Synthesis of cyclic β-1,6-oligosaccharides from glucosamine monomers by electrochemical polyglycosylation

• Published in: Beilstein journal of organic chemistry Vol. 20; no. 1; pp. 1421 - 1427
• Main Authors: Rahman, Md Azadur, Endo, Hirofumi, Yamamoto, Takashi, Okushiba, Shoma, Sasaki, Norihiko, Nokami, Toshiki
• Format: Journal Article
• Language: English
• Published: Germany Beilstein-Institut 26.06.2024
• Subjects: Chemistry; cyclic oligosaccharide; electrochemical glycosylation; Full Research Paper; glucosamine; polyglycosylation; electrochemical glycosylation; glucosamine; polyglycosylation; cyclic oligosaccharide

The synthesis of protected precursors of cyclic β-1,6-oligoglucosamines from thioglycosides as monomers is performed by electrochemical polyglycosylation. The monomer with a 2,3-oxazolidinone protecting group afforded the cyclic disaccharide exclusively. Cyclic oligosaccharides up to the trisacchari...