Hybrid Perovskite Thin‐Film Photovoltaics: In Situ Diagnostics and Importance of the Precursor Solvate Phases

Solution‐processed hybrid perovskite semiconductors attract a great deal of attention, but little is known about their formation process. The one‐step spin‐coating process of perovskites is investigated in situ, revealing that thin‐film formation is mediated by solid‐state precursor solvates and the...

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Published in	Advanced materials (Weinheim) Vol. 29; no. 2; pp. np - n/a
Main Authors	Munir, Rahim, Sheikh, Arif D., Abdelsamie, Maged, Hu, Hanlin, Yu, Liyang, Zhao, Kui, Kim, Taesoo, Tall, Omar El, Li, Ruipeng, Smilgies, Detlef‐M., Amassian, Aram
Format	Journal Article
Language	English
Published	Germany Wiley Subscription Services, Inc 01.01.2017
Subjects	Formations hybrid organic–inorganic perovskite solar cells in situ diagnostics Perovskites Phases Photovoltaic cells Precursors Reproducibility Semiconductors Solar cells solution processing solvates Thin films in situ diagnostics solution processing hybrid organic-inorganic perovskite solar cells solvates precursors
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Abstract	Solution‐processed hybrid perovskite semiconductors attract a great deal of attention, but little is known about their formation process. The one‐step spin‐coating process of perovskites is investigated in situ, revealing that thin‐film formation is mediated by solid‐state precursor solvates and their nature. The stability of these intermediate phases directly impacts the quality and reproducibility of thermally converted perovskite films and their photovoltaic performance.
AbstractList	Solution-processed hybrid perovskite semiconductors attract a great deal of attention, but little is known about their formation process. The one-step spin-coating process of perovskites is investigated in situ, revealing that thin-film formation is mediated by solid-state precursor solvates and their nature. The stability of these intermediate phases directly impacts the quality and reproducibility of thermally converted perovskite films and their photovoltaic performance.
Author	Abdelsamie, Maged Tall, Omar El Smilgies, Detlef‐M. Munir, Rahim Yu, Liyang Zhao, Kui Kim, Taesoo Sheikh, Arif D. Hu, Hanlin Li, Ruipeng Amassian, Aram
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BackLink	https://www.ncbi.nlm.nih.gov/pubmed/28066984$$D View this record in MEDLINE/PubMed
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Snippet	Solution‐processed hybrid perovskite semiconductors attract a great deal of attention, but little is known about their formation process. The one‐step... Solution-processed hybrid perovskite semiconductors attract a great deal of attention, but little is known about their formation process. The one-step...
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SubjectTerms	Formations hybrid organic–inorganic perovskite solar cells in situ diagnostics Perovskites Phases Photovoltaic cells Precursors Reproducibility Semiconductors Solar cells solution processing solvates Thin films
Title	Hybrid Perovskite Thin‐Film Photovoltaics: In Situ Diagnostics and Importance of the Precursor Solvate Phases
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