Regiodivergent sulfonylarylation of 1,3-enynes via nickel/photoredox dual catalysis

• Published in: Chemical science (Cambridge) Vol. 12; no. 40; pp. 13564 - 13571
• Main Authors: Chen, Ya, Zhu, Kun, Huang, Qingqin, Lu, Yixin
• Format: Journal Article
• Language: English
• Published: CAMBRIDGE Royal Soc Chemistry 20.10.2021; Royal Society of Chemistry; The Royal Society of Chemistry
• Subjects: Catalysis; Chemical synthesis; Chemistry; Chemistry, Multidisciplinary; Dienes; Nickel; Photoredox catalysis; Physical Sciences; Science & Technology; Selectivity; Stereoselectivity; Sulfones; VISIBLE-LIGHT PHOTOREDOX

Catalytic difunctionalization of 1,3-enynes represents an efficient and versatile approach to rapidly assemble multifunctional propargylic compounds, allenes and 1,3-dienes. Controlling selectivity in such addition reactions has been a long-standing challenging task due to multiple reactive centers...