A "Hot, Energized" Benzyne
Fundamental aspects of chemically activated reactive intermediates can possibly be learned from the novel generation of arynes. The intramolecular [4+2] cycloaddition between a diyne and an (electronically activated) alkyne also provides a new route to generate arynes (see scheme).
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| Published in | Angewandte Chemie International Edition Vol. 52; no. 10; pp. 2655 - 2656 |
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| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
Weinheim
WILEY-VCH Verlag
04.03.2013
WILEY‐VCH Verlag Wiley Subscription Services, Inc |
| Edition | International ed. in English |
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| Abstract | Fundamental aspects of chemically activated reactive intermediates can possibly be learned from the novel generation of arynes. The intramolecular [4+2] cycloaddition between a diyne and an (electronically activated) alkyne also provides a new route to generate arynes (see scheme). |
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| AbstractList | Fundamental aspects of chemically activated reactive intermediates can possibly be learned from the novel generation of arynes. The intramolecular [4+2]cycloaddition between a diyne and an (electronically activated) alkyne also provides a new route to generate arynes (see scheme). Fundamental aspects of chemically activated reactive intermediates can possibly be learned from the novel generation of arynes. The intramolecular [4+2]cycloaddition between a diyne and an (electronically activated) alkyne also provides a new route to generate arynes. |
| Author | Suzuki, Keisuke Hoffmann, Reinhard W. |
| Author_xml | – sequence: 1 givenname: Reinhard W. surname: Hoffmann fullname: Hoffmann, Reinhard W. email: rwho@chemie.uni-marburg.de organization: Fachbereich Chemie der Philipps-Universität, Hans-Meerwein-Strasse, 35032 Marburg (Germany) – sequence: 2 givenname: Keisuke surname: Suzuki fullname: Suzuki, Keisuke organization: Department of Chemistry, Tokyo Institute of Technology, 2-12-1, O-okayama, Meguro-ku, Tokyo 152-8551 (Japan) |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/23315989$$D View this record in MEDLINE/PubMed |
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| Notes | We thank Prof. B. K. Carpenter, Cardiff, for helpful comments. ark:/67375/WNG-GLTTXQ59-L istex:444269DD9217F2AED0E784B91A99055917151E68 ArticleID:ANIE201209041 ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
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| Snippet | Fundamental aspects of chemically activated reactive intermediates can possibly be learned from the novel generation of arynes. The intramolecular [4+2]... Fundamental aspects of chemically activated reactive intermediates can possibly be learned from the novel generation of arynes. The intramolecular... |
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| SubjectTerms | [4+2] cycloaddition Activated Activation Alkynes arynes chemical activation |
| Title | A "Hot, Energized" Benzyne |
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