Advanced Organic Optoelectronic Materials: Harnessing Excited-State Intramolecular Proton Transfer (ESIPT) Process

Recently, organic fluorescent molecules harnessing the excited‐state intramolecular proton transfer (ESIPT) process are drawing great attention due to their unique photophysical properties which facilitate novel optoelectronic applications. After a brief introduction to the ESIPT process and related...

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Published in	Advanced materials (Weinheim) Vol. 23; no. 32; pp. 3615 - 3642
Main Authors	Kwon, Ji Eon, Park, Soo Young
Format	Journal Article
Language	English
Published	Weinheim WILEY-VCH Verlag 23.08.2011 WILEY‐VCH Verlag
Subjects	Electronics excited-state intramolecular proton transfer fluorescence Fluorescent Dyes - chemistry imaging Materials Testing Molecular Structure Organic Chemicals - chemistry organic optoelectronics Protons Quantum Theory sensor Stereoisomerism
Online Access	Get full text
ISSN	0935-9648 1521-4095 1521-4095
DOI	10.1002/adma.201102046

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Abstract	Recently, organic fluorescent molecules harnessing the excited‐state intramolecular proton transfer (ESIPT) process are drawing great attention due to their unique photophysical properties which facilitate novel optoelectronic applications. After a brief introduction to the ESIPT process and related photophysical properties, molecular design strategies towards tailored emission are discussed in relation to their theoretical aspects. Subsequently, recent studies on advanced ESIPT molecules and their optoelectronic applications are surveyed, particularly focusing on chemical sensors, fluorescence imaging, proton transfer lasers, and organic light‐emitting diodes (OLEDs). Organic fluorescent molecules harnessing excited‐state intramolecular proton transfer (ESIPT) process are drawing great attention due to their unique and beneficial photophysical properties such as a large Stokes' shift, no self‐absorption, and easy population inversion of the keto form, which are attributed to its intrinsic four‐level photocycle scheme. Here, recent studies on advanced ESIPT molecules and their novel optoelectronic applications are reviewed.
AbstractList	Recently, organic fluorescent molecules harnessing the excited-state intramolecular proton transfer (ESIPT) process are drawing great attention due to their unique photophysical properties which facilitate novel optoelectronic applications. After a brief introduction to the ESIPT process and related photo-physical properties, molecular design strategies towards tailored emission are discussed in relation to their theoretical aspects. Subsequently, recent studies on advanced ESIPT molecules and their optoelectronic applications are surveyed, particularly focusing on chemical sensors, fluorescence imaging, proton transfer lasers, and organic light-emitting diodes (OLEDs). Recently, organic fluorescent molecules harnessing the excited‐state intramolecular proton transfer (ESIPT) process are drawing great attention due to their unique photophysical properties which facilitate novel optoelectronic applications. After a brief introduction to the ESIPT process and related photophysical properties, molecular design strategies towards tailored emission are discussed in relation to their theoretical aspects. Subsequently, recent studies on advanced ESIPT molecules and their optoelectronic applications are surveyed, particularly focusing on chemical sensors, fluorescence imaging, proton transfer lasers, and organic light‐emitting diodes (OLEDs). Organic fluorescent molecules harnessing excited‐state intramolecular proton transfer (ESIPT) process are drawing great attention due to their unique and beneficial photophysical properties such as a large Stokes' shift, no self‐absorption, and easy population inversion of the keto form, which are attributed to its intrinsic four‐level photocycle scheme. Here, recent studies on advanced ESIPT molecules and their novel optoelectronic applications are reviewed. Recently, organic fluorescent molecules harnessing the excited-state intramolecular proton transfer (ESIPT) process are drawing great attention due to their unique photophysical properties which facilitate novel optoelectronic applications. After a brief introduction to the ESIPT process and related photo-physical properties, molecular design strategies towards tailored emission are discussed in relation to their theoretical aspects. Subsequently, recent studies on advanced ESIPT molecules and their optoelectronic applications are surveyed, particularly focusing on chemical sensors, fluorescence imaging, proton transfer lasers, and organic light-emitting diodes (OLEDs).Recently, organic fluorescent molecules harnessing the excited-state intramolecular proton transfer (ESIPT) process are drawing great attention due to their unique photophysical properties which facilitate novel optoelectronic applications. After a brief introduction to the ESIPT process and related photo-physical properties, molecular design strategies towards tailored emission are discussed in relation to their theoretical aspects. Subsequently, recent studies on advanced ESIPT molecules and their optoelectronic applications are surveyed, particularly focusing on chemical sensors, fluorescence imaging, proton transfer lasers, and organic light-emitting diodes (OLEDs). Recently, organic fluorescent molecules harnessing the excited‐state intramolecular proton transfer (ESIPT) process are drawing great attention due to their unique photophysical properties which facilitate novel optoelectronic applications. After a brief introduction to the ESIPT process and related photophysical properties, molecular design strategies towards tailored emission are discussed in relation to their theoretical aspects. Subsequently, recent studies on advanced ESIPT molecules and their optoelectronic applications are surveyed, particularly focusing on chemical sensors, fluorescence imaging, proton transfer lasers, and organic light‐emitting diodes (OLEDs).
Author	Kwon, Ji Eon Park, Soo Young
Author_xml	– sequence: 1 givenname: Ji Eon surname: Kwon fullname: Kwon, Ji Eon organization: Creative Research Initiative Center for Supramolecular Optoelectronic, Materials and WCU Hybrid Materials Program, Department of Materials Science and Engineering, Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul 151-744, Korea – sequence: 2 givenname: Soo Young surname: Park fullname: Park, Soo Young email: parksy@snu.ac.kr organization: Creative Research Initiative Center for Supramolecular Optoelectronic, Materials and WCU Hybrid Materials Program, Department of Materials Science and Engineering, Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul 151-744, Korea
BackLink	https://www.ncbi.nlm.nih.gov/pubmed/21780312$$D View this record in MEDLINE/PubMed
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Snippet	Recently, organic fluorescent molecules harnessing the excited‐state intramolecular proton transfer (ESIPT) process are drawing great attention due to their... Recently, organic fluorescent molecules harnessing the excited-state intramolecular proton transfer (ESIPT) process are drawing great attention due to their...
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SubjectTerms	Electronics excited-state intramolecular proton transfer fluorescence Fluorescent Dyes - chemistry imaging Materials Testing Molecular Structure Organic Chemicals - chemistry organic optoelectronics Protons Quantum Theory sensor Stereoisomerism
Title	Advanced Organic Optoelectronic Materials: Harnessing Excited-State Intramolecular Proton Transfer (ESIPT) Process
URI	https://api.istex.fr/ark:/67375/WNG-LK5VF573-W/fulltext.pdf https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fadma.201102046 https://www.ncbi.nlm.nih.gov/pubmed/21780312 https://www.proquest.com/docview/883309848
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