Biomass chitosan derived cobalt/nitrogen doped carbon nanotubes for the electrocatalytic oxygen reduction reaction
Carbon nanomaterials derived from biomass are considered as important sustainable energy carriers. In this study, we report an approach to synthesize cobalt/nitrogen doped carbon nanotubes (Co-NCNTs) for high oxygen reduction reaction (ORR) activity by cobalt catalyzed carbonization of biomass chito...
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Published in | Journal of materials chemistry. A, Materials for energy and sustainability Vol. 6; no. 14; pp. 574 - 5745 |
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Main Authors | , , , , , , , , , |
Format | Journal Article |
Language | English |
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Cambridge
Royal Society of Chemistry
01.01.2018
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Abstract | Carbon nanomaterials derived from biomass are considered as important sustainable energy carriers. In this study, we report an approach to synthesize cobalt/nitrogen doped carbon nanotubes (Co-NCNTs) for high oxygen reduction reaction (ORR) activity by cobalt catalyzed carbonization of biomass chitosan. It is found that the existence of cobalt results in the transition of graphene-like carbon nanosheets to tubular graphitic carbons. Moreover, a strong chemical bonding of cobalt with nitrogen and carbon in Co-NCNTs is found, which is important for enhancing the ORR activity. The Co-NCNT catalyst under optimized synthetic conditions displays attractive ORR activity superior to those of commercial Pt/C catalysts. Furthermore, the mechanism behind the enhanced ORR activity has also been studied. This study provides a feasible synthesis approach for the scalable production of biomass derived high performance carbon based ORR catalysts.
Biomass chitosan was used for the scalable synthesis of cobalt/nitrogen doped carbon nanotube composites with impressive oxygen reduction reaction activity and stability. |
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AbstractList | Carbon nanomaterials derived from biomass are considered as important sustainable energy carriers. In this study, we report an approach to synthesize cobalt/nitrogen doped carbon nanotubes (Co-NCNTs) for high oxygen reduction reaction (ORR) activity by cobalt catalyzed carbonization of biomass chitosan. It is found that the existence of cobalt results in the transition of graphene-like carbon nanosheets to tubular graphitic carbons. Moreover, a strong chemical bonding of cobalt with nitrogen and carbon in Co-NCNTs is found, which is important for enhancing the ORR activity. The Co-NCNT catalyst under optimized synthetic conditions displays attractive ORR activity superior to those of commercial Pt/C catalysts. Furthermore, the mechanism behind the enhanced ORR activity has also been studied. This study provides a feasible synthesis approach for the scalable production of biomass derived high performance carbon based ORR catalysts. Carbon nanomaterials derived from biomass are considered as important sustainable energy carriers. In this study, we report an approach to synthesize cobalt/nitrogen doped carbon nanotubes (Co-NCNTs) for high oxygen reduction reaction (ORR) activity by cobalt catalyzed carbonization of biomass chitosan. It is found that the existence of cobalt results in the transition of graphene-like carbon nanosheets to tubular graphitic carbons. Moreover, a strong chemical bonding of cobalt with nitrogen and carbon in Co-NCNTs is found, which is important for enhancing the ORR activity. The Co-NCNT catalyst under optimized synthetic conditions displays attractive ORR activity superior to those of commercial Pt/C catalysts. Furthermore, the mechanism behind the enhanced ORR activity has also been studied. This study provides a feasible synthesis approach for the scalable production of biomass derived high performance carbon based ORR catalysts. Biomass chitosan was used for the scalable synthesis of cobalt/nitrogen doped carbon nanotube composites with impressive oxygen reduction reaction activity and stability. |
Author | Zhang, Yijie Liu, Jinghai Lu, Luhua Song, Weiguo Tian, Xiaocong Chen, Ying Jin, Hongyun Yang, Dantong Zhang, Si Lv, Zaozao |
AuthorAffiliation | Zhejiang Institute Chinese Academy of Sciences Institute of Chemistry China University of Geosciences Inner Mongolia Key Laboratory of Carbon Nanomaterials Laboratory of Molecular Nanostructures and Nanotechnology Faculty of Materials Science and Chemistry Inner Mongolia University for Nationalities National Experimental Teaching Demonstration Center of Chemistry Beijing National Laboratory of Molecular Sciences |
AuthorAffiliation_xml | – name: Inner Mongolia University for Nationalities – name: Faculty of Materials Science and Chemistry – name: Institute of Chemistry – name: Zhejiang Institute – name: Chinese Academy of Sciences – name: Beijing National Laboratory of Molecular Sciences – name: Inner Mongolia Key Laboratory of Carbon Nanomaterials – name: China University of Geosciences – name: Laboratory of Molecular Nanostructures and Nanotechnology – name: National Experimental Teaching Demonstration Center of Chemistry |
Author_xml | – sequence: 1 givenname: Yijie surname: Zhang fullname: Zhang, Yijie – sequence: 2 givenname: Luhua surname: Lu fullname: Lu, Luhua – sequence: 3 givenname: Si surname: Zhang fullname: Zhang, Si – sequence: 4 givenname: Zaozao surname: Lv fullname: Lv, Zaozao – sequence: 5 givenname: Dantong surname: Yang fullname: Yang, Dantong – sequence: 6 givenname: Jinghai surname: Liu fullname: Liu, Jinghai – sequence: 7 givenname: Ying surname: Chen fullname: Chen, Ying – sequence: 8 givenname: Xiaocong surname: Tian fullname: Tian, Xiaocong – sequence: 9 givenname: Hongyun surname: Jin fullname: Jin, Hongyun – sequence: 10 givenname: Weiguo surname: Song fullname: Song, Weiguo |
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SubjectTerms | Biomass Biomass energy production biomass production Bonding strength Carbon Carbon nanotubes Carbonization Catalysis Catalysts chemical bonding Chemical bonds Chemical reduction Chitosan Cobalt electrochemistry Feasibility studies Nanomaterials nanosheets Nanotechnology Nanotubes Nitrogen Oxygen Oxygen reduction reactions platinum renewable energy sources Sustainable energy |
Title | Biomass chitosan derived cobalt/nitrogen doped carbon nanotubes for the electrocatalytic oxygen reduction reaction |
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