Mechanistically Significant Details of the H/D Exchange Reactions of Propene over Acidic Zeolite Catalysts
Quid pro quo: Hydrogen–deuterium exchange of propene on solid acid catalysts was studied at 573 and 673 K with a reaction time of 3 s (see scheme). At low partial pressures and temperatures, H/D exchange produced [D5]propene as the main product. Complete deuteration ([D6]propene) was observed only a...
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| Published in | Angewandte Chemie International Edition Vol. 45; no. 12; pp. 1933 - 1935 |
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| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
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Weinheim
WILEY-VCH Verlag
13.03.2006
WILEY‐VCH Verlag |
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| Abstract | Quid pro quo: Hydrogen–deuterium exchange of propene on solid acid catalysts was studied at 573 and 673 K with a reaction time of 3 s (see scheme). At low partial pressures and temperatures, H/D exchange produced [D5]propene as the main product. Complete deuteration ([D6]propene) was observed only at a higher temperature with the most acidic catalyst. |
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| AbstractList | Quid pro quo: Hydrogen–deuterium exchange of propene on solid acid catalysts was studied at 573 and 673 K with a reaction time of 3 s (see scheme). At low partial pressures and temperatures, H/D exchange produced [D5]propene as the main product. Complete deuteration ([D6]propene) was observed only at a higher temperature with the most acidic catalyst. |
| Author | Kletnieks, Philip W. Blau, Yoni M. Hayman, Miranda J. Guenther, Darryl R. Haw, James F. Marcus, David M. Ehresmann, Justin O. |
| Author_xml | – sequence: 1 givenname: David M. surname: Marcus fullname: Marcus, David M. organization: Department of Chemistry, University of Southern California, Los Angeles, CA 90089-1661, USA, Fax: (+1) 213-740-0930 – sequence: 2 givenname: Miranda J. surname: Hayman fullname: Hayman, Miranda J. organization: Department of Chemistry, University of Southern California, Los Angeles, CA 90089-1661, USA, Fax: (+1) 213-740-0930 – sequence: 3 givenname: Yoni M. surname: Blau fullname: Blau, Yoni M. organization: Department of Chemistry, University of Southern California, Los Angeles, CA 90089-1661, USA, Fax: (+1) 213-740-0930 – sequence: 4 givenname: Darryl R. surname: Guenther fullname: Guenther, Darryl R. organization: Department of Chemistry, University of Southern California, Los Angeles, CA 90089-1661, USA, Fax: (+1) 213-740-0930 – sequence: 5 givenname: Justin O. surname: Ehresmann fullname: Ehresmann, Justin O. organization: Department of Chemistry, University of Southern California, Los Angeles, CA 90089-1661, USA, Fax: (+1) 213-740-0930 – sequence: 6 givenname: Philip W. surname: Kletnieks fullname: Kletnieks, Philip W. organization: Department of Chemistry, University of Southern California, Los Angeles, CA 90089-1661, USA, Fax: (+1) 213-740-0930 – sequence: 7 givenname: James F. surname: Haw fullname: Haw, James F. email: jhaw@usc.edu organization: Department of Chemistry, University of Southern California, Los Angeles, CA 90089-1661, USA, Fax: (+1) 213-740-0930 |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/16506299$$D View this record in MEDLINE/PubMed |
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| Notes | This work was supported by the US Department of Energy (DOE) Office of Basic Energy Sciences (BES; grant no. DE-FG03-99ER14956). ArticleID:ANIE200503471 ark:/67375/WNG-6Q1B3MNJ-Q istex:EF36AAF77FD283D61EDAE34D21E0D33BCA1347D6 This work was supported by the US Department of Energy (DOE) Office of Basic Energy Sciences (BES; grant no. DE‐FG03‐99ER14956). ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
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| Snippet | Quid pro quo: Hydrogen–deuterium exchange of propene on solid acid catalysts was studied at 573 and 673 K with a reaction time of 3 s (see scheme). At low... |
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| SubjectTerms | heterogeneous catalysis isotopic labeling microporous materials oligomerization zeolites |
| Title | Mechanistically Significant Details of the H/D Exchange Reactions of Propene over Acidic Zeolite Catalysts |
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