Advanced non-noble materials in bifunctional catalysts for ORR and OER toward aqueous metal-air batteries

The catalyst in the oxygen electrode is the core component of the aqueous metal-air battery, which plays a vital role in the determination of the open circuit potential, energy density, and cycle life of the battery. For rechargeable aqueous metal-air batteries, the catalyst should have both good ox...

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Published inNanoscale Vol. 12; no. 42; pp. 21534 - 21559
Main Authors Zhang, Yun-Long, Goh, Kokswee, Zhao, Lei, Sui, Xu-Lei, Gong, Xiao-Fei, Cai, Jia-Jun, Zhou, Qing-Yan, Zhang, Hong-Da, Li, Lin, Kong, Fan-Rong, Gu, Da-Ming, Wang, Zhen-Bo
Format Journal Article
LanguageEnglish
Published Cambridge Royal Society of Chemistry 05.11.2020
Subjects
Battery cycles
Carbon
Catalysts
Flux density
Metal air batteries
Noble metals
Open circuit voltage
Oxygen evolution reactions
Oxygen reduction reactions
Rechargeable batteries
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Abstract The catalyst in the oxygen electrode is the core component of the aqueous metal-air battery, which plays a vital role in the determination of the open circuit potential, energy density, and cycle life of the battery. For rechargeable aqueous metal-air batteries, the catalyst should have both good oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) catalytic performance. Compared with precious metal catalysts, non-precious metal materials have more advantages in terms of abundant resource reserves and low prices. Over the past few years, great efforts have been made in the development of non-precious metal bifunctional catalysts. This review selectively evaluates the advantages, disadvantages and development status of recent advanced materials including pure carbon materials, carbon-based metal materials and carbon-free materials as bifunctional oxygen catalysts. Preliminary improvement strategies are formulated to make up for the deficiency of each material. The development prospects and challenges facing bifunctional catalysts in the future are also discussed. Different types of advanced non-noble materials in bifunctional catalysts for ORR and OER.
AbstractList The catalyst in the oxygen electrode is the core component of the aqueous metal-air battery, which plays a vital role in the determination of the open circuit potential, energy density, and cycle life of the battery. For rechargeable aqueous metal-air batteries, the catalyst should have both good oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) catalytic performance. Compared with precious metal catalysts, non-precious metal materials have more advantages in terms of abundant resource reserves and low prices. Over the past few years, great efforts have been made in the development of non-precious metal bifunctional catalysts. This review selectively evaluates the advantages, disadvantages and development status of recent advanced materials including pure carbon materials, carbon-based metal materials and carbon-free materials as bifunctional oxygen catalysts. Preliminary improvement strategies are formulated to make up for the deficiency of each material. The development prospects and challenges facing bifunctional catalysts in the future are also discussed.The catalyst in the oxygen electrode is the core component of the aqueous metal-air battery, which plays a vital role in the determination of the open circuit potential, energy density, and cycle life of the battery. For rechargeable aqueous metal-air batteries, the catalyst should have both good oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) catalytic performance. Compared with precious metal catalysts, non-precious metal materials have more advantages in terms of abundant resource reserves and low prices. Over the past few years, great efforts have been made in the development of non-precious metal bifunctional catalysts. This review selectively evaluates the advantages, disadvantages and development status of recent advanced materials including pure carbon materials, carbon-based metal materials and carbon-free materials as bifunctional oxygen catalysts. Preliminary improvement strategies are formulated to make up for the deficiency of each material. The development prospects and challenges facing bifunctional catalysts in the future are also discussed.
The catalyst in the oxygen electrode is the core component of the aqueous metal–air battery, which plays a vital role in the determination of the open circuit potential, energy density, and cycle life of the battery. For rechargeable aqueous metal–air batteries, the catalyst should have both good oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) catalytic performance. Compared with precious metal catalysts, non-precious metal materials have more advantages in terms of abundant resource reserves and low prices. Over the past few years, great efforts have been made in the development of non-precious metal bifunctional catalysts. This review selectively evaluates the advantages, disadvantages and development status of recent advanced materials including pure carbon materials, carbon-based metal materials and carbon-free materials as bifunctional oxygen catalysts. Preliminary improvement strategies are formulated to make up for the deficiency of each material. The development prospects and challenges facing bifunctional catalysts in the future are also discussed.
The catalyst in the oxygen electrode is the core component of the aqueous metal-air battery, which plays a vital role in the determination of the open circuit potential, energy density, and cycle life of the battery. For rechargeable aqueous metal-air batteries, the catalyst should have both good oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) catalytic performance. Compared with precious metal catalysts, non-precious metal materials have more advantages in terms of abundant resource reserves and low prices. Over the past few years, great efforts have been made in the development of non-precious metal bifunctional catalysts. This review selectively evaluates the advantages, disadvantages and development status of recent advanced materials including pure carbon materials, carbon-based metal materials and carbon-free materials as bifunctional oxygen catalysts. Preliminary improvement strategies are formulated to make up for the deficiency of each material. The development prospects and challenges facing bifunctional catalysts in the future are also discussed. Different types of advanced non-noble materials in bifunctional catalysts for ORR and OER.
Author Gu, Da-Ming
Li, Lin
Goh, Kokswee
Zhou, Qing-Yan
Kong, Fan-Rong
Gong, Xiao-Fei
Wang, Zhen-Bo
Zhang, Yun-Long
Zhao, Lei
Cai, Jia-Jun
Sui, Xu-Lei
Zhang, Hong-Da
AuthorAffiliation Electric Power Research Institute
Harbin Institute of Technology
State Grid Heilongjiang Electric Power Co
State Key Lab of Urban Water Resource and Environment
Ltd
School of Chemistry and Chemical Engineering
Sunwoda Electric Vehicle Battery Co
MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage
AuthorAffiliation_xml – name: MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage
– name: School of Chemistry and Chemical Engineering
– name: State Grid Heilongjiang Electric Power Co
– name: State Key Lab of Urban Water Resource and Environment
– name: Sunwoda Electric Vehicle Battery Co
– name: Ltd
– name: Electric Power Research Institute
– name: Harbin Institute of Technology
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Notes Dr Lei Zhao is currently working as a lecturer at Harbin Institute of Technology (HIT), China, and is a visiting scholar under the supervision of Prof. Zhongwei Chen at University of Waterloo. He received his B. E., M. E. and Ph.D. degree under the supervision of Prof. Zhenbo Wang at HIT in 2012, 2014 and 2017, respectively. His research interests focus on electrocatalysis, fuel cells and metal-air batteries.
Xu-Lei Sui currently is a lecturer at School of Chemistry and Chemical Engineering in Harbin Institute of Technology (HIT), China. He received his Ph.D. degree from HIT in 2015. Now he is also a postdoctoral fellow assisting Prof. Xue-Liang (Andy) Sun at University of Western Ontario, Canada and Prof. Zhen-Bo Wang at HIT. His current research interests are focused on the design and synthesis of advanced nano-materials for electrocatalysis in fuel cells.
Jiajun Cai received her Bachelor's degree from College of Chemistry, Jilin University in 2016. Currently, she is carrying out her Ph.D. research in School of Chemistry and Chemical Engineering at Harbin Institute of Technology under the supervision of Prof. Zhen-Bo Wang. She works on the synthesis and characterization of highly efficient catalysts for Zn-air batteries.
Yunlong Zhang received his B.S. degree in Chemical Engineering and Technology from Harbin Engineering University in 2017. He is carrying out his Ph.D. research in Harbin Institute of Technology under the supervision of Prof. Zhen-Bo Wang. Currently, he works on the synthesis and characterization of Metal Organic Frame materials as high-efficiency ORR catalysts for zinc-air batteries.
Xiaofei Gong received her B.S. degree in Chemical Engineering and Technology from Harbin Institute of Technology (Weihai) in 2015. She is carrying out her Ph.D. research in Harbin Institute of Technology under the supervision of Prof. Zhen-Bo Wang. Her current research focuses on carbon-based non-noble metal catalysts for oxygen reduction reaction in fuel cells.
Dr Zhen-Bo Wang, is currently a professor of Harbin Institute of Technology. He is a distinguished professor of National 'Ten Thousand Talents' Plan Science & Technology Innovation Leader (4th batch), Ministry of Science & Technology Young Scientific & Technological Innovator and consecutively selected for 5 years as Elsevier's "Most cited Chinese scientists". He obtained PhD degrees from HIT in 2006, and completed a post-doctoral stint at the University of Puerto Rico from 2006 to 2007. He has published more than 180 papers in peer-reviewed journals with 4500 citations (H-index = 39). His interests lie in chemical power sources and nanoelectrode materials.
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Snippet The catalyst in the oxygen electrode is the core component of the aqueous metal-air battery, which plays a vital role in the determination of the open circuit...
The catalyst in the oxygen electrode is the core component of the aqueous metal–air battery, which plays a vital role in the determination of the open circuit...
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SubjectTerms Battery cycles
Carbon
Catalysts
Flux density
Metal air batteries
Noble metals
Open circuit voltage
Oxygen evolution reactions
Oxygen reduction reactions
Rechargeable batteries
Title Advanced non-noble materials in bifunctional catalysts for ORR and OER toward aqueous metal-air batteries
URI https://www.proquest.com/docview/2457553023
https://www.proquest.com/docview/2455844359
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