Green Synthesis and Investigation of Surface Effects of α-Fe2O3@TiO2 Nanocomposites by Impedance Spectroscopy

• Published in: Materials Vol. 15; no. 16; p. 5768
• Main Authors: Sultan, Hira, Sultan, Aeysha, Orfali, Raha, Perveen, Shagufta, Ali, Tahir, Ullah, Sana, Anas, Haji Muhammad, Ghaffar, Safina, Al-Taweel, Areej, Waqas, Muhammad, Shahzad, Waseem, Kareem, Aftaab, Liaqat, Aqsa, Ashraf, Zaman, Shahid, Ayesha, Rauf, Abdul
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 21.08.2022; MDPI
• Subjects: Chemical analysis; Crystal defects; Decomposition; Energy dispersive X ray spectroscopy; Fourier transforms; ginger extract; Grain boundaries; Grain size; Green chemistry; green synthesis; hematite; Impedance spectroscopy; Infrared spectroscopy; iron oxide-titania nanocomposite; Iron oxides; Metabolites; Morphology; Nanocomposites; Nanoparticles; Particle size; Photocatalysis; Photon correlation spectroscopy; Room temperature; Scanning electron microscopy; Sintering; Surface defects; surface effects; Synthesis; Titanium dioxide; Titanium oxides
• ISSN: 1996-1944; 1996-1944
• DOI: 10.3390/ma15165768

Nanocomposites based on iron oxide/titanium oxide nanoparticles were prepared by employing green synthesis, which involved phytochemical-mediated reduction using ginger extract. XRD confirmed the composite formation, while scanning electron microscopy (SEM), dynamic light scattering (DLS), and energy-dispersive X-ray spectroscopy (EDX) was employed to investigate the particle size, particle morphology, and elemental analysis. SEM indicated the formation of particles with non-uniform shape and size distribution, while EDX confirmed the presence of Fe, Ti and oxygen in their elemental state. The surface effects were investigated by Fourier transform infrared radiation (FTIR) and impedance spectroscopy (IS) at room temperature. IS confirmed the co-existence of grains and grain boundaries. Thus, FTIR and IS analysis helped establish a correlation between enhanced surface activity and the synthesis route adopted. It was established that the surface activity was sensitive to the synthesis route adopted. The sample density, variation in grain size, and electrical resistivity were linked with surface defects, and these defects were related to temperature. The disorder and defects created trap centers at the sample’s surface, leading to adsorption of CO2 from the environment.