High Emissivity MoSi2-SiC-Al2O3 Coating on Rigid Insulation Tiles with Enhanced Thermal Protection Performance
High emissivity coatings with sol as the binder have the advantages of room temperature curing, good thermal shock resistance, and high emissivity; however, only silica sol has been used in the current systems. In this study, aluminum sol was used as the binder for the first time, and MoSi2 and SiC...
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Published in | Materials Vol. 17; no. 1; p. 220 |
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Abstract | High emissivity coatings with sol as the binder have the advantages of room temperature curing, good thermal shock resistance, and high emissivity; however, only silica sol has been used in the current systems. In this study, aluminum sol was used as the binder for the first time, and MoSi2 and SiC were used as emittance agents to prepare a high emissivity MoSi2-SiC-Al2O3 coating on mullite insulation tiles. The evolution of structure and composition at 1000–1400 °C, the spectral emissivity from 200 nm to 25 μm, and the insulation performance were studied. Compared with the coating with silica sol as a binder, the MoSi2-SiC-Al2O3 coating has better structural uniformity and greater surface roughness and can generate mullite whiskers at lower temperatures. The total emissivity is 0.922 and 0.897, respectively, at the wavelength range of 200–2500 nm and 2.5–25 μm, and the superior emissivity at a low wavelength (<10 μm) is related to a higher surface roughness and reduced feature absorption. The emissivity reduction related to the oxidation of emittance agents at a high temperature (−10.2%) is smaller than that of the silica-sol-bonded coating (−18.6%). The cold surface temperature of the coated substrate is 215 °C lower than the bare substrate, suggesting excellent thermal insulation performance of the coating. |
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AbstractList | High emissivity coatings with sol as the binder have the advantages of room temperature curing, good thermal shock resistance, and high emissivity; however, only silica sol has been used in the current systems. In this study, aluminum sol was used as the binder for the first time, and MoSi2 and SiC were used as emittance agents to prepare a high emissivity MoSi2-SiC-Al2O3 coating on mullite insulation tiles. The evolution of structure and composition at 1000–1400 °C, the spectral emissivity from 200 nm to 25 μm, and the insulation performance were studied. Compared with the coating with silica sol as a binder, the MoSi2-SiC-Al2O3 coating has better structural uniformity and greater surface roughness and can generate mullite whiskers at lower temperatures. The total emissivity is 0.922 and 0.897, respectively, at the wavelength range of 200–2500 nm and 2.5–25 μm, and the superior emissivity at a low wavelength (<10 μm) is related to a higher surface roughness and reduced feature absorption. The emissivity reduction related to the oxidation of emittance agents at a high temperature (−10.2%) is smaller than that of the silica-sol-bonded coating (−18.6%). The cold surface temperature of the coated substrate is 215 °C lower than the bare substrate, suggesting excellent thermal insulation performance of the coating. High emissivity coatings with sol as the binder have the advantages of room temperature curing, good thermal shock resistance, and high emissivity; however, only silica sol has been used in the current systems. In this study, aluminum sol was used as the binder for the first time, and MoSi 2 and SiC were used as emittance agents to prepare a high emissivity MoSi 2 -SiC-Al 2 O 3 coating on mullite insulation tiles. The evolution of structure and composition at 1000–1400 °C, the spectral emissivity from 200 nm to 25 μm, and the insulation performance were studied. Compared with the coating with silica sol as a binder, the MoSi 2 -SiC-Al 2 O 3 coating has better structural uniformity and greater surface roughness and can generate mullite whiskers at lower temperatures. The total emissivity is 0.922 and 0.897, respectively, at the wavelength range of 200–2500 nm and 2.5–25 μm, and the superior emissivity at a low wavelength (<10 μm) is related to a higher surface roughness and reduced feature absorption. The emissivity reduction related to the oxidation of emittance agents at a high temperature (−10.2%) is smaller than that of the silica-sol-bonded coating (−18.6%). The cold surface temperature of the coated substrate is 215 °C lower than the bare substrate, suggesting excellent thermal insulation performance of the coating. High emissivity coatings with sol as the binder have the advantages of room temperature curing, good thermal shock resistance, and high emissivity; however, only silica sol has been used in the current systems. In this study, aluminum sol was used as the binder for the first time, and MoSi2 and SiC were used as emittance agents to prepare a high emissivity MoSi2-SiC-Al2O3 coating on mullite insulation tiles. The evolution of structure and composition at 1000-1400 °C, the spectral emissivity from 200 nm to 25 μm, and the insulation performance were studied. Compared with the coating with silica sol as a binder, the MoSi2-SiC-Al2O3 coating has better structural uniformity and greater surface roughness and can generate mullite whiskers at lower temperatures. The total emissivity is 0.922 and 0.897, respectively, at the wavelength range of 200-2500 nm and 2.5-25 μm, and the superior emissivity at a low wavelength (<10 μm) is related to a higher surface roughness and reduced feature absorption. The emissivity reduction related to the oxidation of emittance agents at a high temperature (-10.2%) is smaller than that of the silica-sol-bonded coating (-18.6%). The cold surface temperature of the coated substrate is 215 °C lower than the bare substrate, suggesting excellent thermal insulation performance of the coating. |
Author | Yang, Xukun Wan, Yange Tao, Xin Wang, Mingchao Li, Jiancun Liu, Jiachen |
AuthorAffiliation | 4 College of Science, Civil Aviation University of China, Tianjin 300300, China 2 Beijing Institute of Astronautical Systems Engineering, Beijing 100076, China 1 Key Lab of Advanced Ceramics and Machining Technology of Ministry of Education, School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China 3 School of Safety Science and Engineering, Civil Aviation University of China, Tianjin 300300, China |
AuthorAffiliation_xml | – name: 4 College of Science, Civil Aviation University of China, Tianjin 300300, China – name: 2 Beijing Institute of Astronautical Systems Engineering, Beijing 100076, China – name: 3 School of Safety Science and Engineering, Civil Aviation University of China, Tianjin 300300, China – name: 1 Key Lab of Advanced Ceramics and Machining Technology of Ministry of Education, School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China |
Author_xml | – sequence: 1 givenname: Xukun surname: Yang fullname: Yang, Xukun – sequence: 2 givenname: Yange surname: Wan fullname: Wan, Yange – sequence: 3 givenname: Jiancun surname: Li fullname: Li, Jiancun – sequence: 4 givenname: Jiachen surname: Liu fullname: Liu, Jiachen – sequence: 5 givenname: Mingchao surname: Wang fullname: Wang, Mingchao – sequence: 6 givenname: Xin surname: Tao fullname: Tao, Xin |
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SubjectTerms | Aircraft Alumina alumina sol Aluminum Aluminum oxide Cold surfaces Emittance flame heating experiment Fourier transforms Heat resistance high emissivity coating High temperature Molybdenum disilicides Mullite Oxidation Radiation Room temperature Shock resistance Silica Silicon carbide Silicon dioxide Spectral emissivity Substrates Surface roughness Temperature Thermal insulation Thermal protection thermal protection system Thermal resistance Thermal shock Tiles |
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Title | High Emissivity MoSi2-SiC-Al2O3 Coating on Rigid Insulation Tiles with Enhanced Thermal Protection Performance |
URI | https://www.proquest.com/docview/2912686952 https://search.proquest.com/docview/2913447029 https://pubmed.ncbi.nlm.nih.gov/PMC10779669 https://doaj.org/article/46fd13072f3047a6bd37d6b9f5918d10 |
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