Macroscopic-Scale Template Synthesis of Robust Carbonaceous Nanofiber Hydrogels and Aerogels and Their Applications

Robust nanofiber gels: Monolithic hydrogels and aerogels consisting of uniform carbonaceous nanofibers (CNFs) were fabricated on a macroscopic scale (12 L, see picture) by a simple template‐directed, hydrothermal carbonization process. The high surface reactivity of the CNFs and high porosity and ro...

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Published in	Angewandte Chemie International Edition Vol. 51; no. 21; pp. 5101 - 5105
Main Authors	Liang, Hai-Wei, Guan, Qing-Fang, Chen, Li-Feng, Zhu, Zhu, Zhang, Wen-Jun, Yu, Shu-Hong
Format	Journal Article
Language	English
Published	Weinheim WILEY-VCH Verlag 21.05.2012 WILEY‐VCH Verlag Wiley Subscription Services, Inc
Edition	International ed. in English
Subjects	Adsorbents Aerogels carbon Carbonization Gels Hydrogels mechanical properties nanofibers Nanostructure Porosity Synthesis template synthesis
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Abstract	Robust nanofiber gels: Monolithic hydrogels and aerogels consisting of uniform carbonaceous nanofibers (CNFs) were fabricated on a macroscopic scale (12 L, see picture) by a simple template‐directed, hydrothermal carbonization process. The high surface reactivity of the CNFs and high porosity and robust nature of the gels can be exploited in applications such as selective adsorbents and templates for creating functional composite gels.
AbstractList	Robust nanofiber gels: Monolithic hydrogels and aerogels consisting of uniform carbonaceous nanofibers (CNFs) were fabricated on a macroscopic scale (12L, see picture) by a simple template-directed, hydrothermal carbonization process. The high surface reactivity of the CNFs and high porosity and robust nature of the gels can be exploited in applications such as selective adsorbents and templates for creating functional composite gels. Robust nanofiber gels: Monolithic hydrogels and aerogels consisting of uniform carbonaceous nanofibers (CNFs) were fabricated on a macroscopic scale (12 L, see picture) by a simple template‐directed, hydrothermal carbonization process. The high surface reactivity of the CNFs and high porosity and robust nature of the gels can be exploited in applications such as selective adsorbents and templates for creating functional composite gels.
Author	Zhu, Zhu Guan, Qing-Fang Liang, Hai-Wei Zhang, Wen-Jun Chen, Li-Feng Yu, Shu-Hong
Author_xml	– sequence: 1 givenname: Hai-Wei surname: Liang fullname: Liang, Hai-Wei organization: Division of Nanomaterials and Chemistry, Hefei National Laboratory for Physical Sciences at Microscale, Department of Chemistry, National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Anhui 230026 (China) http://staff.ustc.edu.cn/∼yulab/ – sequence: 2 givenname: Qing-Fang surname: Guan fullname: Guan, Qing-Fang organization: Division of Nanomaterials and Chemistry, Hefei National Laboratory for Physical Sciences at Microscale, Department of Chemistry, National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Anhui 230026 (China) http://staff.ustc.edu.cn/∼yulab/ – sequence: 3 givenname: Li-Feng surname: Chen fullname: Chen, Li-Feng organization: Division of Nanomaterials and Chemistry, Hefei National Laboratory for Physical Sciences at Microscale, Department of Chemistry, National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Anhui 230026 (China) http://staff.ustc.edu.cn/∼yulab/ – sequence: 4 givenname: Zhu surname: Zhu fullname: Zhu, Zhu organization: Division of Nanomaterials and Chemistry, Hefei National Laboratory for Physical Sciences at Microscale, Department of Chemistry, National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Anhui 230026 (China) http://staff.ustc.edu.cn/∼yulab/ – sequence: 5 givenname: Wen-Jun surname: Zhang fullname: Zhang, Wen-Jun organization: Division of Nanomaterials and Chemistry, Hefei National Laboratory for Physical Sciences at Microscale, Department of Chemistry, National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Anhui 230026 (China) http://staff.ustc.edu.cn/∼yulab/ – sequence: 6 givenname: Shu-Hong surname: Yu fullname: Yu, Shu-Hong email: shyu@ustc.edu.cn organization: Division of Nanomaterials and Chemistry, Hefei National Laboratory for Physical Sciences at Microscale, Department of Chemistry, National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Anhui 230026 (China) http://staff.ustc.edu.cn/∼yulab/
BackLink	https://www.ncbi.nlm.nih.gov/pubmed/22505338$$D View this record in MEDLINE/PubMed
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Notes	ArticleID:ANIE201200710 Chinese Academy of Sciences S.H.Y. acknowledges the special funding support from the National Basic Research Program of China (No. 2010CB934700), the National Natural Science Foundation of China (Nos. 91022032, 21061160492, J1030412), Chinese Academy of Sciences (Grant KJZD-EW-M01-1), International Science & Technology Cooperation Program of China (No. 2010DFA41170), the Principal Investigator Award by the National Synchrotron Radiation Laboratory at the USTC, the Partner-Group of the Chinese Academy of Sciences and the Max Planck Society. H.W.L. acknowledges the funding support from the Fundamental Research Funds for the Central Universities. We thank Prof. Xin Xu and Mr. Jiang-Wei Zhang for assisting in rheological tests. National Basic Research Program of China - No. 2010CB934700 ark:/67375/WNG-9KM3S8HD-3 International Science & Technology Cooperation Program of China - No. 2010DFA41170 istex:BE0505BF64C0803B7F17170113F8EFC53404E582 Chinese Academy of Sciences - No. KJZD-EW-M01-1 Max Planck Society National Natural Science Foundation of China - No. 91022032; No. 21061160492; No. J1030412 S.H.Y. acknowledges the special funding support from the National Basic Research Program of China (No. 2010CB934700), the National Natural Science Foundation of China (Nos. 91022032, 21061160492, J1030412), Chinese Academy of Sciences (Grant KJZD‐EW‐M01‐1), International Science & Technology Cooperation Program of China (No. 2010DFA41170), the Principal Investigator Award by the National Synchrotron Radiation Laboratory at the USTC, the Partner‐Group of the Chinese Academy of Sciences and the Max Planck Society. H.W.L. acknowledges the funding support from the Fundamental Research Funds for the Central Universities. We thank Prof. Xin Xu and Mr. Jiang‐Wei Zhang for assisting in rheological tests. ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 content type line 23
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Snippet	Robust nanofiber gels: Monolithic hydrogels and aerogels consisting of uniform carbonaceous nanofibers (CNFs) were fabricated on a macroscopic scale (12 L, see... Robust nanofiber gels: Monolithic hydrogels and aerogels consisting of uniform carbonaceous nanofibers (CNFs) were fabricated on a macroscopic scale (12L, see...
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SubjectTerms	Adsorbents Aerogels carbon Carbonization Gels Hydrogels mechanical properties nanofibers Nanostructure Porosity Synthesis template synthesis
Title	Macroscopic-Scale Template Synthesis of Robust Carbonaceous Nanofiber Hydrogels and Aerogels and Their Applications
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