Alternative fuel additives from glycerol by etherification with isobutene: Structure–performance relationships in solid catalysts

The expansion of biodiesel industry is expected to introduce over three million tons of glycerol into the market in 2020. Various routes have been proposed to produce glycerol-based value-added products to sustain renewable glycerol and biodiesel industries. One of these routes is the catalytic ethe...

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Published inFuel processing technology Vol. 138; pp. 780 - 804
Main Authors Bozkurt, Özge D., Tunç, F. Meliz, Bağlar, Nur, Çelebi, Serdar, Günbaş, İ. Doğan, Uzun, Alper
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.10.2015
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Abstract The expansion of biodiesel industry is expected to introduce over three million tons of glycerol into the market in 2020. Various routes have been proposed to produce glycerol-based value-added products to sustain renewable glycerol and biodiesel industries. One of these routes is the catalytic etherification of glycerol with isobutene for producing fuel oxygenate glycerol ethers as an alternative to today's petroleum based oxygenates. The products of the etherification of glycerol with isobutene are mono-, di-, and tri-tertiary butyl ethers of glycerol (MTBG, DTBG, and TTBG) and dimers of isobutene (DIB). Among these, DTBG and TTBG are the desired products for fuel blends because of their better blending properties. Different heterogeneous catalysts including acidic ion exchange resins (e.g. Amberlyst 15 and 36), sulfonated wide pore zeolites (e.g. zeolite Beta and Y), sulfonated mesoporous silica (e.g. MCM-41 and SBA-15) and some functionalized porous materials (e.g. sulfonated peanut shell, sulfonated aerogel, sulfonated graphene, spherical silica supported Hyflon) have been proved to demonstrate superior catalytic activity with complete glycerol conversion and over 90mol% selectivity to the desired ethers. Here, we review the studies on glycerol etherification with isobutene from 1990s to the first half of 2015 specifically focusing on structure–performance relationships in heterogeneous catalysts. [Display omitted] •Literature on glycerol etherification with isobutene is reviewed.•Structure–performance relationships in solid catalysts are discussed.•Parameters controlling product selectivity and catalytic activity are elaborated.•Suggestions on future research subjects are provided.
AbstractList The expansion of biodiesel industry is expected to introduce over three million tons of glycerol into the market in 2020. Various routes have been proposed to produce glycerol-based value-added products to sustain renewable glycerol and biodiesel industries. One of these routes is the catalytic etherification of glycerol with isobutene for producing fuel oxygenate glycerol ethers as an alternative to today's petroleum based oxygenates. The products of the etherification of glycerol with isobutene are mono-, di-, and tri-tertiary butyl ethers of glycerol (MTBG, DTBG, and TTBG) and dimers of isobutene (DIB). Among these, DTBG and TTBG are the desired products for fuel blends because of their better blending properties. Different heterogeneous catalysts including acidic ion exchange resins (e.g. Amberlyst 15 and 36), sulfonated wide pore zeolites (e.g. zeolite Beta and Y), sulfonated mesoporous silica (e.g. MCM-41 and SBA-15) and some functionalized porous materials (e.g. sulfonated peanut shell, sulfonated aerogel, sulfonated graphene, spherical silica supported Hyflon) have been proved to demonstrate superior catalytic activity with complete glycerol conversion and over 90 mol% selectivity to the desired ethers. Here, we review the studies on glycerol etherification with isobutene from 1990s to the first half of 2015 specifically focusing on structure-performance relationships in heterogeneous catalysts.
The expansion of biodiesel industry is expected to introduce over three million tons of glycerol into the market in 2020. Various routes have been proposed to produce glycerol-based value-added products to sustain renewable glycerol and biodiesel industries. One of these routes is the catalytic etherification of glycerol with isobutene for producing fuel oxygenate glycerol ethers as an alternative to today's petroleum based oxygenates. The products of the etherification of glycerol with isobutene are mono-, di-, and tri-tertiary butyl ethers of glycerol (MTBG, DTBG, and TTBG) and dimers of isobutene (DIB). Among these, DTBG and TTBG are the desired products for fuel blends because of their better blending properties. Different heterogeneous catalysts including acidic ion exchange resins (e.g. Amberlyst 15 and 36), sulfonated wide pore zeolites (e.g. zeolite Beta and Y), sulfonated mesoporous silica (e.g. MCM-41 and SBA-15) and some functionalized porous materials (e.g. sulfonated peanut shell, sulfonated aerogel, sulfonated graphene, spherical silica supported Hyflon) have been proved to demonstrate superior catalytic activity with complete glycerol conversion and over 90mol% selectivity to the desired ethers. Here, we review the studies on glycerol etherification with isobutene from 1990s to the first half of 2015 specifically focusing on structure–performance relationships in heterogeneous catalysts. [Display omitted] •Literature on glycerol etherification with isobutene is reviewed.•Structure–performance relationships in solid catalysts are discussed.•Parameters controlling product selectivity and catalytic activity are elaborated.•Suggestions on future research subjects are provided.
The expansion of biodiesel industry is expected to introduce over three million tons of glycerol into the market in 2020. Various routes have been proposed to produce glycerol-based value-added products to sustain renewable glycerol and biodiesel industries. One of these routes is the catalytic etherification of glycerol with isobutene for producing fuel oxygenate glycerol ethers as an alternative to today's petroleum based oxygenates. The products of the etherification of glycerol with isobutene are mono-, di-, and tri-tertiary butyl ethers of glycerol (MTBG, DTBG, and TTBG) and dimers of isobutene (DIB). Among these, DTBG and TTBG are the desired products for fuel blends because of their better blending properties. Different heterogeneous catalysts including acidic ion exchange resins (e.g. Amberlyst 15 and 36), sulfonated wide pore zeolites (e.g. zeolite Beta and Y), sulfonated mesoporous silica (e.g. MCM-41 and SBA-15) and some functionalized porous materials (e.g. sulfonated peanut shell, sulfonated aerogel, sulfonated graphene, spherical silica supported Hyflon) have been proved to demonstrate superior catalytic activity with complete glycerol conversion and over 90mol% selectivity to the desired ethers. Here, we review the studies on glycerol etherification with isobutene from 1990s to the first half of 2015 specifically focusing on structure–performance relationships in heterogeneous catalysts.
Author Bağlar, Nur
Bozkurt, Özge D.
Çelebi, Serdar
Günbaş, İ. Doğan
Tunç, F. Meliz
Uzun, Alper
Author_xml – sequence: 1
  givenname: Özge D.
  surname: Bozkurt
  fullname: Bozkurt, Özge D.
  organization: Department of Chemical and Biological Engineering, Koç University, Rumelifeneri Yolu, 34450, Sariyer, Istanbul, Turkey
– sequence: 2
  givenname: F. Meliz
  surname: Tunç
  fullname: Tunç, F. Meliz
  organization: Turkish Petroleum Refineries Co. (TÜPRAŞ) R&D Center, Guney Mah. Petrol Cad., 41790 Korfez, Kocaeli, Turkey
– sequence: 3
  givenname: Nur
  surname: Bağlar
  fullname: Bağlar, Nur
  organization: Turkish Petroleum Refineries Co. (TÜPRAŞ) R&D Center, Guney Mah. Petrol Cad., 41790 Korfez, Kocaeli, Turkey
– sequence: 4
  givenname: Serdar
  surname: Çelebi
  fullname: Çelebi, Serdar
  organization: Turkish Petroleum Refineries Co. (TÜPRAŞ) R&D Center, Guney Mah. Petrol Cad., 41790 Korfez, Kocaeli, Turkey
– sequence: 5
  givenname: İ. Doğan
  surname: Günbaş
  fullname: Günbaş, İ. Doğan
  email: idgunbas@gmail.com
  organization: Turkish Petroleum Refineries Co. (TÜPRAŞ) R&D Center, Guney Mah. Petrol Cad., 41790 Korfez, Kocaeli, Turkey
– sequence: 6
  givenname: Alper
  surname: Uzun
  fullname: Uzun, Alper
  email: auzun@ku.edu.tr
  organization: Department of Chemical and Biological Engineering, Koç University, Rumelifeneri Yolu, 34450, Sariyer, Istanbul, Turkey
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Keywords Heterogeneous catalyst
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Glycerol etherification
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Snippet The expansion of biodiesel industry is expected to introduce over three million tons of glycerol into the market in 2020. Various routes have been proposed to...
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SubjectTerms additives
Alternative fuels
Arachis hypogaea
Biodiesel
Catalysis
Catalysts
catalytic activity
Ethers
Fuels
glycerol
Glycerol etherification
Glycerol ethers
Glycerols
Graphene
Heterogeneous catalyst
industry
ion exchange resins
markets
mixing
Oxygenate fuel additive
peanuts
petroleum
porous media
silica
value-added products
zeolites
Title Alternative fuel additives from glycerol by etherification with isobutene: Structure–performance relationships in solid catalysts
URI https://dx.doi.org/10.1016/j.fuproc.2015.06.047
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https://www.proquest.com/docview/2000471242
Volume 138
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