Hydrogen generated from hydrolysis of ammonia borane using cobalt and ruthenium based catalysts
Ammonia borane (NH 3BH 3, AB), one kind of promising hydrogen storage materials, is hydrolyzed to produce hydrogen in presence of HCl, Co/IR-120 and Ru/IR-120 catalysts. The kinetics analysis of the AB hydrolysis shows that hydrogen production is of the first-order reaction in regard to both concent...
Saved in:
| Published in | International journal of hydrogen energy Vol. 37; no. 3; pp. 2950 - 2959 |
|---|---|
| Main Authors | , , , , , , |
| Format | Journal Article Conference Proceeding |
| Language | English |
| Published |
Kidlington
Elsevier Ltd
01.02.2012
Elsevier |
| Subjects | |
| Online Access | Get full text |
Cover
Loading…
| Abstract | Ammonia borane (NH
3BH
3, AB), one kind of promising hydrogen storage materials, is hydrolyzed to produce hydrogen in presence of HCl, Co/IR-120 and Ru/IR-120 catalysts. The kinetics analysis of the AB hydrolysis shows that hydrogen production is of the first-order reaction in regard to both concentrations of ammonia borane and catalysts initially present, respectively. The hydrolyzate of ammonia borane after hydrogen evolution is also characterized with XRD, FT-IR and
11B NMR. Boric acid (H
3BO
3) is found to be the dominant product in the hydrolyzate. Besides, the produced gas is discovered to contain both hydrogen and ammonia according to the GC–MS analysis and the indophenol colorimetric analysis. A possible reaction pathway on hydrogen generation from hydrolysis of ammonia borane is, accordingly, proposed based on the existence of boric acid, hydrogen and ammonia in the products. The total life cycle of ammonia borane is also proposed to illustrate formation of different intermediates during the AB hydrolysis for hydrogen generation and a possible regeneration scheme of the spent ammonia borane.
► Hydrogen is produced from hydrolysis of ammonia borane in presence of light-weight Co or Ru catalysts. ► The hydrolysis reaction of ammonia borane is of the first-order in concentrations of ammonia borane and catalysts. ► Ammonia is conjointly produced with hydrogen from hydrolysis of ammonia borane, and can be reduced with proper management of exothermic reaction heat. ► Boric acid is the major hydrolyzate of ammonia borane for hydrogen evolution. |
|---|---|
| AbstractList | Ammonia borane (NH
3BH
3, AB), one kind of promising hydrogen storage materials, is hydrolyzed to produce hydrogen in presence of HCl, Co/IR-120 and Ru/IR-120 catalysts. The kinetics analysis of the AB hydrolysis shows that hydrogen production is of the first-order reaction in regard to both concentrations of ammonia borane and catalysts initially present, respectively. The hydrolyzate of ammonia borane after hydrogen evolution is also characterized with XRD, FT-IR and
11B NMR. Boric acid (H
3BO
3) is found to be the dominant product in the hydrolyzate. Besides, the produced gas is discovered to contain both hydrogen and ammonia according to the GC–MS analysis and the indophenol colorimetric analysis. A possible reaction pathway on hydrogen generation from hydrolysis of ammonia borane is, accordingly, proposed based on the existence of boric acid, hydrogen and ammonia in the products. The total life cycle of ammonia borane is also proposed to illustrate formation of different intermediates during the AB hydrolysis for hydrogen generation and a possible regeneration scheme of the spent ammonia borane.
► Hydrogen is produced from hydrolysis of ammonia borane in presence of light-weight Co or Ru catalysts. ► The hydrolysis reaction of ammonia borane is of the first-order in concentrations of ammonia borane and catalysts. ► Ammonia is conjointly produced with hydrogen from hydrolysis of ammonia borane, and can be reduced with proper management of exothermic reaction heat. ► Boric acid is the major hydrolyzate of ammonia borane for hydrogen evolution. Ammonia borane (NH3BH3, AB), one kind of promising hydrogen storage materials, is hydrolyzed to produce hydrogen in presence of HCl, Co/IR-120 and Ru/IR-120 catalysts. The kinetics analysis of the AB hydrolysis shows that hydrogen production is of the first-order reaction in regard to both concentrations of ammonia borane and catalysts initially present, respectively. The hydrolyzate of ammonia borane after hydrogen evolution is also characterized with XRD, FT-IR and 11B NMR. Boric acid (H3BO3) is found to be the dominant product in the hydrolyzate. Besides, the produced gas is discovered to contain both hydrogen and ammonia according to the GC-MS analysis and the indophenol colorimetric analysis. A possible reaction pathway on hydrogen generation from hydrolysis of ammonia borane is, accordingly, proposed based on the existence of boric acid, hydrogen and ammonia in the products. The total life cycle of ammonia borane is also proposed to illustrate formation of different intermediates during the AB hydrolysis for hydrogen generation and a possible regeneration scheme of the spent ammonia borane. |
| Author | Tsau, Fanghei Liu, Cheng-Hong Chen, Bing-Hung Wu, Yi-Chun Chou, Chang-Cheng Hsueh, Chan-Li Ku, Jie-Ren |
| Author_xml | – sequence: 1 givenname: Cheng-Hong surname: Liu fullname: Liu, Cheng-Hong organization: Department of Chemical Engineering, National Cheng Kung University, 1 University Road, Tainan 70101, Taiwan – sequence: 2 givenname: Yi-Chun surname: Wu fullname: Wu, Yi-Chun organization: Department of Chemical Engineering, National Cheng Kung University, 1 University Road, Tainan 70101, Taiwan – sequence: 3 givenname: Chang-Cheng surname: Chou fullname: Chou, Chang-Cheng organization: Department of Chemical Engineering, National Cheng Kung University, 1 University Road, Tainan 70101, Taiwan – sequence: 4 givenname: Bing-Hung surname: Chen fullname: Chen, Bing-Hung email: bhchen@alumni.rice.edu organization: Department of Chemical Engineering, National Cheng Kung University, 1 University Road, Tainan 70101, Taiwan – sequence: 5 givenname: Chan-Li surname: Hsueh fullname: Hsueh, Chan-Li organization: New Energy Technology Division, Green Energy and Environment Research Laboratories, Industrial Technology Research Institute (ITRI), Hsinchu County 31040, Taiwan – sequence: 6 givenname: Jie-Ren surname: Ku fullname: Ku, Jie-Ren organization: New Energy Technology Division, Green Energy and Environment Research Laboratories, Industrial Technology Research Institute (ITRI), Hsinchu County 31040, Taiwan – sequence: 7 givenname: Fanghei surname: Tsau fullname: Tsau, Fanghei organization: New Energy Technology Division, Green Energy and Environment Research Laboratories, Industrial Technology Research Institute (ITRI), Hsinchu County 31040, Taiwan |
| BackLink | http://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=25466800$$DView record in Pascal Francis |
| BookMark | eNqFkMFK5TAUhsOg4NXxFSSbATft5LRpmu5GRMcBwY2zDqfpqTeXNnGSVrhvby5XZ-siHAjff_7Dd85OfPDE2BWIEgSon7vS7bb7gTyVlQAoRVOKqvrGNqDbrqilbk_YRtRKFDV03Rk7T2knBLRCdhtmHvZDDC_keX4UcaGBjzHMfHv4n_bJJR5GjvMcvEPeh4ie-Jqcf-E29DgtHP3A47psybt15j2mvMLigjm8pO_sdMQp0eXHvGB_7--ebx-Kx6fff25vHgsrZbMUI-Q7QekKtZDYSUlKtQNK1BZQjw1oO9TUYAUSlWqqBupa9ZKkkD0AYH3Bro97X2P4t1JazOySpWnK54Y1GWhVBXWbx9eogC7DnRYZVUfUxpBSpNG8Rjdj3GfowCmzM5_yzUG-EY3J8nPwx0cHJovTmK1Zl_6nq0YqpcWh4NeRo-zmzVE0yTrylgYXyS5mCO6rqnc9nZ-L |
| CODEN | IJHEDX |
| CitedBy_id | crossref_primary_10_1021_acssuschemeng_0c06696 crossref_primary_10_3389_fchem_2020_00604 crossref_primary_10_1016_j_ijhydene_2013_03_002 crossref_primary_10_3390_en13123071 crossref_primary_10_1016_S1452_3981_23_16230_4 crossref_primary_10_1039_D2CY01465C crossref_primary_10_1021_jp3032989 crossref_primary_10_1016_j_renene_2020_03_088 crossref_primary_10_1016_j_ijhydene_2012_03_164 crossref_primary_10_1021_acscatal_6b02209 crossref_primary_10_1002_ente_201402136 crossref_primary_10_1016_j_ijhydene_2014_04_214 crossref_primary_10_3390_ma8063456 crossref_primary_10_1016_j_jechem_2023_07_027 crossref_primary_10_1016_j_ijhydene_2020_08_131 crossref_primary_10_1016_j_ijhydene_2020_01_223 crossref_primary_10_1016_j_ijhydene_2014_11_052 crossref_primary_10_1039_D4YA00126E crossref_primary_10_1016_j_ijhydene_2016_09_088 crossref_primary_10_1016_j_ijhydene_2022_02_134 crossref_primary_10_1016_j_ijhydene_2013_04_121 crossref_primary_10_1016_j_apsusc_2016_06_118 crossref_primary_10_1016_j_jpowsour_2014_04_117 crossref_primary_10_1016_j_jpowsour_2015_05_091 crossref_primary_10_1021_cs300499d crossref_primary_10_1016_j_jallcom_2023_172369 crossref_primary_10_1039_D2NJ03334H crossref_primary_10_1134_S002315841466001X crossref_primary_10_1016_j_ijhydene_2016_07_163 crossref_primary_10_1016_j_joei_2017_10_004 crossref_primary_10_1039_D1CY01619A crossref_primary_10_1016_j_jallcom_2017_02_239 crossref_primary_10_1016_j_micromeso_2015_12_018 crossref_primary_10_1134_S0036024422090357 crossref_primary_10_1016_j_ensm_2020_01_010 crossref_primary_10_1063_5_0064881 crossref_primary_10_1039_C4RA12230E crossref_primary_10_1016_j_ijhydene_2012_05_108 crossref_primary_10_1007_s12274_014_0438_7 crossref_primary_10_1021_acs_energyfuels_3c01393 crossref_primary_10_1016_j_gee_2020_03_012 crossref_primary_10_3390_inorganics7080096 crossref_primary_10_1002_aic_15389 crossref_primary_10_1007_s10853_020_05493_7 crossref_primary_10_1016_j_ijhydene_2020_08_035 crossref_primary_10_1039_C6QI00518G crossref_primary_10_1016_j_egypro_2014_11_925 crossref_primary_10_1016_j_jclepro_2023_138297 crossref_primary_10_1039_D0CS00515K crossref_primary_10_1007_s11144_013_0569_y crossref_primary_10_1016_j_ijhydene_2013_03_153 crossref_primary_10_1007_s41779_021_00673_3 crossref_primary_10_1016_j_ijhydene_2017_01_154 crossref_primary_10_1002_ente_201700486 crossref_primary_10_3390_en14082199 crossref_primary_10_1039_C4EE03690E crossref_primary_10_1021_acsomega_7b02003 |
| Cites_doi | 10.1016/j.jpowsour.2006.12.012 10.1016/j.apcatb.2009.06.003 10.1016/j.jpowsour.2005.05.043 10.1016/j.ijhydene.2010.03.006 10.1021/je00041a029 10.1016/j.ijhydene.2009.01.002 10.1016/j.ijhydene.2010.06.021 10.1016/j.ijhydene.2009.03.003 10.1021/ja01097a056 10.1016/j.apcatb.2010.06.015 10.1016/j.jpowsour.2005.12.033 10.1016/j.ijhydene.2010.09.027 10.1021/ja01097a054 10.1021/ic700772a 10.1016/j.ijhydene.2009.06.074 10.1016/j.jpowsour.2007.11.096 10.1016/j.ijhydene.2010.04.093 10.1016/j.ijhydene.2009.01.038 10.1021/ie100520r 10.1016/j.jpowsour.2007.03.015 10.1016/S1359-0286(02)00108-0 10.1021/ie101309f |
| ContentType | Journal Article Conference Proceeding |
| Copyright | 2011 Hydrogen Energy Publications, LLC. 2015 INIST-CNRS |
| Copyright_xml | – notice: 2011 Hydrogen Energy Publications, LLC. – notice: 2015 INIST-CNRS |
| DBID | IQODW AAYXX CITATION 7SP 7SU 8FD C1K FR3 L7M |
| DOI | 10.1016/j.ijhydene.2011.05.022 |
| DatabaseName | Pascal-Francis CrossRef Electronics & Communications Abstracts Environmental Engineering Abstracts Technology Research Database Environmental Sciences and Pollution Management Engineering Research Database Advanced Technologies Database with Aerospace |
| DatabaseTitle | CrossRef Engineering Research Database Technology Research Database Advanced Technologies Database with Aerospace Electronics & Communications Abstracts Environmental Engineering Abstracts Environmental Sciences and Pollution Management |
| DatabaseTitleList | Engineering Research Database Engineering Research Database |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Engineering Applied Sciences |
| EISSN | 1879-3487 |
| EndPage | 2959 |
| ExternalDocumentID | 10_1016_j_ijhydene_2011_05_022 25466800 S0360319911011761 |
| GroupedDBID | --K --M .~1 0R~ 1B1 1~. 1~5 29J 4.4 457 4G. 5GY 5VS 7-5 71M 8P~ 9JN AABNK AABXZ AACTN AAEDT AAEDW AAHCO AAIAV AAIKJ AAKOC AALRI AAOAW AAQFI AAQXK AARJD AARLI AAXUO ABFNM ABJNI ABMAC ABXDB ABYKQ ACDAQ ACGFS ACNNM ACRLP ADBBV ADECG ADEZE ADMUD AEBSH AEKER AENEX AEZYN AFKWA AFRZQ AFTJW AFZHZ AGHFR AGUBO AGYEJ AHHHB AHIDL AIEXJ AIKHN AITUG AJBFU AJOXV AJSZI ALMA_UNASSIGNED_HOLDINGS AMFUW AMRAJ ASPBG AVWKF AXJTR AZFZN BELTK BKOJK BLXMC CS3 DU5 EBS EFJIC EFLBG EJD EO8 EO9 EP2 EP3 F5P FDB FEDTE FGOYB FIRID FLBIZ FNPLU FYGXN G-2 G-Q GBLVA HVGLF HZ~ IHE J1W JARJE KOM LY6 M41 MO0 N9A O-L O9- OAUVE OZT P-8 P-9 P2P PC. Q38 R2- RIG RNS ROL RPZ SAC SCB SCC SDF SDG SES SEW SPC SPCBC SSK SSM SSR SSZ T5K T9H TN5 WUQ XPP ZMT ~G- ABPIF ABPTK IQODW AAXKI AAYXX AFJKZ AKRWK CITATION 7SP 7SU 8FD C1K FR3 L7M |
| ID | FETCH-LOGICAL-c445t-f13481682a804a944e667da4a8c1a8f518cd3e5a214a665251336b4e404b111a3 |
| IEDL.DBID | AIKHN |
| ISSN | 0360-3199 |
| IngestDate | Fri Oct 25 10:57:07 EDT 2024 Thu Oct 24 22:46:55 EDT 2024 Thu Sep 26 17:36:15 EDT 2024 Sun Oct 22 16:05:22 EDT 2023 Fri Feb 23 02:20:14 EST 2024 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 3 |
| Keywords | Boric acid Ru/IR-120 Hydrogen generation Co/IR-120 Catalyst Ammonia borane |
| Language | English |
| License | CC BY 4.0 |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-c445t-f13481682a804a944e667da4a8c1a8f518cd3e5a214a665251336b4e404b111a3 |
| Notes | ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 23 ObjectType-Article-1 ObjectType-Feature-2 |
| PQID | 1019621980 |
| PQPubID | 23500 |
| PageCount | 10 |
| ParticipantIDs | proquest_miscellaneous_1762137176 proquest_miscellaneous_1019621980 crossref_primary_10_1016_j_ijhydene_2011_05_022 pascalfrancis_primary_25466800 elsevier_sciencedirect_doi_10_1016_j_ijhydene_2011_05_022 |
| PublicationCentury | 2000 |
| PublicationDate | 2012-02-01 |
| PublicationDateYYYYMMDD | 2012-02-01 |
| PublicationDate_xml | – month: 02 year: 2012 text: 2012-02-01 day: 01 |
| PublicationDecade | 2010 |
| PublicationPlace | Kidlington |
| PublicationPlace_xml | – name: Kidlington |
| PublicationTitle | International journal of hydrogen energy |
| PublicationYear | 2012 |
| Publisher | Elsevier Ltd Elsevier |
| Publisher_xml | – name: Elsevier Ltd – name: Elsevier |
| References | Sa, Silva, Brandao, Sousa, Mendes (bib3) 2010; 99 Chandra, Xu (bib6) 2006; 159 Umegaki, Yan, Zhang, Shioyama, Kuriyama, Xu (bib14) 2009; 34 Kuo, Pedram, Hines (bib21) 1985; 30 Rakap, Kalu, Ozkar (bib8) 2011; 36 Ramachandran, Gagare (bib16) 2007; 46 Demirci, Akdim, Miele (bib10) 2009; 34 Liu, Chen, Hsueh, Ku, Tsau, Hwang (bib22) 2009; 91 Schlesinger, Brown, Finholt (bib18) 1953; 75 Schlesinger, Brown, Mayfield, Gilbreath (bib23) 1953; 75 Ghenciu (bib5) 2002; 6 Chandra, Xu (bib11) 2006; 156 . Padilla, Benito, Rodriguez, Serrano, Munoz, Daza (bib2) 2010; 35 Kalidindi, Nethaji, Jagirdar (bib9) 2010; 35 Liu, Chen, Lee, Ku, Tsau (bib17) 2010; 49 Seo, Youn, Jung, Song (bib1) 2010; 35 Durap, Zahmakıran, Saim Özkar (bib7) 2009; 34 Chandra, Xu (bib12) 2007; 168 Hwang, Al-Kukhun, Varma (bib15) 2010; 49 Cheng, Shi, Glass, Zhang, Zhang, Song (bib4) 2007; 165 Umegaki, Yan, Zhang, Shioyama, Kuriyama, Xu (bib13) 2009; 34 Hsueh, Chen, Ku, Tsai, Hsu, Tsau (bib19) 2008; 177 Hwang (10.1016/j.ijhydene.2011.05.022_bib15) 2010; 49 Kalidindi (10.1016/j.ijhydene.2011.05.022_bib9) 2010; 35 10.1016/j.ijhydene.2011.05.022_bib20 Kuo (10.1016/j.ijhydene.2011.05.022_bib21) 1985; 30 Liu (10.1016/j.ijhydene.2011.05.022_bib22) 2009; 91 Chandra (10.1016/j.ijhydene.2011.05.022_bib12) 2007; 168 Chandra (10.1016/j.ijhydene.2011.05.022_bib6) 2006; 159 Demirci (10.1016/j.ijhydene.2011.05.022_bib10) 2009; 34 Durap (10.1016/j.ijhydene.2011.05.022_bib7) 2009; 34 Rakap (10.1016/j.ijhydene.2011.05.022_bib8) 2011; 36 Umegaki (10.1016/j.ijhydene.2011.05.022_bib13) 2009; 34 Cheng (10.1016/j.ijhydene.2011.05.022_bib4) 2007; 165 Chandra (10.1016/j.ijhydene.2011.05.022_bib11) 2006; 156 Hsueh (10.1016/j.ijhydene.2011.05.022_bib19) 2008; 177 Umegaki (10.1016/j.ijhydene.2011.05.022_bib14) 2009; 34 Seo (10.1016/j.ijhydene.2011.05.022_bib1) 2010; 35 Sa (10.1016/j.ijhydene.2011.05.022_bib3) 2010; 99 Schlesinger (10.1016/j.ijhydene.2011.05.022_bib18) 1953; 75 Ghenciu (10.1016/j.ijhydene.2011.05.022_bib5) 2002; 6 Padilla (10.1016/j.ijhydene.2011.05.022_bib2) 2010; 35 Liu (10.1016/j.ijhydene.2011.05.022_bib17) 2010; 49 Schlesinger (10.1016/j.ijhydene.2011.05.022_bib23) 1953; 75 Ramachandran (10.1016/j.ijhydene.2011.05.022_bib16) 2007; 46 |
| References_xml | – volume: 35 start-page: 6738 year: 2010 end-page: 6746 ident: bib1 article-title: Hydrogen production by steam reforming of liquefied natural gas (LNG) over mesoporous nickel-alumina aerogel catalyst publication-title: Int J Hydrogen Energy contributor: fullname: Song – volume: 75 start-page: 205 year: 1953 end-page: 209 ident: bib18 article-title: The preparation of sodium borohydride by the high temperature reaction of sodium hydride with borate esters publication-title: J Am Chem Soc contributor: fullname: Finholt – volume: 75 start-page: 213 year: 1953 end-page: 215 ident: bib23 article-title: Procedures for the preparation of methyl borate publication-title: J Am Chem Soc contributor: fullname: Gilbreath – volume: 36 start-page: 254 year: 2011 end-page: 261 ident: bib8 article-title: Hydrogen generation from the hydrolysis of ammonia borane using cobalt–nickel–phosphorus (Co–Ni–P) catalyst supported on Pd-activated TiO publication-title: Int J Hydrogen Energy contributor: fullname: Ozkar – volume: 156 start-page: 190 year: 2006 end-page: 194 ident: bib11 article-title: A high-performance hydrogen generation system: transition metal-catalyzed dissociation and hydrolysis of ammonia–borane publication-title: J Power Sources contributor: fullname: Xu – volume: 34 start-page: 3816 year: 2009 end-page: 3822 ident: bib14 article-title: Preparation and catalysis of poly(N-vinyl-2-pyrrolidone) (PVP) stabilized nickel catalyst for hydrolytic dehydrogenation of ammonia borane publication-title: Int J Hydrogen Energy contributor: fullname: Xu – volume: 168 start-page: 135 year: 2007 end-page: 142 ident: bib12 article-title: Room temperature hydrogen generation from aqueous ammonia–borane using noble metal nano-clusters as highly active catalysts publication-title: J Power Sources contributor: fullname: Xu – volume: 6 start-page: 389 year: 2002 end-page: 399 ident: bib5 article-title: Review of fuel processing catalysts for hydrogen production in PEM fuel cell systems publication-title: Curr Opin Solid State Mater Sci contributor: fullname: Ghenciu – volume: 159 start-page: 855 year: 2006 end-page: 860 ident: bib6 article-title: Dissociation and hydrolysis of ammonia–borane with solid acids and carbon dioxide: an efficient hydrogen generation system publication-title: J Power Sources contributor: fullname: Xu – volume: 99 start-page: 43 year: 2010 end-page: 57 ident: bib3 article-title: Catalysts for methanol steam reforming–a review publication-title: Appl Catal B Environ contributor: fullname: Mendes – volume: 34 start-page: 7223 year: 2009 end-page: 7230 ident: bib7 article-title: Water soluble laurate-stabilized ruthenium(0) nanoclusters catalyst for hydrogen generation from the hydrolysis of ammonia–borane: high activity and long lifetime publication-title: Int J Hydrogen Energy contributor: fullname: Saim Özkar – volume: 35 start-page: 8921 year: 2010 end-page: 8928 ident: bib2 article-title: Nickel and cobalt as active phase on supported zirconia catalysts for bio-ethanol reforming: influence of the reaction mechanism on catalysts performance publication-title: Int J Hydrogen Energy contributor: fullname: Daza – volume: 34 start-page: 2638 year: 2009 end-page: 2645 ident: bib10 article-title: Ten-year efforts and a no-go recommendation for sodium borohydride for on-board automotive hydrogen storage publication-title: Int J Hydrogen Energy contributor: fullname: Miele – volume: 34 start-page: 2303 year: 2009 end-page: 2311 ident: bib13 article-title: Boron- and nitrogen-based chemical hydrogen storage materials publication-title: Int J Hydrogen Energy contributor: fullname: Xu – volume: 49 start-page: 9864 year: 2010 end-page: 9869 ident: bib17 article-title: Trimethyl borate regenerated from spent sodium borohydride after hydrogen production publication-title: Ind Eng Chem Res contributor: fullname: Tsau – volume: 49 start-page: 10994 year: 2010 end-page: 11000 ident: bib15 article-title: Hydrogen for vehicle applications from hydrothermolysis of ammonia borane: hydrogen yield, thermal characteristics, and ammonia formation publication-title: Ind Eng Chem Res contributor: fullname: Varma – volume: 91 start-page: 368 year: 2009 end-page: 379 ident: bib22 article-title: Preparation of magnetic cobalt-based catalyst for hydrogen generation from alkaline NaBH publication-title: Appl Catal B Environ contributor: fullname: Hwang – volume: 177 start-page: 485 year: 2008 end-page: 492 ident: bib19 article-title: Simple and fast fabrication of polymer template-Ru composite as a catalyst for hydrogen generation from alkaline NaBH publication-title: J Power Sources contributor: fullname: Tsau – volume: 46 start-page: 7810 year: 2007 end-page: 7817 ident: bib16 article-title: Preparation of ammonia borane in high yield and purity, methanolysis publication-title: Inorg Chem contributor: fullname: Gagare – volume: 30 start-page: 330 year: 1985 end-page: 332 ident: bib21 article-title: Analysis of ammonia adsorption on silica gel using the modified potential theory publication-title: J Chem Eng Data contributor: fullname: Hines – volume: 165 start-page: 739 year: 2007 end-page: 756 ident: bib4 article-title: A review of PEM hydrogen fuel cell contamination: impacts, mechanisms, and mitigation publication-title: J Power Sources contributor: fullname: Song – volume: 35 start-page: 10819 year: 2010 end-page: 10825 ident: bib9 article-title: Dehydrogenation of ammonia borane in fluoro alcohols publication-title: Int J Hydrogen Energy contributor: fullname: Jagirdar – volume: 165 start-page: 739 year: 2007 ident: 10.1016/j.ijhydene.2011.05.022_bib4 article-title: A review of PEM hydrogen fuel cell contamination: impacts, mechanisms, and mitigation publication-title: J Power Sources doi: 10.1016/j.jpowsour.2006.12.012 contributor: fullname: Cheng – volume: 91 start-page: 368 year: 2009 ident: 10.1016/j.ijhydene.2011.05.022_bib22 article-title: Preparation of magnetic cobalt-based catalyst for hydrogen generation from alkaline NaBH4 solution publication-title: Appl Catal B Environ doi: 10.1016/j.apcatb.2009.06.003 contributor: fullname: Liu – volume: 156 start-page: 190 year: 2006 ident: 10.1016/j.ijhydene.2011.05.022_bib11 article-title: A high-performance hydrogen generation system: transition metal-catalyzed dissociation and hydrolysis of ammonia–borane publication-title: J Power Sources doi: 10.1016/j.jpowsour.2005.05.043 contributor: fullname: Chandra – volume: 35 start-page: 10819 year: 2010 ident: 10.1016/j.ijhydene.2011.05.022_bib9 article-title: Dehydrogenation of ammonia borane in fluoro alcohols publication-title: Int J Hydrogen Energy doi: 10.1016/j.ijhydene.2010.03.006 contributor: fullname: Kalidindi – volume: 30 start-page: 330 year: 1985 ident: 10.1016/j.ijhydene.2011.05.022_bib21 article-title: Analysis of ammonia adsorption on silica gel using the modified potential theory publication-title: J Chem Eng Data doi: 10.1021/je00041a029 contributor: fullname: Kuo – volume: 34 start-page: 2303 year: 2009 ident: 10.1016/j.ijhydene.2011.05.022_bib13 article-title: Boron- and nitrogen-based chemical hydrogen storage materials publication-title: Int J Hydrogen Energy doi: 10.1016/j.ijhydene.2009.01.002 contributor: fullname: Umegaki – ident: 10.1016/j.ijhydene.2011.05.022_bib20 – volume: 35 start-page: 8921 year: 2010 ident: 10.1016/j.ijhydene.2011.05.022_bib2 article-title: Nickel and cobalt as active phase on supported zirconia catalysts for bio-ethanol reforming: influence of the reaction mechanism on catalysts performance publication-title: Int J Hydrogen Energy doi: 10.1016/j.ijhydene.2010.06.021 contributor: fullname: Padilla – volume: 34 start-page: 3816 year: 2009 ident: 10.1016/j.ijhydene.2011.05.022_bib14 article-title: Preparation and catalysis of poly(N-vinyl-2-pyrrolidone) (PVP) stabilized nickel catalyst for hydrolytic dehydrogenation of ammonia borane publication-title: Int J Hydrogen Energy doi: 10.1016/j.ijhydene.2009.03.003 contributor: fullname: Umegaki – volume: 75 start-page: 213 year: 1953 ident: 10.1016/j.ijhydene.2011.05.022_bib23 article-title: Procedures for the preparation of methyl borate publication-title: J Am Chem Soc doi: 10.1021/ja01097a056 contributor: fullname: Schlesinger – volume: 99 start-page: 43 year: 2010 ident: 10.1016/j.ijhydene.2011.05.022_bib3 article-title: Catalysts for methanol steam reforming–a review publication-title: Appl Catal B Environ doi: 10.1016/j.apcatb.2010.06.015 contributor: fullname: Sa – volume: 159 start-page: 855 year: 2006 ident: 10.1016/j.ijhydene.2011.05.022_bib6 article-title: Dissociation and hydrolysis of ammonia–borane with solid acids and carbon dioxide: an efficient hydrogen generation system publication-title: J Power Sources doi: 10.1016/j.jpowsour.2005.12.033 contributor: fullname: Chandra – volume: 36 start-page: 254 year: 2011 ident: 10.1016/j.ijhydene.2011.05.022_bib8 article-title: Hydrogen generation from the hydrolysis of ammonia borane using cobalt–nickel–phosphorus (Co–Ni–P) catalyst supported on Pd-activated TiO2 by electroless deposition publication-title: Int J Hydrogen Energy doi: 10.1016/j.ijhydene.2010.09.027 contributor: fullname: Rakap – volume: 75 start-page: 205 year: 1953 ident: 10.1016/j.ijhydene.2011.05.022_bib18 article-title: The preparation of sodium borohydride by the high temperature reaction of sodium hydride with borate esters publication-title: J Am Chem Soc doi: 10.1021/ja01097a054 contributor: fullname: Schlesinger – volume: 46 start-page: 7810 year: 2007 ident: 10.1016/j.ijhydene.2011.05.022_bib16 article-title: Preparation of ammonia borane in high yield and purity, methanolysis publication-title: Inorg Chem doi: 10.1021/ic700772a contributor: fullname: Ramachandran – volume: 34 start-page: 7223 year: 2009 ident: 10.1016/j.ijhydene.2011.05.022_bib7 article-title: Water soluble laurate-stabilized ruthenium(0) nanoclusters catalyst for hydrogen generation from the hydrolysis of ammonia–borane: high activity and long lifetime publication-title: Int J Hydrogen Energy doi: 10.1016/j.ijhydene.2009.06.074 contributor: fullname: Durap – volume: 177 start-page: 485 year: 2008 ident: 10.1016/j.ijhydene.2011.05.022_bib19 article-title: Simple and fast fabrication of polymer template-Ru composite as a catalyst for hydrogen generation from alkaline NaBH4 solution publication-title: J Power Sources doi: 10.1016/j.jpowsour.2007.11.096 contributor: fullname: Hsueh – volume: 35 start-page: 6738 year: 2010 ident: 10.1016/j.ijhydene.2011.05.022_bib1 article-title: Hydrogen production by steam reforming of liquefied natural gas (LNG) over mesoporous nickel-alumina aerogel catalyst publication-title: Int J Hydrogen Energy doi: 10.1016/j.ijhydene.2010.04.093 contributor: fullname: Seo – volume: 34 start-page: 2638 year: 2009 ident: 10.1016/j.ijhydene.2011.05.022_bib10 article-title: Ten-year efforts and a no-go recommendation for sodium borohydride for on-board automotive hydrogen storage publication-title: Int J Hydrogen Energy doi: 10.1016/j.ijhydene.2009.01.038 contributor: fullname: Demirci – volume: 49 start-page: 10994 year: 2010 ident: 10.1016/j.ijhydene.2011.05.022_bib15 article-title: Hydrogen for vehicle applications from hydrothermolysis of ammonia borane: hydrogen yield, thermal characteristics, and ammonia formation publication-title: Ind Eng Chem Res doi: 10.1021/ie100520r contributor: fullname: Hwang – volume: 168 start-page: 135 year: 2007 ident: 10.1016/j.ijhydene.2011.05.022_bib12 article-title: Room temperature hydrogen generation from aqueous ammonia–borane using noble metal nano-clusters as highly active catalysts publication-title: J Power Sources doi: 10.1016/j.jpowsour.2007.03.015 contributor: fullname: Chandra – volume: 6 start-page: 389 year: 2002 ident: 10.1016/j.ijhydene.2011.05.022_bib5 article-title: Review of fuel processing catalysts for hydrogen production in PEM fuel cell systems publication-title: Curr Opin Solid State Mater Sci doi: 10.1016/S1359-0286(02)00108-0 contributor: fullname: Ghenciu – volume: 49 start-page: 9864 year: 2010 ident: 10.1016/j.ijhydene.2011.05.022_bib17 article-title: Trimethyl borate regenerated from spent sodium borohydride after hydrogen production publication-title: Ind Eng Chem Res doi: 10.1021/ie101309f contributor: fullname: Liu |
| SSID | ssj0017049 |
| Score | 2.3459246 |
| Snippet | Ammonia borane (NH
3BH
3, AB), one kind of promising hydrogen storage materials, is hydrolyzed to produce hydrogen in presence of HCl, Co/IR-120 and Ru/IR-120... Ammonia borane (NH3BH3, AB), one kind of promising hydrogen storage materials, is hydrolyzed to produce hydrogen in presence of HCl, Co/IR-120 and Ru/IR-120... |
| SourceID | proquest crossref pascalfrancis elsevier |
| SourceType | Aggregation Database Index Database Publisher |
| StartPage | 2950 |
| SubjectTerms | Alternative fuels. Production and utilization Ammonia Ammonia borane Applied sciences Boranes Boric acid Boric acids Catalysis Catalyst Catalysts Co/IR-120 Colorimetry Energy Exact sciences and technology Fuels Hydrogen Hydrogen generation Hydrogen storage Hydrolysis Ru/IR-120 |
| Title | Hydrogen generated from hydrolysis of ammonia borane using cobalt and ruthenium based catalysts |
| URI | https://dx.doi.org/10.1016/j.ijhydene.2011.05.022 https://search.proquest.com/docview/1019621980 https://search.proquest.com/docview/1762137176 |
| Volume | 37 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV1LbxMxEB6V9AJCiKcIj8hIXDfZx9jrHKuKKoDoBSr1Zjl-tBupmyjZHHLhtzOzj6oVAg4c1_LuWp_H34x3Zz4DfPTB5pGNd15GmaDTMdE6YuIRnSs8mbTjQuFv52pxgV8u5eURnA61MJxW2XN_x-ktW_ctsx7N2aaqZt-Je7kEh1Yr65rxFuiY3FGuR3B88vnr4vz2Z0LZR8HUP-Eb7hQKr6bV6vpAKzz0ap5ymub5n3zU443dEXKxO_LiN_ZuXdLZU3jSx5LipBvuMzgK9XN4dEdh8AWYxcFv12Qk4qrVl6b4UnBFibjm9laORKyjsGyNlRVsEHUQnAx_JRxLhTTC1l5sOQ--rvY3gr2eF-1Hn8Ou2b2Ei7NPP04XSX-mQuIQZZPEjCtvlc6tTtHOEYNSpbdotcusjjLTzhdB2jxDq5TM-fgXtcSAKS6JFm3xCkb1ug6vQaCS1i9L7QufovORY7Uy0n4li8wScgyzAUWz6aQzzJBTtjID7oZxN6k0hPsY5gPY5p4RGOL3f947uTc7t69kwX9FYfEYPgzTZWgJ8X8RQnS93_FT54qYW_-tDzmNrKC9r3rzH4N8Cw_pKu-yvt_BqNnuw3sKaprlBB5Mf2aT3nR_ATT696Q |
| link.rule.ids | 310,311,315,783,787,792,793,4509,23942,23943,24128,25152,27936,27937,45597,45691 |
| linkProvider | Elsevier |
| linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV1LT9wwELYQHNqqQvSlbmmpK_UaNo-x4xwRKgqvvRQkbpbXD8hKZFe72cP--87kgUBVy4GrYyfWeOabcTzzmbGfzps0kPIWeRARWBUipQJEDsDazKFKWyoUvpzI8hrObsTNFjseamEorbLH_g7TW7TuW8a9NMeLqhr_RuylEhy0VuI1oy3QDkYDBVrnztHpeTl5OEzI-ygY-0c04FGh8Oywmt1t0MJ9z-YpDuM0_ZePerswK5Rc6K68-Au9W5d0ssd2-1iSH3XTfce2fP2evXnEMPiB6XLjlnNUEn7b8ktjfMmpooTfUXtLR8LngRvSxspwUojac0qGv-WWqEIabmrHl5QHX1fre05ez_H2p89m1aw-suuTX1fHZdTfqRBZANFEIaHKW6lSo2IwBYCXMncGjLKJUUEkyrrMC5MmYKQUKV3_IqfgIYYpwqLJPrHtel77z4yDFMZNc-UyF4N1gWK1POB-JQmEEmLExoMU9aKjztBDTtlMD3LXJHcdC41yH7FiELZ-ogQa8f3ZsQdPVufhk0T4LzEsHrEfw3JpNCE6F0GJztcremshEbnV__qg00gy3PvKLy-Y5Hf2qry6vNAXp5PzffYan6RdBvhXtt0s1_4bBjjN9KBX4D8yy_mY |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=proceeding&rft.title=International+journal+of+hydrogen+energy&rft.atitle=Hydrogen+generated+from+hydrolysis+of+ammonia+borane+using+cobalt+and+ruthenium+based+catalysts&rft.au=LIU%2C+Cheng-Hong&rft.au=WU%2C+Yi-Chun&rft.au=CHOU%2C+Chang-Cheng&rft.au=CHEN%2C+Bing-Hung&rft.date=2012-02-01&rft.pub=Elsevier&rft.issn=0360-3199&rft.eissn=1879-3487&rft.volume=37&rft.issue=3&rft.spage=2950&rft.epage=2959&rft_id=info:doi/10.1016%2Fj.ijhydene.2011.05.022&rft.externalDBID=n%2Fa&rft.externalDocID=25466800 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0360-3199&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0360-3199&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0360-3199&client=summon |