Synthesis of Spirocyclic 1‐Pyrrolines from Nitrones and Arynes through a Dearomative [3,3′]‐Sigmatropic Rearrangement - Alshreimi, Abdullah S.; Zhang, Guanqun; Reidl, Tyler W.; Peña, Ricardo L.; Koto, Nicholas‐George; Islam, Shahidul M.; Wink, Donald J.; Anderson, Laura L. (Angewandte Chemie International Edition, 2020)
Keywords: Cascade chemical reactions; Chemistry; Chemistry, Multidisciplinary; Cycloaddition; dearomatization; dipolar cycloaddition; Divergence; nitrones; Physical Sciences; Pyrrolidine; Science & Technology; sigmatropic rearrangement; spirocyclic pyrroline; Stereoselectivity; dearomatization; CATALYTIC ASYMMETRIC DEAROMATIZATION; dipolar cycloaddition; CLAISEN REARRANGEMENT; INTRAMOLECULAR DEAROMATIZATION; INDOLES; AMINO-ACIDS; 1,3-DIPOLAR CYCLOADDITION; CONSTRUCTION; nitrones; spirocyclic pyrroline; PHENOL DEAROMATIZATION; STEREOGENIC CENTERS; sigmatropic rearrangement; DERIVATIVES