Onset of nanotube decay under extreme thermal and electronic excitations

• Published in: Physica. B, Condensed matter Vol. 323; no. 1; pp. 78 - 85
• Main Authors: Miyamoto, Yoshiyuki, Berber, Savas, Yoon, Mina, Rubio, Angel, Tománek, David
• Format: Journal Article Conference Proceeding
• Language: English
• Published: Amsterdam Elsevier B.V 01.10.2002; Elsevier
• Subjects: Carbon nanotubes; Clusters, nanoparticles, and nanocrystalline materials; Condensed matter: structure, mechanical and thermal properties; Defects; Density functional theory; Exact sciences and technology; Lattice dynamics; Molecular dynamics; Nanoscale materials: clusters, nanoparticles, nanotubes, and nanocrystals; Phonons in low-dimensional structures and small particles; Physics; Structure of solids and liquids; crystallography; 71.15.Pd; Carbon nanotubes; Molecular dynamics; 61.48.+c; Density functional theory; 61.72.Bb; Defects; Vacancies; Stability; Molecular dynamics method; Theoretical study; Thermal excitation; Bond lengths; Dangling bonds; Tight binding approximation; Vibrational modes; Chemical bonds; Density functional method; Atomic structure
• ISSN: 0921-4526; 1873-2135
• DOI: 10.1016/S0921-4526(02)00988-2

Stability test of nanotubes with presence of single vacancies has been performed by means of tight-binding molecular dynamics and electron–ion dynamics within the framework of the density functional theory. A 4 A ̊ diameter nanotube having a single vacancy with three dangling bonds has been found to retain its cylindrical shape under high temperature around 4000 K , despite its large internal strain energy. Meanwhile, an electronic excitation of vacancy-related state has shown considerable atomic displacement, which may cause extraordinary large lattice vibration or nanotube decay. Furthermore, the single vacancy can stabilize itself by making carbon dimer to remain with only one dangling bond. Narrower nanotubes tend to prefer this self-stabilization and thus could be tolerant to the presence of defects.