Molecularly‐Engineered, 4D‐Printed Liquid Crystal Elastomer Actuators
Three‐dimensional structures that undergo reversible shape changes in response to mild stimuli enable a wide range of smart devices, such as soft robots or implantable medical devices. Herein, a dual thiol‐ene reaction scheme is used to synthesize a class of liquid crystal (LC) elastomers that can b...
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| Published in | Advanced functional materials Vol. 29; no. 3 |
|---|---|
| Main Authors | , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Hoboken
Wiley Subscription Services, Inc
17.01.2019
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| Subjects | |
| Online Access | Get full text |
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| Abstract | Three‐dimensional structures that undergo reversible shape changes in response to mild stimuli enable a wide range of smart devices, such as soft robots or implantable medical devices. Herein, a dual thiol‐ene reaction scheme is used to synthesize a class of liquid crystal (LC) elastomers that can be 3D printed into complex shapes and subsequently undergo controlled shape change. Through controlling the phase transition temperature of polymerizable LC inks, morphing 3D structures with tunable actuation temperature (28 ± 2 to 105 ± 1 °C) are fabricated. Finally, multiple LC inks are 3D printed into single structures to allow for the production of untethered, thermo‐responsive structures that sequentially and reversibly undergo multiple shape changes.
Novel inks for printable liquid crystal elastomers (LCEs) are reported herein. The 3D‐printed LCE structures undergo controlled and reversible shape change upon heating. By controlling the reaction parameters (e.g., reaction type, mesogen concentration, or crosslinking density), a wide range of LCEs are synthesized and characterized for their use as soft actuators. |
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| AbstractList | Three‐dimensional structures that undergo reversible shape changes in response to mild stimuli enable a wide range of smart devices, such as soft robots or implantable medical devices. Herein, a dual thiol‐ene reaction scheme is used to synthesize a class of liquid crystal (LC) elastomers that can be 3D printed into complex shapes and subsequently undergo controlled shape change. Through controlling the phase transition temperature of polymerizable LC inks, morphing 3D structures with tunable actuation temperature (28 ± 2 to 105 ± 1 °C) are fabricated. Finally, multiple LC inks are 3D printed into single structures to allow for the production of untethered, thermo‐responsive structures that sequentially and reversibly undergo multiple shape changes. Three‐dimensional structures that undergo reversible shape changes in response to mild stimuli enable a wide range of smart devices, such as soft robots or implantable medical devices. Herein, a dual thiol‐ene reaction scheme is used to synthesize a class of liquid crystal (LC) elastomers that can be 3D printed into complex shapes and subsequently undergo controlled shape change. Through controlling the phase transition temperature of polymerizable LC inks, morphing 3D structures with tunable actuation temperature (28 ± 2 to 105 ± 1 °C) are fabricated. Finally, multiple LC inks are 3D printed into single structures to allow for the production of untethered, thermo‐responsive structures that sequentially and reversibly undergo multiple shape changes. Novel inks for printable liquid crystal elastomers (LCEs) are reported herein. The 3D‐printed LCE structures undergo controlled and reversible shape change upon heating. By controlling the reaction parameters (e.g., reaction type, mesogen concentration, or crosslinking density), a wide range of LCEs are synthesized and characterized for their use as soft actuators. |
| Author | Stefan, Mihaela C. Ambulo, Cedric P. Shankar, M. Ravi Raval, Vyom Kim, Hyun De, Rohit Cue, John Michael O. Ware, Taylor H. Searles, Kyle Saed, Mohand O. Siddiqui, Danyal A. |
| Author_xml | – sequence: 1 givenname: Mohand O. orcidid: 0000-0001-5154-6378 surname: Saed fullname: Saed, Mohand O. organization: University of Texas at Dallas – sequence: 2 givenname: Cedric P. surname: Ambulo fullname: Ambulo, Cedric P. organization: University of Texas at Dallas – sequence: 3 givenname: Hyun surname: Kim fullname: Kim, Hyun organization: University of Texas at Dallas – sequence: 4 givenname: Rohit surname: De fullname: De, Rohit organization: University of Texas at Dallas – sequence: 5 givenname: Vyom surname: Raval fullname: Raval, Vyom organization: University of Texas at Dallas – sequence: 6 givenname: Kyle surname: Searles fullname: Searles, Kyle organization: University of Texas at Dallas – sequence: 7 givenname: Danyal A. surname: Siddiqui fullname: Siddiqui, Danyal A. organization: University of Texas at Dallas – sequence: 8 givenname: John Michael O. surname: Cue fullname: Cue, John Michael O. organization: University of Texas at Dallas – sequence: 9 givenname: Mihaela C. surname: Stefan fullname: Stefan, Mihaela C. organization: University of Texas at Dallas – sequence: 10 givenname: M. Ravi surname: Shankar fullname: Shankar, M. Ravi organization: University of Pittsburgh – sequence: 11 givenname: Taylor H. orcidid: 0000-0001-7996-7393 surname: Ware fullname: Ware, Taylor H. email: Taylor.ware@utdallas.edu organization: University of Texas at Dallas |
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| SubjectTerms | 4D printing Actuation actuators Chemical synthesis Crystal structure Crystals Elastomers Inks liquid crystal elastomers Liquid crystals Materials science Medical devices Medical electronics Medical equipment Morphing multi‐materials printing Phase transitions soft robots Three dimensional printing Transition temperature |
| Title | Molecularly‐Engineered, 4D‐Printed Liquid Crystal Elastomer Actuators |
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