Hydrolysis of Element (White) Phosphorus under the Action of Heterometallic Cubane-Type Cluster {Mo3PdS4}

• Published in: Molecules (Basel, Switzerland) Vol. 26; no. 3; p. 538
• Main Authors: Kuchkaev, Airat M., Shmelev, Nikita Y., Kuchkaev, Aidar M., Sukhov, Aleksandr V., Babaev, Vasily M., Khayarov, Khasan R., Gushchin, Artem L., Sokolov, Maxim N., Sinyashin, Oleg G., Yakhvarov, Dmitry G.
• Format: Journal Article
• Language: English
• Published: Switzerland MDPI AG 21.01.2021; MDPI
• Subjects: Acids; heterometallic cubane-type clusters; Ligands; molybdenum; Oxidation; palladium; phosphine; phosphorous acid; Phosphorus; Spectrum analysis; white phosphorus; phosphorous acid; palladium; white phosphorus; phosphine; heterometallic cubane-type clusters; molybdenum

Reaction of heterometallic cubane-type cluster complexes—[Mo3{Pd(dba)}S4Cl3(dbbpy)3]PF6, [Mo3{Pd(tu)}S4Cl3(dbbpy)3]Cl and [Mo3{Pd(dba)}S4(acac)3(py)3]PF6, where dba—dibenzylideneacetone, dbbpy—4,4′-di-tert-butyl-2,2′-bipyridine, tu—thiourea, acac—acetylacetonate, py—pyridine, with white phosphorus (...