Aura of Corroles
Corroles display distinctive structural, spectroscopic, and photophysical properties, as well as some exceptional chemical reactivities that are not shared by other molecules. In addition, low‐valent metal complexes are extremely reactive when chelated by corroles and the opposite holds for the high...
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Published in | Chemistry : a European journal Vol. 15; no. 34; pp. 8382 - 8394 |
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Main Authors | , |
Format | Journal Article |
Language | English |
Published |
Weinheim
WILEY-VCH Verlag
24.08.2009
WILEY‐VCH Verlag |
Subjects | |
Online Access | Get full text |
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Abstract | Corroles display distinctive structural, spectroscopic, and photophysical properties, as well as some exceptional chemical reactivities that are not shared by other molecules. In addition, low‐valent metal complexes are extremely reactive when chelated by corroles and the opposite holds for the high‐valent counterparts. One aim of this account is to provide a thorough understanding of the underlying principles that govern these phenomena, while the other goal is to demonstrate how these features may be used advantageously for utilization of corroles and their corresponding metal complexes in applications for which they could display superior performances. The main examples that are emphasized regarding the above respect are catalysis, imaging, and aspects relevant to drug development.
From fundamental to applied chemistry: The distinctive structural, spectroscopic, and photophysical properties, as well as the exceptional chemical reactivities of corroles, are highlighted in the context of their utilization for advanced applications in catalysis, whole animal imaging, and the development of new drug candidates for various diseases (see scheme). |
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AbstractList | Corroles display distinctive structural, spectroscopic, and photophysical properties, as well as some exceptional chemical reactivities that are not shared by other molecules. In addition, low‐valent metal complexes are extremely reactive when chelated by corroles and the opposite holds for the high‐valent counterparts. One aim of this account is to provide a thorough understanding of the underlying principles that govern these phenomena, while the other goal is to demonstrate how these features may be used advantageously for utilization of corroles and their corresponding metal complexes in applications for which they could display superior performances. The main examples that are emphasized regarding the above respect are catalysis, imaging, and aspects relevant to drug development.
From fundamental to applied chemistry: The distinctive structural, spectroscopic, and photophysical properties, as well as the exceptional chemical reactivities of corroles, are highlighted in the context of their utilization for advanced applications in catalysis, whole animal imaging, and the development of new drug candidates for various diseases (see scheme). Abstract Corroles display distinctive structural, spectroscopic, and photophysical properties, as well as some exceptional chemical reactivities that are not shared by other molecules. In addition, low‐valent metal complexes are extremely reactive when chelated by corroles and the opposite holds for the high‐valent counterparts. One aim of this account is to provide a thorough understanding of the underlying principles that govern these phenomena, while the other goal is to demonstrate how these features may be used advantageously for utilization of corroles and their corresponding metal complexes in applications for which they could display superior performances. The main examples that are emphasized regarding the above respect are catalysis, imaging, and aspects relevant to drug development. Corroles display distinctive structural, spectroscopic, and photophysical properties, as well as some exceptional chemical reactivities that are not shared by other molecules. In addition, low-valent metal complexes are extremely reactive when chelated by corroles and the opposite holds for the high-valent counterparts. One aim of this account is to provide a thorough understanding of the underlying principles that govern these phenomena, while the other goal is to demonstrate how these features may be used advantageously for utilization of corroles and their corresponding metal complexes in applications for which they could display superior performances. The main examples that are emphasized regarding the above respect are catalysis, imaging, and aspects relevant to drug development. |
Author | Gross, Zeev Aviv-Harel, Iris |
Author_xml | – sequence: 1 givenname: Iris surname: Aviv-Harel fullname: Aviv-Harel, Iris organization: Schulich Faculty of Chemistry, Technion-Israel Institute of Technology, Haifa 32000 (Israel), Fax: (+972) 4829-5703 – sequence: 2 givenname: Zeev surname: Gross fullname: Gross, Zeev email: chr10zg@tx.technion.ac.il organization: Schulich Faculty of Chemistry, Technion-Israel Institute of Technology, Haifa 32000 (Israel), Fax: (+972) 4829-5703 |
BackLink | https://www.ncbi.nlm.nih.gov/pubmed/19630016$$D View this record in MEDLINE/PubMed |
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Snippet | Corroles display distinctive structural, spectroscopic, and photophysical properties, as well as some exceptional chemical reactivities that are not shared by... Abstract Corroles display distinctive structural, spectroscopic, and photophysical properties, as well as some exceptional chemical reactivities that are not... |
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SubjectTerms | atherosclerosis cancer Catalysis Cobalt - chemistry corroles Crystallography, X-Ray fluorescence Fluorescent Dyes Metalloporphyrins - chemistry Molecular Structure Porphyrins Spectrum Analysis Vitamin B 12 - chemistry |
Title | Aura of Corroles |
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