Metastable pitting corrosion behavior of laser powder bed fusion produced Ti-6Al-4V in Hank’s solution

The metastable pitting corrosion behavior of laser powder bed fusion (LPBF) produced Ti-6Al-4V is still unclear. Therefore, this work investigated the metastable pitting corrosion of LPBF-produced Ti-6Al-4V in Hank’s solution by electrochemical methods. The LPBF-produced sample (dominant by α′ phase...

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Published inCorrosion science Vol. 203; p. 110333
Main Authors Cui, Yu-Wei, Chen, Liang-Yu, Qin, Peng, Li, Ruifeng, Zang, Qianhao, Peng, Jinhua, Zhang, Lina, Lu, Sheng, Wang, Liqiang, Zhang, Lai-Chang
Format Journal Article
LanguageEnglish
Published Amsterdam Elsevier Ltd 15.07.2022
Elsevier BV
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Abstract The metastable pitting corrosion behavior of laser powder bed fusion (LPBF) produced Ti-6Al-4V is still unclear. Therefore, this work investigated the metastable pitting corrosion of LPBF-produced Ti-6Al-4V in Hank’s solution by electrochemical methods. The LPBF-produced sample (dominant by α′ phase in the microstructure) shows a higher frequency of pit nucleation than the annealed counterpart (composed by α + β dual phase). The passive films formed on the LPBF-produced sample exhibit a higher flux of oxygen vacancies, resulting in the absorption of more aggressive ions (e.g., Cl-) thereby producing more cation vacancies. The condensation of excessive cation vacancies contributes to the pit nucleation. [Display omitted] •Laser powder bed fusion (LPBF) produced Ti–6Al–4 V alloy was used as the sample.•Corrosion behavior of the LPBF-produced sample was investigated in Hank’s solution.•The LPBF-produced Ti-6Al-4 V shows frequent metastable pitting corrosion.•The flux of oxygen vacancy is large in the passive film of LPBF-produced Ti-6Al-4 V.•Redundant vacancies assemble and condense into a void at metal/film interface.
AbstractList The metastable pitting corrosion behavior of laser powder bed fusion (LPBF) produced Ti-6Al-4V is still unclear. Therefore, this work investigated the metastable pitting corrosion of LPBF-produced Ti-6Al-4V in Hank's solution by electrochemical methods. The LPBF-produced sample (dominant by α′ phase in the microstructure) shows a higher frequency of pit nucleation than the annealed counterpart (composed by α + β dual phase). The passive films formed on the LPBF-produced sample exhibit a higher flux of oxygen vacancies, resulting in the absorption of more aggressive ions (e.g., Cl-) thereby producing more cation vacancies. The condensation of excessive cation vacancies contributes to the pit nucleation.
The metastable pitting corrosion behavior of laser powder bed fusion (LPBF) produced Ti-6Al-4V is still unclear. Therefore, this work investigated the metastable pitting corrosion of LPBF-produced Ti-6Al-4V in Hank’s solution by electrochemical methods. The LPBF-produced sample (dominant by α′ phase in the microstructure) shows a higher frequency of pit nucleation than the annealed counterpart (composed by α + β dual phase). The passive films formed on the LPBF-produced sample exhibit a higher flux of oxygen vacancies, resulting in the absorption of more aggressive ions (e.g., Cl-) thereby producing more cation vacancies. The condensation of excessive cation vacancies contributes to the pit nucleation. [Display omitted] •Laser powder bed fusion (LPBF) produced Ti–6Al–4 V alloy was used as the sample.•Corrosion behavior of the LPBF-produced sample was investigated in Hank’s solution.•The LPBF-produced Ti-6Al-4 V shows frequent metastable pitting corrosion.•The flux of oxygen vacancy is large in the passive film of LPBF-produced Ti-6Al-4 V.•Redundant vacancies assemble and condense into a void at metal/film interface.
ArticleNumber 110333
Author Chen, Liang-Yu
Peng, Jinhua
Qin, Peng
Lu, Sheng
Li, Ruifeng
Zang, Qianhao
Cui, Yu-Wei
Zhang, Lina
Wang, Liqiang
Zhang, Lai-Chang
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  surname: Cui
  fullname: Cui, Yu-Wei
  organization: School of Science, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu 212100, China
– sequence: 2
  givenname: Liang-Yu
  surname: Chen
  fullname: Chen, Liang-Yu
  email: lychen@just.edu.cn
  organization: School of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu 212100, China
– sequence: 3
  givenname: Peng
  surname: Qin
  fullname: Qin, Peng
  organization: School of Engineering, Edith Cowan University, 270 Joondalup Drive, Joondalup, Perth, WA 6027, Australia
– sequence: 4
  givenname: Ruifeng
  surname: Li
  fullname: Li, Ruifeng
  organization: School of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu 212100, China
– sequence: 5
  givenname: Qianhao
  surname: Zang
  fullname: Zang, Qianhao
  organization: School of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu 212100, China
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  givenname: Jinhua
  surname: Peng
  fullname: Peng, Jinhua
  organization: School of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu 212100, China
– sequence: 7
  givenname: Lina
  surname: Zhang
  fullname: Zhang, Lina
  organization: School of Science, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu 212100, China
– sequence: 8
  givenname: Sheng
  surname: Lu
  fullname: Lu, Sheng
  organization: School of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu 212100, China
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  givenname: Liqiang
  surname: Wang
  fullname: Wang, Liqiang
  email: wang_liqiang@sjtu.edu.cn
  organization: State Key Laboratory of Metal Matrix Composites, School of Material Science and Engineering, Shanghai Jiao Tong University, No. 800 Dongchuan Road, Shanghai 200240, China
– sequence: 10
  givenname: Lai-Chang
  surname: Zhang
  fullname: Zhang, Lai-Chang
  email: l.zhang@ecu.edu.au, lczhangimr@gmail.com
  organization: School of Engineering, Edith Cowan University, 270 Joondalup Drive, Joondalup, Perth, WA 6027, Australia
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Keywords Titanium alloy
Laser powder bed fusion
Metastable pitting corrosion
Passive film
Corrosion behavior
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Snippet The metastable pitting corrosion behavior of laser powder bed fusion (LPBF) produced Ti-6Al-4V is still unclear. Therefore, this work investigated the...
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SubjectTerms Cations
Corrosion behavior
Laser powder bed fusion
Metastable pitting corrosion
Nucleation
Passive film
Pitting (corrosion)
Powder beds
Titanium alloy
Titanium base alloys
Vacancies
Title Metastable pitting corrosion behavior of laser powder bed fusion produced Ti-6Al-4V in Hank’s solution
URI https://dx.doi.org/10.1016/j.corsci.2022.110333
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