Microstructure and Mechanical Properties of Core-Shell B4C-Reinforced Ti Matrix Composites

• Published in: Materials Vol. 16; no. 3; p. 1166
• Main Authors: Xiu, Ziyang, Ju, Boyu, Zhan, Junhai, Zhang, Ningbo, Wang, Pengjun, Zhao, Keguang, Liu, Mingda, Yin, Aiping, Chen, Weidi, Jiao, Yang, Wang, Hao, Li, Shuyang, Zhu, Xiaolin, Wu, Ping, Yang, Wenshu
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 30.01.2023; MDPI
• Subjects: B4C; Ball milling; Boron carbide; Ceramic matrix composites; Composite materials; Compressive properties; Compressive strength; Continuity; core-shell composite; Core-shell structure; High temperature; Hot pressing; Material properties; Mechanical properties; Metal matrix composites; Morphology; Particle size; Plasma sintering; R&D; Research & development; Sintering (powder metallurgy); Spark plasma sintering; Spherical powders; Strain rate; Stress distribution; Structural design; Thermal conductivity; Ti matrix composite; Titanium alloys; Titanium carbide; Titanium diboride; United States > US; China
• ISSN: 1996-1944; 1996-1944
• DOI: 10.3390/ma16031166

Composite material uses ceramic reinforcement to add to the metal matrix to obtain higher material properties. Structural design is an important direction of composite research. The reinforcement distribution of the core-shell structure has the unique advantages of strong continuity and uniform stress distribution. In this paper, a method of preparing boron carbide (B4C)-coated titanium (Ti) powder particles by ball milling and preparing core-shell B4C-reinforced Ti matrix composites by Spark Plasma Sintering was proposed. It can be seen that B4C coated on the surface of the spherical Ti powder to form a shell structure, and B4C had a certain continuity. Through X-ray diffraction characterization, it was found that B4C reacted with Ti to form layered phases of titanium boride (TiB) and titanium carbide (TiC). The compressive strength of the composite reached 1529.1 MPa, while maintaining a compressive strain rate of 5%. At the same time, conductivity and thermal conductivity were also characterized. The preparation process of the core-shell structure composites proposed in this paper has high feasibility and universality, and it is expected to be applied to other ceramic reinforcements. This result provides a reference for the design, preparation and performance research of core-shell composite materials.