Formation of Polymer-Carbon Nanotube Composites by Two-Step Supercritical Fluid Treatment

An approach for polymer-carbon nanotube (CNT) composite preparation is proposed based on a two-step supercritical fluid treatment. The first step, rapid expansion of a suspension (RESS) of CNTs in supercritical carbon dioxide, is used to de-bundle CNTs in order to simplify their mixing with polymer...

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Published inMaterials Vol. 14; no. 23; p. 7428
Main Authors Vorobei, Anton M., Ustinovich, Konstantin B., Chernyak, Sergei A., Savilov, Sergei V., Parenago, Olga O., Kiselev, Mikhail G.
Format Journal Article
LanguageEnglish
Published Basel MDPI AG 03.12.2021
MDPI
Subjects
Atmospheric pressure
Carbon dioxide
Chemical precipitation
CNT-polymer composites
Composite materials
Multi wall carbon nanotubes
Nanocomposites
Phase transitions
Polymer matrix composites
Polymers
Power
rapid expansion of supercritical suspensions (RESS)
Solvents
supercritical antisolvent precipitation (SAS)
Supercritical fluids
Tensile strength
Ultrasonic imaging
Russia
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Abstract An approach for polymer-carbon nanotube (CNT) composite preparation is proposed based on a two-step supercritical fluid treatment. The first step, rapid expansion of a suspension (RESS) of CNTs in supercritical carbon dioxide, is used to de-bundle CNTs in order to simplify their mixing with polymer in solution. The ability of RESS pre-treatment to de-bundle CNTs and to cause significant bulk volume expansion is demonstrated. The second step is the formation of polymer-CNT composite from solution via supercritical antisolvent (SAS) precipitation. SAS treatment allows avoiding CNT agglomeration during transition from a solution into solid state due to the high speed of phase transition. The combination of these two supercritical fluid methods allowed obtaining a polycarbonate-multiwalled carbon nanotube composite with tensile strength two times higher compared to the initial polymer and enhanced elasticity.
AbstractList An approach for polymer-carbon nanotube (CNT) composite preparation is proposed based on a two-step supercritical fluid treatment. The first step, rapid expansion of a suspension (RESS) of CNTs in supercritical carbon dioxide, is used to de-bundle CNTs in order to simplify their mixing with polymer in solution. The ability of RESS pre-treatment to de-bundle CNTs and to cause significant bulk volume expansion is demonstrated. The second step is the formation of polymer-CNT composite from solution via supercritical antisolvent (SAS) precipitation. SAS treatment allows avoiding CNT agglomeration during transition from a solution into solid state due to the high speed of phase transition. The combination of these two supercritical fluid methods allowed obtaining a polycarbonate-multiwalled carbon nanotube composite with tensile strength two times higher compared to the initial polymer and enhanced elasticity.
Author Ustinovich, Konstantin B
Vorobei, Anton M
Savilov, Sergei V
Chernyak, Sergei A
Parenago, Olga O
Kiselev, Mikhail G
AuthorAffiliation 3 G. A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, 153045 Ivanovo, Russia; mgk@isc-ras.ru
2 Chemical Department, Lomonosov Moscow State University, 119991 Moscow, Russia; madseryi@mail.ru
1 Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, 119071 Moscow, Russia; ystinovich@supercritical.ru (K.B.U.); savilov@mail.ru (S.V.S.); oparenago@scf-tp.ru (O.O.P.)
AuthorAffiliation_xml – name: 2 Chemical Department, Lomonosov Moscow State University, 119991 Moscow, Russia; madseryi@mail.ru
– name: 1 Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, 119071 Moscow, Russia; ystinovich@supercritical.ru (K.B.U.); savilov@mail.ru (S.V.S.); oparenago@scf-tp.ru (O.O.P.)
– name: 3 G. A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, 153045 Ivanovo, Russia; mgk@isc-ras.ru
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CitedBy_id crossref_primary_10_1134_S1990793123070126
crossref_primary_10_3390_polym16060770
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Snippet An approach for polymer-carbon nanotube (CNT) composite preparation is proposed based on a two-step supercritical fluid treatment. The first step, rapid...
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SubjectTerms Atmospheric pressure
Carbon dioxide
Chemical precipitation
CNT-polymer composites
Composite materials
Multi wall carbon nanotubes
Nanocomposites
Phase transitions
Polymer matrix composites
Polymers
Power
rapid expansion of supercritical suspensions (RESS)
Solvents
supercritical antisolvent precipitation (SAS)
Supercritical fluids
Tensile strength
Ultrasonic imaging
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Title Formation of Polymer-Carbon Nanotube Composites by Two-Step Supercritical Fluid Treatment
URI https://www.proquest.com/docview/2608140319/abstract/
https://search.proquest.com/docview/2608535880
https://pubmed.ncbi.nlm.nih.gov/PMC8659219
https://doaj.org/article/9fe69dbf655a4a7888a56b328ac61c0a
Volume 14
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