An Organic–Inorganic Hybrid Exhibiting Electrical Conduction and Single‐Ion Magnetism

• Published in: Angewandte Chemie International Edition Vol. 59; no. 6; pp. 2399 - 2406
• Main Authors: Shen, Yongbing, Cosquer, Goulven, Ito, Hiroshi, Izuogu, David C., Thom, Alex J. W., Ina, Toshiaki, Uruga, Tomoya, Yoshida, Takefumi, Takaishi, Shinya, Breedlove, Brian K., Li, Zhao‐Yang, Yamashita, Masahiro
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 03.02.2020
• Edition: International ed. in English
• Subjects: 3D networks; Benzene; Charge transfer; Conduction; Conductors; crystalline solids; d–pi interactions; Electric conductors; Electrical conduction; Electrical conductivity; Electrical resistivity; Hysteresis loops; Low temperature; Magnetic induction; Magnetic relaxation; Magnetism; Oxidation; crystalline solids; d-pi interactions; electrical conductivity; 3D networks; charge transfer

The first three‐dimensional (3D) conductive single‐ion magnet (SIM), (TTF)2[Co(pdms)2] (TTF=tetrathiafulvalene and H2pdms=1,2‐bis(methanesulfonamido)benzene), was electrochemically synthesised and investigated structurally, physically, and theoretically. The similar oxidation potentials of neutral T...