Photoacoustic detection of ozone with a red laser diode
The photoacoustic detection of ozone using the Chappuis band is demonstrated. A visible red laser diode emitting at 638 nm was employed as a light source. The photoacoustic cell consisted of a conventional resonance tube with a MEMS (microelectromechanical systems) microphone placed outside an openi...
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| Published in | Talanta (Oxford) Vol. 223; no. Pt 2; p. 121890 |
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| Main Authors | , |
| Format | Journal Article |
| Language | English |
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Elsevier B.V
01.02.2021
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| Abstract | The photoacoustic detection of ozone using the Chappuis band is demonstrated. A visible red laser diode emitting at 638 nm was employed as a light source. The photoacoustic cell consisted of a conventional resonance tube with a MEMS (microelectromechanical systems) microphone placed outside an opening along the tube. A calibration curve for the range from 33 ppmV to 215 ppmV was found to be highly linear with a coefficient of determination (r2) of 0.9999, when allowing for different measurement frequencies to account for shifts in the speed of sound due to changes in the gas matrix. The limit of detection was found to be 1.6 ppmV for an optical power of the laser diode of about 130 mW.
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•A visible laser diode is employed for the first time.•The light source is inexpensive.•The detection limit is in the low ppmV range. |
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| AbstractList | The photoacoustic detection of ozone using the Chappuis band is demonstrated. A visible red laser diode emitting at 638 nm was employed as a light source. The photoacoustic cell consisted of a conventional resonance tube with a MEMS (microelectromechanical systems) microphone placed outside an opening along the tube. A calibration curve for the range from 33 ppmV to 215 ppmV was found to be highly linear with a coefficient of determination (r
) of 0.9999, when allowing for different measurement frequencies to account for shifts in the speed of sound due to changes in the gas matrix. The limit of detection was found to be 1.6 ppmV for an optical power of the laser diode of about 130 mW. The photoacoustic detection of ozone using the Chappuis band is demonstrated. A visible red laser diode emitting at 638 nm was employed as a light source. The photoacoustic cell consisted of a conventional resonance tube with a MEMS (microelectromechanical systems) microphone placed outside an opening along the tube. A calibration curve for the range from 33 ppmV to 215 ppmV was found to be highly linear with a coefficient of determination (r2) of 0.9999, when allowing for different measurement frequencies to account for shifts in the speed of sound due to changes in the gas matrix. The limit of detection was found to be 1.6 ppmV for an optical power of the laser diode of about 130 mW. [Display omitted] •A visible laser diode is employed for the first time.•The light source is inexpensive.•The detection limit is in the low ppmV range. The photoacoustic detection of ozone using the Chappuis band is demonstrated. A visible red laser diode emitting at 638 nm was employed as a light source. The photoacoustic cell consisted of a conventional resonance tube with a MEMS (microelectromechanical systems) microphone placed outside an opening along the tube. A calibration curve for the range from 33 ppmV to 215 ppmV was found to be highly linear with a coefficient of determination (r2) of 0.9999, when allowing for different measurement frequencies to account for shifts in the speed of sound due to changes in the gas matrix. The limit of detection was found to be 1.6 ppmV for an optical power of the laser diode of about 130 mW.The photoacoustic detection of ozone using the Chappuis band is demonstrated. A visible red laser diode emitting at 638 nm was employed as a light source. The photoacoustic cell consisted of a conventional resonance tube with a MEMS (microelectromechanical systems) microphone placed outside an opening along the tube. A calibration curve for the range from 33 ppmV to 215 ppmV was found to be highly linear with a coefficient of determination (r2) of 0.9999, when allowing for different measurement frequencies to account for shifts in the speed of sound due to changes in the gas matrix. The limit of detection was found to be 1.6 ppmV for an optical power of the laser diode of about 130 mW. The photoacoustic detection of ozone using the Chappuis band is demonstrated. A visible red laser diode emitting at 638 nm was employed as a light source. The photoacoustic cell consisted of a conventional resonance tube with a MEMS (microelectromechanical systems) microphone placed outside an opening along the tube. A calibration curve for the range from 33 ppmV to 215 ppmV was found to be highly linear with a coefficient of determination (r²) of 0.9999, when allowing for different measurement frequencies to account for shifts in the speed of sound due to changes in the gas matrix. The limit of detection was found to be 1.6 ppmV for an optical power of the laser diode of about 130 mW. |
| ArticleNumber | 121890 |
| Author | Hauser, Peter C. Keeratirawee, Kanchalar |
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| Cites_doi | 10.5194/amt-7-609-2014 10.1016/j.atmosenv.2011.11.063 10.1080/10934520903217740 10.1080/01919519608547327 10.1006/jema.1999.0256 10.5194/essd-5-365-2013 10.1016/j.sna.2017.06.036 10.1081/SL-200058726 10.1111/j.1438-8677.2009.00263.x 10.1029/93GL02311 10.1080/01919510701813376 10.1088/1742-6596/1153/1/012086 10.3389/fimmu.2019.02518 10.1016/j.watres.2008.11.006 10.1016/S1010-6030(03)00061-3 10.1109/JSTQE.2012.2182761 10.1016/j.watres.2013.04.059 10.1103/PhysRev.31.267 |
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| Keywords | MEMS microphone Ozone Photoacoustic spectroscopy Red laser diode |
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| Snippet | The photoacoustic detection of ozone using the Chappuis band is demonstrated. A visible red laser diode emitting at 638 nm was employed as a light source. The... The photoacoustic detection of ozone using the Chappuis band is demonstrated. A visible red laser diode emitting at 638 nm was employed as a light source. The... |
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| SubjectTerms | calibration detection limit diodes light measurement MEMS microphone microphones Ozone Photoacoustic spectroscopy Red laser diode |
| Title | Photoacoustic detection of ozone with a red laser diode |
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