Engineering Homochiral Metal-Organic Frameworks for Heterogeneous Asymmetric Catalysis and Enantioselective Separation
Owing to the potential applications in technological areas such as gas storage, catalysis, separation, sensing and nonlinear optics, tremendous efforts have been devoted to the development of porous metal‐organic frameworks (MOFs) over the past ten years. Homochiral porous MOFs are particularly attr...
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| Published in | Advanced materials (Weinheim) Vol. 22; no. 37; pp. 4112 - 4135 |
|---|---|
| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Weinheim
WILEY-VCH Verlag
01.10.2010
WILEY‐VCH Verlag |
| Subjects | |
| Online Access | Get full text |
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| Abstract | Owing to the potential applications in technological areas such as gas storage, catalysis, separation, sensing and nonlinear optics, tremendous efforts have been devoted to the development of porous metal‐organic frameworks (MOFs) over the past ten years. Homochiral porous MOFs are particularly attractive candidates as heterogeneous asymmetric catalysts and enantioselective adsorbents and separators for production of optically active organic compounds due to the lack of homochiral inorganic porous materials such as zeolites. In this review, we summarize the recent research progress in homochiral MOF materials, including their synthetic strategy, distinctive structural features and latest advances in asymmetric heterogeneous catalysis and enantioselective separation.
Homochiral porous metal‐organic frameworks (MOFs) are particularly attractive candidates as heterogeneous asymmetric catalysts and enantioselective adsorbents and separators for production of optically active organic compounds. This review summarizes the recent research progress in homochiral MOF materials, including their synthetic strategy, distinctive structural features and applications in enantioselective catalysis and separation. |
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| AbstractList | Owing to the potential applications in technological areas such as gas storage, catalysis, separation, sensing and nonlinear optics, tremendous efforts have been devoted to the development of porous metal‐organic frameworks (MOFs) over the past ten years. Homochiral porous MOFs are particularly attractive candidates as heterogeneous asymmetric catalysts and enantioselective adsorbents and separators for production of optically active organic compounds due to the lack of homochiral inorganic porous materials such as zeolites. In this review, we summarize the recent research progress in homochiral MOF materials, including their synthetic strategy, distinctive structural features and latest advances in asymmetric heterogeneous catalysis and enantioselective separation.
Homochiral porous metal‐organic frameworks (MOFs) are particularly attractive candidates as heterogeneous asymmetric catalysts and enantioselective adsorbents and separators for production of optically active organic compounds. This review summarizes the recent research progress in homochiral MOF materials, including their synthetic strategy, distinctive structural features and applications in enantioselective catalysis and separation. Owing to the potential applications in technological areas such as gas storage, catalysis, separation, sensing and nonlinear optics, tremendous efforts have been devoted to the development of porous metal-organic frameworks (MOFs) over the past ten years. Homochiral porous MOFs are particularly attractive candidates as heterogeneous asymmetric catalysts and enantioselective adsorbents and separators for production of optically active organic compounds due to the lack of homochiral inorganic porous materials such as zeolites. In this review, we summarize the recent research progress in homochiral MOF materials, including their synthetic strategy, distinctive structural features and latest advances in asymmetric heterogeneous catalysis and enantioselective separation. Owing to the potential applications in technological areas such as gas storage, catalysis, separation, sensing and nonlinear optics, tremendous efforts have been devoted to the development of porous metal-organic frameworks (MOFs) over the past ten years. Homochiral porous MOFs are particularly attractive candidates as heterogeneous asymmetric catalysts and enantioselective adsorbents and separators for production of optically active organic compounds due to the lack of homochiral inorganic porous materials such as zeolites. In this review, we summarize the recent research progress in homochiral MOF materials, including their synthetic strategy, distinctive structural features and latest advances in asymmetric heterogeneous catalysis and enantioselective separation.Owing to the potential applications in technological areas such as gas storage, catalysis, separation, sensing and nonlinear optics, tremendous efforts have been devoted to the development of porous metal-organic frameworks (MOFs) over the past ten years. Homochiral porous MOFs are particularly attractive candidates as heterogeneous asymmetric catalysts and enantioselective adsorbents and separators for production of optically active organic compounds due to the lack of homochiral inorganic porous materials such as zeolites. In this review, we summarize the recent research progress in homochiral MOF materials, including their synthetic strategy, distinctive structural features and latest advances in asymmetric heterogeneous catalysis and enantioselective separation. |
| Author | Liu, Yan Cui, Yong Xuan, Weimin |
| Author_xml | – sequence: 1 givenname: Yan surname: Liu fullname: Liu, Yan organization: School of Chemistry and Chemical Technology and State Key, Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, 800 Dongchuan Rd, Shanghai 200240 (China) – sequence: 2 givenname: Weimin surname: Xuan fullname: Xuan, Weimin organization: School of Chemistry and Chemical Technology and State Key, Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, 800 Dongchuan Rd, Shanghai 200240 (China) – sequence: 3 givenname: Yong surname: Cui fullname: Cui, Yong email: yongcui@sjtu.edu.cn organization: School of Chemistry and Chemical Technology and State Key, Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, 800 Dongchuan Rd, Shanghai 200240 (China) |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/20799372$$D View this record in MEDLINE/PubMed |
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| Snippet | Owing to the potential applications in technological areas such as gas storage, catalysis, separation, sensing and nonlinear optics, tremendous efforts have... |
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| SubjectTerms | Biomimetics Catalysis Chirality Crystallization Enantioselectivity Metal-organic frameworks Metals - chemistry Organic Chemicals - chemistry Porosity Separation Stereoisomerism |
| Title | Engineering Homochiral Metal-Organic Frameworks for Heterogeneous Asymmetric Catalysis and Enantioselective Separation |
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