New type of imidazole based salts designed specifically for lithium ion batteries
In this manuscript we announce new type of “tailored” imidazole-derived salts designed, synthesized and tested for application in lithium conductive electrolytes. Basic characterization of the structure of described materials has been made by Raman, IR and NMR ( 13C NMR, 19F NMR) techniques. DSC and...
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| Published in | Electrochimica acta Vol. 55; no. 4; pp. 1450 - 1454 |
|---|---|
| Main Authors | , , , , , , , , , , |
| Format | Journal Article Conference Proceeding |
| Language | English |
| Published |
Kidlington
Elsevier Ltd
25.01.2010
Elsevier |
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| Online Access | Get full text |
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| Abstract | In this manuscript we announce new type of “tailored” imidazole-derived salts designed, synthesized and tested for application in lithium conductive electrolytes. Basic characterization of the structure of described materials has been made by Raman, IR and NMR (
13C NMR,
19F NMR) techniques. DSC and CV studies showed thermal stability of all salts over 200
°C and electrochemical stability in liquid and solid polymer solvents up to +4.6
V vs. metallic lithium anode and Al collectors. Such properties proved applicability of these salts as lithium electrolytes for modern types of lithium ion batteries. |
|---|---|
| AbstractList | In this manuscript we announce new type of "tailored" imidazole-derived salts designed, synthesized and tested for application in lithium conductive electrolytes. Basic characterization of the structure of described materials has been made by Raman, IR and NMR ((13)C NMR, (19)F NMR) techniques. DSC and CV studies showed thermal stability of all salts over 200 'C and electrochemical stability in liquid and solid polymer solvents up to +4.6 V vs. metallic lithium anode and Al collectors. Such properties proved applicability of these salts as lithium electrolytes for modern types of lithium ion batteries. In this manuscript we announce new type of “tailored” imidazole-derived salts designed, synthesized and tested for application in lithium conductive electrolytes. Basic characterization of the structure of described materials has been made by Raman, IR and NMR ( 13C NMR, 19F NMR) techniques. DSC and CV studies showed thermal stability of all salts over 200 °C and electrochemical stability in liquid and solid polymer solvents up to +4.6 V vs. metallic lithium anode and Al collectors. Such properties proved applicability of these salts as lithium electrolytes for modern types of lithium ion batteries. |
| Author | Laruelle, S. Wieczorek, W. Szczeciński, P. Bukowska, M. Grugeon, S. Panero, S. Żukowska, G.Z. Armand, M. Niedzicki, L. Marcinek, M. Scrosati, B. |
| Author_xml | – sequence: 1 givenname: L. surname: Niedzicki fullname: Niedzicki, L. email: asalm@ch.pw.edu.pl organization: Department of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00664 Warsaw, Poland – sequence: 2 givenname: G.Z. surname: Żukowska fullname: Żukowska, G.Z. organization: Department of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00664 Warsaw, Poland – sequence: 3 givenname: M. surname: Bukowska fullname: Bukowska, M. organization: Department of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00664 Warsaw, Poland – sequence: 4 givenname: P. surname: Szczeciński fullname: Szczeciński, P. organization: Department of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00664 Warsaw, Poland – sequence: 5 givenname: S. surname: Grugeon fullname: Grugeon, S. organization: Laboratoire de Reactivite et de Chimie des Solides University de Picardie Jules Verne, 33 rue de Saint-Leu, 80039 Amiens, France – sequence: 6 givenname: S. surname: Laruelle fullname: Laruelle, S. organization: Laboratoire de Reactivite et de Chimie des Solides University de Picardie Jules Verne, 33 rue de Saint-Leu, 80039 Amiens, France – sequence: 7 givenname: M. surname: Armand fullname: Armand, M. organization: Laboratoire de Reactivite et de Chimie des Solides University de Picardie Jules Verne, 33 rue de Saint-Leu, 80039 Amiens, France – sequence: 8 givenname: S. surname: Panero fullname: Panero, S. organization: Department of Chemistry, The University of Rome “La Sapienza”, Piazzale Aldo Moro 5, 00185 Rome, Italy – sequence: 9 givenname: B. surname: Scrosati fullname: Scrosati, B. organization: Department of Chemistry, The University of Rome “La Sapienza”, Piazzale Aldo Moro 5, 00185 Rome, Italy – sequence: 10 givenname: M. surname: Marcinek fullname: Marcinek, M. organization: Department of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00664 Warsaw, Poland – sequence: 11 givenname: W. surname: Wieczorek fullname: Wieczorek, W. organization: Department of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00664 Warsaw, Poland |
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| Keywords | Electrolytes Salts Synthesis Batteries Lithium ion Infrared spectrometry Fourier transformation Electrolyte Lithion ion batteries Secondary cell Raman spectrometry |
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| SubjectTerms | Applied sciences Batteries Direct energy conversion and energy accumulation Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Electrolytes Exact sciences and technology Lithium ion Salts Synthesis |
| Title | New type of imidazole based salts designed specifically for lithium ion batteries |
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