Phthalorubines: Fused‐Ring Compounds Synthesized from Phthalonitrile
A series of dibenzo[a,f][1,3,5]triazino[2,1,6‐cd] pyrrolizine compounds have been synthesized from phthalonitriles by a facile intramolecular cyclization process using “half‐phthalocyanine” precursors, and they were characterized by X‐ray crystallography, 1H NMR spectroscopy, UV/Vis, and theoretical...
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Published in | Angewandte Chemie International Edition Vol. 57; no. 47; pp. 15384 - 15389 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
Published |
WEINHEIM
Wiley
19.11.2018
Wiley Subscription Services, Inc |
Edition | International ed. in English |
Subjects | |
Online Access | Get full text |
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Summary: | A series of dibenzo[a,f][1,3,5]triazino[2,1,6‐cd] pyrrolizine compounds have been synthesized from phthalonitriles by a facile intramolecular cyclization process using “half‐phthalocyanine” precursors, and they were characterized by X‐ray crystallography, 1H NMR spectroscopy, UV/Vis, and theoretical calculations. These compounds have spectroscopic profiles similar to phthalocyanines and porphyrins, although their inner‐core structures and coordination types are totally different. They can be regarded as a new class of aromatic fused‐ring compounds. The low‐energy absorption of these new fused‐ring compounds are located at around 600 nm. Such a low‐energy π–π* transition is scarce in aromatic compounds having a similar molecular size. According to the nomenclature of phthalocyanines, these types of compounds have been named phthalorubines (Prs).
Ruby red: A new class of fused‐ring compounds has been synthesized from phthalonitrile. These compounds have very similar spectroscopic profiles as phthalocyanines, but have a very different inner‐core structure and coordination properties. According to the nomenclature of phthalocyanines, these compounds have been named as phthalorubines (Prs). |
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Bibliography: | These authors contributed equally to this work. |
ISSN: | 1433-7851 1521-3773 1521-3773 |
DOI: | 10.1002/anie.201807281 |