Hydrogen generated from hydrolysis of ammonia borane using cobalt and ruthenium based catalysts
Ammonia borane (NH 3BH 3, AB), one kind of promising hydrogen storage materials, is hydrolyzed to produce hydrogen in presence of HCl, Co/IR-120 and Ru/IR-120 catalysts. The kinetics analysis of the AB hydrolysis shows that hydrogen production is of the first-order reaction in regard to both concent...
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Published in | International journal of hydrogen energy Vol. 37; no. 3; pp. 2950 - 2959 |
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Main Authors | , , , , , , |
Format | Journal Article Conference Proceeding |
Language | English |
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Elsevier Ltd
01.02.2012
Elsevier |
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Abstract | Ammonia borane (NH
3BH
3, AB), one kind of promising hydrogen storage materials, is hydrolyzed to produce hydrogen in presence of HCl, Co/IR-120 and Ru/IR-120 catalysts. The kinetics analysis of the AB hydrolysis shows that hydrogen production is of the first-order reaction in regard to both concentrations of ammonia borane and catalysts initially present, respectively. The hydrolyzate of ammonia borane after hydrogen evolution is also characterized with XRD, FT-IR and
11B NMR. Boric acid (H
3BO
3) is found to be the dominant product in the hydrolyzate. Besides, the produced gas is discovered to contain both hydrogen and ammonia according to the GC–MS analysis and the indophenol colorimetric analysis. A possible reaction pathway on hydrogen generation from hydrolysis of ammonia borane is, accordingly, proposed based on the existence of boric acid, hydrogen and ammonia in the products. The total life cycle of ammonia borane is also proposed to illustrate formation of different intermediates during the AB hydrolysis for hydrogen generation and a possible regeneration scheme of the spent ammonia borane.
► Hydrogen is produced from hydrolysis of ammonia borane in presence of light-weight Co or Ru catalysts. ► The hydrolysis reaction of ammonia borane is of the first-order in concentrations of ammonia borane and catalysts. ► Ammonia is conjointly produced with hydrogen from hydrolysis of ammonia borane, and can be reduced with proper management of exothermic reaction heat. ► Boric acid is the major hydrolyzate of ammonia borane for hydrogen evolution. |
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AbstractList | Ammonia borane (NH3BH3, AB), one kind of promising hydrogen storage materials, is hydrolyzed to produce hydrogen in presence of HCl, Co/IR-120 and Ru/IR-120 catalysts. The kinetics analysis of the AB hydrolysis shows that hydrogen production is of the first-order reaction in regard to both concentrations of ammonia borane and catalysts initially present, respectively. The hydrolyzate of ammonia borane after hydrogen evolution is also characterized with XRD, FT-IR and 11B NMR. Boric acid (H3BO3) is found to be the dominant product in the hydrolyzate. Besides, the produced gas is discovered to contain both hydrogen and ammonia according to the GC-MS analysis and the indophenol colorimetric analysis. A possible reaction pathway on hydrogen generation from hydrolysis of ammonia borane is, accordingly, proposed based on the existence of boric acid, hydrogen and ammonia in the products. The total life cycle of ammonia borane is also proposed to illustrate formation of different intermediates during the AB hydrolysis for hydrogen generation and a possible regeneration scheme of the spent ammonia borane. Ammonia borane (NH 3BH 3, AB), one kind of promising hydrogen storage materials, is hydrolyzed to produce hydrogen in presence of HCl, Co/IR-120 and Ru/IR-120 catalysts. The kinetics analysis of the AB hydrolysis shows that hydrogen production is of the first-order reaction in regard to both concentrations of ammonia borane and catalysts initially present, respectively. The hydrolyzate of ammonia borane after hydrogen evolution is also characterized with XRD, FT-IR and 11B NMR. Boric acid (H 3BO 3) is found to be the dominant product in the hydrolyzate. Besides, the produced gas is discovered to contain both hydrogen and ammonia according to the GC–MS analysis and the indophenol colorimetric analysis. A possible reaction pathway on hydrogen generation from hydrolysis of ammonia borane is, accordingly, proposed based on the existence of boric acid, hydrogen and ammonia in the products. The total life cycle of ammonia borane is also proposed to illustrate formation of different intermediates during the AB hydrolysis for hydrogen generation and a possible regeneration scheme of the spent ammonia borane. ► Hydrogen is produced from hydrolysis of ammonia borane in presence of light-weight Co or Ru catalysts. ► The hydrolysis reaction of ammonia borane is of the first-order in concentrations of ammonia borane and catalysts. ► Ammonia is conjointly produced with hydrogen from hydrolysis of ammonia borane, and can be reduced with proper management of exothermic reaction heat. ► Boric acid is the major hydrolyzate of ammonia borane for hydrogen evolution. |
Author | Tsau, Fanghei Liu, Cheng-Hong Chen, Bing-Hung Wu, Yi-Chun Chou, Chang-Cheng Hsueh, Chan-Li Ku, Jie-Ren |
Author_xml | – sequence: 1 givenname: Cheng-Hong surname: Liu fullname: Liu, Cheng-Hong organization: Department of Chemical Engineering, National Cheng Kung University, 1 University Road, Tainan 70101, Taiwan – sequence: 2 givenname: Yi-Chun surname: Wu fullname: Wu, Yi-Chun organization: Department of Chemical Engineering, National Cheng Kung University, 1 University Road, Tainan 70101, Taiwan – sequence: 3 givenname: Chang-Cheng surname: Chou fullname: Chou, Chang-Cheng organization: Department of Chemical Engineering, National Cheng Kung University, 1 University Road, Tainan 70101, Taiwan – sequence: 4 givenname: Bing-Hung surname: Chen fullname: Chen, Bing-Hung email: bhchen@alumni.rice.edu organization: Department of Chemical Engineering, National Cheng Kung University, 1 University Road, Tainan 70101, Taiwan – sequence: 5 givenname: Chan-Li surname: Hsueh fullname: Hsueh, Chan-Li organization: New Energy Technology Division, Green Energy and Environment Research Laboratories, Industrial Technology Research Institute (ITRI), Hsinchu County 31040, Taiwan – sequence: 6 givenname: Jie-Ren surname: Ku fullname: Ku, Jie-Ren organization: New Energy Technology Division, Green Energy and Environment Research Laboratories, Industrial Technology Research Institute (ITRI), Hsinchu County 31040, Taiwan – sequence: 7 givenname: Fanghei surname: Tsau fullname: Tsau, Fanghei organization: New Energy Technology Division, Green Energy and Environment Research Laboratories, Industrial Technology Research Institute (ITRI), Hsinchu County 31040, Taiwan |
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Keywords | Boric acid Ru/IR-120 Hydrogen generation Co/IR-120 Catalyst Ammonia borane |
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Snippet | Ammonia borane (NH
3BH
3, AB), one kind of promising hydrogen storage materials, is hydrolyzed to produce hydrogen in presence of HCl, Co/IR-120 and Ru/IR-120... Ammonia borane (NH3BH3, AB), one kind of promising hydrogen storage materials, is hydrolyzed to produce hydrogen in presence of HCl, Co/IR-120 and Ru/IR-120... |
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SubjectTerms | Alternative fuels. Production and utilization Ammonia Ammonia borane Applied sciences Boranes Boric acid Boric acids Catalysis Catalyst Catalysts Co/IR-120 Colorimetry Energy Exact sciences and technology Fuels Hydrogen Hydrogen generation Hydrogen storage Hydrolysis Ru/IR-120 |
Title | Hydrogen generated from hydrolysis of ammonia borane using cobalt and ruthenium based catalysts |
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