High Emissivity MoSi2-SiC-Al2O3 Coating on Rigid Insulation Tiles with Enhanced Thermal Protection Performance

High emissivity coatings with sol as the binder have the advantages of room temperature curing, good thermal shock resistance, and high emissivity; however, only silica sol has been used in the current systems. In this study, aluminum sol was used as the binder for the first time, and MoSi2 and SiC...

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Published inMaterials Vol. 17; no. 1; p. 220
Main Authors Yang, Xukun, Wan, Yange, Li, Jiancun, Liu, Jiachen, Wang, Mingchao, Tao, Xin
Format Journal Article
LanguageEnglish
Published Basel MDPI AG 01.01.2024
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Abstract High emissivity coatings with sol as the binder have the advantages of room temperature curing, good thermal shock resistance, and high emissivity; however, only silica sol has been used in the current systems. In this study, aluminum sol was used as the binder for the first time, and MoSi2 and SiC were used as emittance agents to prepare a high emissivity MoSi2-SiC-Al2O3 coating on mullite insulation tiles. The evolution of structure and composition at 1000–1400 °C, the spectral emissivity from 200 nm to 25 μm, and the insulation performance were studied. Compared with the coating with silica sol as a binder, the MoSi2-SiC-Al2O3 coating has better structural uniformity and greater surface roughness and can generate mullite whiskers at lower temperatures. The total emissivity is 0.922 and 0.897, respectively, at the wavelength range of 200–2500 nm and 2.5–25 μm, and the superior emissivity at a low wavelength (<10 μm) is related to a higher surface roughness and reduced feature absorption. The emissivity reduction related to the oxidation of emittance agents at a high temperature (−10.2%) is smaller than that of the silica-sol-bonded coating (−18.6%). The cold surface temperature of the coated substrate is 215 °C lower than the bare substrate, suggesting excellent thermal insulation performance of the coating.
AbstractList High emissivity coatings with sol as the binder have the advantages of room temperature curing, good thermal shock resistance, and high emissivity; however, only silica sol has been used in the current systems. In this study, aluminum sol was used as the binder for the first time, and MoSi2 and SiC were used as emittance agents to prepare a high emissivity MoSi2-SiC-Al2O3 coating on mullite insulation tiles. The evolution of structure and composition at 1000–1400 °C, the spectral emissivity from 200 nm to 25 μm, and the insulation performance were studied. Compared with the coating with silica sol as a binder, the MoSi2-SiC-Al2O3 coating has better structural uniformity and greater surface roughness and can generate mullite whiskers at lower temperatures. The total emissivity is 0.922 and 0.897, respectively, at the wavelength range of 200–2500 nm and 2.5–25 μm, and the superior emissivity at a low wavelength (<10 μm) is related to a higher surface roughness and reduced feature absorption. The emissivity reduction related to the oxidation of emittance agents at a high temperature (−10.2%) is smaller than that of the silica-sol-bonded coating (−18.6%). The cold surface temperature of the coated substrate is 215 °C lower than the bare substrate, suggesting excellent thermal insulation performance of the coating.
High emissivity coatings with sol as the binder have the advantages of room temperature curing, good thermal shock resistance, and high emissivity; however, only silica sol has been used in the current systems. In this study, aluminum sol was used as the binder for the first time, and MoSi 2 and SiC were used as emittance agents to prepare a high emissivity MoSi 2 -SiC-Al 2 O 3 coating on mullite insulation tiles. The evolution of structure and composition at 1000–1400 °C, the spectral emissivity from 200 nm to 25 μm, and the insulation performance were studied. Compared with the coating with silica sol as a binder, the MoSi 2 -SiC-Al 2 O 3 coating has better structural uniformity and greater surface roughness and can generate mullite whiskers at lower temperatures. The total emissivity is 0.922 and 0.897, respectively, at the wavelength range of 200–2500 nm and 2.5–25 μm, and the superior emissivity at a low wavelength (<10 μm) is related to a higher surface roughness and reduced feature absorption. The emissivity reduction related to the oxidation of emittance agents at a high temperature (−10.2%) is smaller than that of the silica-sol-bonded coating (−18.6%). The cold surface temperature of the coated substrate is 215 °C lower than the bare substrate, suggesting excellent thermal insulation performance of the coating.
High emissivity coatings with sol as the binder have the advantages of room temperature curing, good thermal shock resistance, and high emissivity; however, only silica sol has been used in the current systems. In this study, aluminum sol was used as the binder for the first time, and MoSi2 and SiC were used as emittance agents to prepare a high emissivity MoSi2-SiC-Al2O3 coating on mullite insulation tiles. The evolution of structure and composition at 1000-1400 °C, the spectral emissivity from 200 nm to 25 μm, and the insulation performance were studied. Compared with the coating with silica sol as a binder, the MoSi2-SiC-Al2O3 coating has better structural uniformity and greater surface roughness and can generate mullite whiskers at lower temperatures. The total emissivity is 0.922 and 0.897, respectively, at the wavelength range of 200-2500 nm and 2.5-25 μm, and the superior emissivity at a low wavelength (<10 μm) is related to a higher surface roughness and reduced feature absorption. The emissivity reduction related to the oxidation of emittance agents at a high temperature (-10.2%) is smaller than that of the silica-sol-bonded coating (-18.6%). The cold surface temperature of the coated substrate is 215 °C lower than the bare substrate, suggesting excellent thermal insulation performance of the coating.
Author Yang, Xukun
Wan, Yange
Tao, Xin
Wang, Mingchao
Li, Jiancun
Liu, Jiachen
AuthorAffiliation 4 College of Science, Civil Aviation University of China, Tianjin 300300, China
2 Beijing Institute of Astronautical Systems Engineering, Beijing 100076, China
1 Key Lab of Advanced Ceramics and Machining Technology of Ministry of Education, School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China
3 School of Safety Science and Engineering, Civil Aviation University of China, Tianjin 300300, China
AuthorAffiliation_xml – name: 4 College of Science, Civil Aviation University of China, Tianjin 300300, China
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– name: 1 Key Lab of Advanced Ceramics and Machining Technology of Ministry of Education, School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China
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CitedBy_id crossref_primary_10_3390_ma17061251
crossref_primary_10_3390_ma17133234
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Snippet High emissivity coatings with sol as the binder have the advantages of room temperature curing, good thermal shock resistance, and high emissivity; however,...
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StartPage 220
SubjectTerms Aircraft
Alumina
alumina sol
Aluminum
Aluminum oxide
Cold surfaces
Emittance
flame heating experiment
Fourier transforms
Heat resistance
high emissivity coating
High temperature
Molybdenum disilicides
Mullite
Oxidation
Radiation
Room temperature
Shock resistance
Silica
Silicon carbide
Silicon dioxide
Spectral emissivity
Substrates
Surface roughness
Temperature
Thermal insulation
Thermal protection
thermal protection system
Thermal resistance
Thermal shock
Tiles
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Title High Emissivity MoSi2-SiC-Al2O3 Coating on Rigid Insulation Tiles with Enhanced Thermal Protection Performance
URI https://www.proquest.com/docview/2912686952
https://search.proquest.com/docview/2913447029
https://pubmed.ncbi.nlm.nih.gov/PMC10779669
https://doaj.org/article/46fd13072f3047a6bd37d6b9f5918d10
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