface) recombinations on the conversion efficiency are discussed. We also show how the main conclusions and trends can be described using relatively simple analytic models. Prospects for overcoming the 29% limit by means of silicon/perovskite tandems are briefly discussed.
Author Kowalczewski, Piotr
Bozzola, Angelo
Liscidini, Marco
Andreani, Lucio Claudio
Redorici, Lisa
Author_xml – sequence: 1
  givenname: Lucio Claudio
  surname: Andreani
  fullname: Andreani, Lucio Claudio
  email: lucio.andreani@unipv.it
  organization: Department of Physics, University of Pavia
– sequence: 2
  givenname: Angelo
  surname: Bozzola
  fullname: Bozzola, Angelo
  organization: Department of Physics, University of Pavia
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  surname: Kowalczewski
  fullname: Kowalczewski, Piotr
  organization: Department of Physics, University of Pavia
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  givenname: Marco
  surname: Liscidini
  fullname: Liscidini, Marco
  organization: Department of Physics, University of Pavia
– sequence: 5
  givenname: Lisa
  surname: Redorici
  fullname: Redorici, Lisa
  organization: Department of Physics, University of Pavia
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Snippet Photovoltaic (PV) conversion of solar energy starts to give an appreciable contribution to power generation in many countries, with more than 90% of the global...
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SubjectTerms 78.20.Bh Theory
88.40.hj Efficiency and performance of solar cells
88.40.jj Silicon solar cells
Absorption
Computational efficiency
Computing time
Current efficiency
Efficiency
efficiency limits
Energy conversion efficiency
Lambertian light trapping
numerical simulation 42.25.Bs Wave propagation
optoelectronic simulations
Perovskites
Photovoltaic cells
Silicon
Silicon photovoltaics
Solar cells
Solar energy conversion
Thickness
thin-film solar cells
transmission and absorption
Transport equations
Trends
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Title Silicon solar cells: toward the efficiency limits
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