Enthalpy and Entropy Barriers Explain the Effects of Topology on the Kinetics of Zeolite-Catalyzed Reactions

• Published in: Chemistry : a European journal Vol. 19; no. 35; pp. 11568 - 11576
• Main Authors: Van der Mynsbrugge, Jeroen, De Ridder, Jeroen, Hemelsoet, Karen, Waroquier, Michel, Van Speybroeck, Veronique
• Format: Journal Article
• Language: English
• Published: Weinheim WILEY-VCH Verlag 26.08.2013; WILEY‐VCH Verlag; Wiley Subscription Services, Inc
• Subjects: ab initio calculations; chemical kinetics; Chemistry; density functional calculations; Entropy; methylation; Topology; X-rays; Zeolites; density functional calculations; ab initio calculations; chemical kinetics; zeolites; methylation
• DOI: 10.1002/chem.201301272
• ISSN: 0947-6539

The methylation of ethene, propene, and trans‐2‐butene on zeolites H‐ZSM‐58 (DDR), H‐ZSM‐22 (TON), and H‐ZSM‐5 (MFI) is studied to elucidate the particular influence of topology on the kinetics of zeolite‐catalyzed reactions. H‐ZSM‐58 and H‐ZSM‐22 are found to display overall lower methylation rates compared to H‐ZSM‐5 and also different trends in methylation rates with increasing alkene size. These variations may be rationalized based on a decomposition of the free‐energy barriers into enthalpic and entropic contributions, which reveals that the lower methylation rates on H‐ZSM‐58 and H‐ZSM‐22 have virtually opposite reasons. On H‐ZSM‐58, the lower methylation rates are caused by higher enthalpy barriers, owing to inefficient stabilization of the reaction intermediates in the large cage‐like pores. On the other hand, on H‐ZSM‐22, the methylation rates mostly suffer from higher entropy barriers, because excessive entropy losses are incurred inside the narrow‐channel structure. These results show that the kinetics of crucial elementary steps hinge on the balance between proper stabilization of the reaction intermediates inside the zeolite pores and the resulting entropy losses. These fundamental insights into their inner workings are indispensable for ultimately selecting or designing better zeolite catalysts. Breaking it down: The methylation of ethene, propene, and trans‐2‐butene on zeolites H‐ZSM‐58 (DDR), H‐ZSM‐22 (TON), and H‐ZSM‐5 (MFI) was studied to elucidate the influence of topology on the kinetics of zeolite‐catalyzed reactions. Analysis of the free‐energy barriers revealed that methylation rates are determined by the interplay between the stabilization of reaction intermediates inside the zeolite pores and the resulting entropy losses.