Engineering Self‐Supported Noble Metal Foams Toward Electrocatalysis and Beyond
Noble metals, despite their expensiveness, display irreplaceable roles in widespread fields. To acquire novel physicochemical properties and boost the performance‐to‐price ratio for practical applications, one core direction is to engineer noble metals into nanostructured porous networks. Noble meta...
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Published in | Advanced energy materials Vol. 10; no. 11 |
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Format | Journal Article |
Language | English |
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01.03.2020
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Abstract | Noble metals, despite their expensiveness, display irreplaceable roles in widespread fields. To acquire novel physicochemical properties and boost the performance‐to‐price ratio for practical applications, one core direction is to engineer noble metals into nanostructured porous networks. Noble metal foams (NMFs), featuring self‐supported, 3D interconnected networks structured from noble‐metal‐based building blocks, have drawn tremendous attention in the last two decades. Inheriting structural traits of foams and physicochemical properties of noble metals, NMFs showcase a variety of interesting properties and impressive prospect in diverse fields, including electrocatalysis, heterogeneous catalysis, surface‐enhanced Raman scattering, sensing and actuation, etc. A number of NMFs have been created and versatile synthetic approaches have been developed. However, because of the innate limitation of specific methods and the insufficient understanding of formation mechanisms, flexible manipulation of compositions, structures, and corresponding properties of NMFs are still challenging. Thus, the correlations between composition/structure and properties are seldom established, retarding material design/optimization for specific applications. This review is devoted to a comprehensive introduction of NMFs ranging from synthesis to applications, with an emphasis on electrocatalysis. Challenges and opportunities are also included to guide possible research directions in this field and promote the interest of interdisciplinary scientists.
Noble metal foams (NMFs) are 3D interconnected networks structured from noble‐metal‐based building blocks. Featuring abundant active sites and 3D mass/electron transfer channels, they showcase a variety of interesting properties and impressive prospects in diverse fields. A comprehensive review on NMFs from synthesis to applications is given, with an emphasis on their applications in energy‐related fields. |
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AbstractList | Noble metals, despite their expensiveness, display irreplaceable roles in widespread fields. To acquire novel physicochemical properties and boost the performance‐to‐price ratio for practical applications, one core direction is to engineer noble metals into nanostructured porous networks. Noble metal foams (NMFs), featuring self‐supported, 3D interconnected networks structured from noble‐metal‐based building blocks, have drawn tremendous attention in the last two decades. Inheriting structural traits of foams and physicochemical properties of noble metals, NMFs showcase a variety of interesting properties and impressive prospect in diverse fields, including electrocatalysis, heterogeneous catalysis, surface‐enhanced Raman scattering, sensing and actuation, etc. A number of NMFs have been created and versatile synthetic approaches have been developed. However, because of the innate limitation of specific methods and the insufficient understanding of formation mechanisms, flexible manipulation of compositions, structures, and corresponding properties of NMFs are still challenging. Thus, the correlations between composition/structure and properties are seldom established, retarding material design/optimization for specific applications. This review is devoted to a comprehensive introduction of NMFs ranging from synthesis to applications, with an emphasis on electrocatalysis. Challenges and opportunities are also included to guide possible research directions in this field and promote the interest of interdisciplinary scientists.
Noble metal foams (NMFs) are 3D interconnected networks structured from noble‐metal‐based building blocks. Featuring abundant active sites and 3D mass/electron transfer channels, they showcase a variety of interesting properties and impressive prospects in diverse fields. A comprehensive review on NMFs from synthesis to applications is given, with an emphasis on their applications in energy‐related fields. |
Author | Du, Ran Hübner, René Fan, Xuelin Hu, Yue Jin, Xinyi Eychmüller, Alexander |
Author_xml | – sequence: 1 givenname: Ran surname: Du fullname: Du, Ran email: Ran.Du@chemie.tu-dresden.de organization: Technische Universität Dresden – sequence: 2 givenname: Xinyi surname: Jin fullname: Jin, Xinyi organization: Zhejiang University – sequence: 3 givenname: René surname: Hübner fullname: Hübner, René organization: Institute of Ion Beam Physics and Materials Research – sequence: 4 givenname: Xuelin surname: Fan fullname: Fan, Xuelin organization: Technische Universität Dresden – sequence: 5 givenname: Yue surname: Hu fullname: Hu, Yue organization: Wenzhou University – sequence: 6 givenname: Alexander orcidid: 0000-0001-9926-6279 surname: Eychmüller fullname: Eychmüller, Alexander email: alexander.eychmueller@chemie.tu-dresden.de organization: Technische Universität Dresden |
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SubjectTerms | aerogels electrocatalysis foams nanostructures noble metals |
Title | Engineering Self‐Supported Noble Metal Foams Toward Electrocatalysis and Beyond |
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