Graphene-based nanocomposite anodes for lithium-ion batteries

Graphene-based nanocomposites have been demonstrated to be promising high-capacity anodes for lithium ion batteries to satisfy the ever-growing demands for higher capacity, longer cycle life and better high-rate performance. Synergetic effects between graphene and the introduced second-phase compone...

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Published inNanoscale Vol. 6; no. 2; pp. 11528 - 11552
Main Authors Sun, Weiwei, Wang, Yong
Format Journal Article
LanguageEnglish
Published England 01.01.2014
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Abstract Graphene-based nanocomposites have been demonstrated to be promising high-capacity anodes for lithium ion batteries to satisfy the ever-growing demands for higher capacity, longer cycle life and better high-rate performance. Synergetic effects between graphene and the introduced second-phase component are generally observed. In this feature review article, we will focus on the recent work on four different categories of graphene-based nanocomposite anodes by us and others: graphene-transitional metal oxide, graphene-Sn/Si/Ge, graphene-metal sulfide, and graphene-carbon nanotubes. For the supported materials on graphene, we will emphasize the non-zero dimensional (non-particle) morphologies such as two dimensional nanosheet/nanoplate and one dimensional nanorod/nanofibre/nanotube morphologies. The synthesis strategies and lithium-ion storage properties of these highlighted electrode morphologies are distinct from those of the commonly obtained zero dimensional nanoparticles. We aim to stress the importance of structure matching in the composites and their morphology-dependent lithium-storage properties and mechanisms. Graphene-based nanocomposite anodes are reviewed with emphasis on the structure matching and interaction between graphene and the second-phase component and their Li-ion storage performances.
AbstractList Graphene-based nanocomposites have been demonstrated to be promising high-capacity anodes for lithium ion batteries to satisfy the ever-growing demands for higher capacity, longer cycle life and better high-rate performance. Synergetic effects between graphene and the introduced second-phase component are generally observed. In this feature review article, we will focus on the recent work on four different categories of graphene-based nanocomposite anodes by us and others: graphene-transitional metal oxide, graphene-Sn/Si/Ge, graphene-metal sulfide, and graphene-carbon nanotubes. For the supported materials on graphene, we will emphasize the non-zero dimensional (non-particle) morphologies such as two dimensional nanosheet/nanoplate and one dimensional nanorod/nanofibre/nanotube morphologies. The synthesis strategies and lithium-ion storage properties of these highlighted electrode morphologies are distinct from those of the commonly obtained zero dimensional nanoparticles. We aim to stress the importance of structure matching in the composites and their morphology-dependent lithium-storage properties and mechanisms. Graphene-based nanocomposite anodes are reviewed with emphasis on the structure matching and interaction between graphene and the second-phase component and their Li-ion storage performances.
Graphene-based nanocomposites have been demonstrated to be promising high-capacity anodes for lithium ion batteries to satisfy the ever-growing demands for higher capacity, longer cycle life and better high-rate performance. Synergetic effects between graphene and the introduced second-phase component are generally observed. In this feature review article, we will focus on the recent work on four different categories of graphene-based nanocomposite anodes by us and others: graphene-transitional metal oxide, graphene–Sn/Si/Ge, graphene–metal sulfide, and graphene–carbon nanotubes. For the supported materials on graphene, we will emphasize the non-zero dimensional (non-particle) morphologies such as two dimensional nanosheet/nanoplate and one dimensional nanorod/nanofibre/nanotube morphologies. The synthesis strategies and lithium-ion storage properties of these highlighted electrode morphologies are distinct from those of the commonly obtained zero dimensional nanoparticles. We aim to stress the importance of structure matching in the composites and their morphology-dependent lithium-storage properties and mechanisms.
Graphene-based nanocomposites have been demonstrated to be promising high-capacity anodes for lithium ion batteries to satisfy the ever-growing demands for higher capacity, longer cycle life and better high-rate performance. Synergetic effects between graphene and the introduced second-phase component are generally observed. In this feature review article, we will focus on the recent work on four different categories of graphene-based nanocomposite anodes by us and others: graphene-transitional metal oxide, graphene-Sn/Si/Ge, graphene-metal sulfide, and graphene-carbon nanotubes. For the supported materials on graphene, we will emphasize the non-zero dimensional (non-particle) morphologies such as two dimensional nanosheet/nanoplate and one dimensional nanorod/nanofibre/nanotube morphologies. The synthesis strategies and lithium-ion storage properties of these highlighted electrode morphologies are distinct from those of the commonly obtained zero dimensional nanoparticles. We aim to stress the importance of structure matching in the composites and their morphology-dependent lithium-storage properties and mechanisms.Graphene-based nanocomposites have been demonstrated to be promising high-capacity anodes for lithium ion batteries to satisfy the ever-growing demands for higher capacity, longer cycle life and better high-rate performance. Synergetic effects between graphene and the introduced second-phase component are generally observed. In this feature review article, we will focus on the recent work on four different categories of graphene-based nanocomposite anodes by us and others: graphene-transitional metal oxide, graphene-Sn/Si/Ge, graphene-metal sulfide, and graphene-carbon nanotubes. For the supported materials on graphene, we will emphasize the non-zero dimensional (non-particle) morphologies such as two dimensional nanosheet/nanoplate and one dimensional nanorod/nanofibre/nanotube morphologies. The synthesis strategies and lithium-ion storage properties of these highlighted electrode morphologies are distinct from those of the commonly obtained zero dimensional nanoparticles. We aim to stress the importance of structure matching in the composites and their morphology-dependent lithium-storage properties and mechanisms.
Author Wang, Yong
Sun, Weiwei
AuthorAffiliation Department of Chemical Engineering
Shanghai University
School of Environmental and Chemical Engineering
AuthorAffiliation_xml – name: Department of Chemical Engineering
– name: Shanghai University
– name: School of Environmental and Chemical Engineering
Author_xml – sequence: 1
  givenname: Weiwei
  surname: Sun
  fullname: Sun, Weiwei
– sequence: 2
  givenname: Yong
  surname: Wang
  fullname: Wang, Yong
BackLink https://www.ncbi.nlm.nih.gov/pubmed/25177843$$D View this record in MEDLINE/PubMed
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Notes Weiwei Sun was born in 1982 and received her BS degree (2004) in chemistry from Shanxi Normal University and Ph.D. (2009) in chemistry from East China Normal University. She was a postdoctoral fellow in Fudan University, China and Wollongong University, Australia, before joining Shanghai University. She is currently a lecturer in the Department of Chemical Engineering. Her research interests include materials for lithium ion batteries and hydrogen storage.
Yong Wang was born in 1976 and received his B Eng (1997) and a M Eng (2000) in chemical engineering from Tianjin University, China, and a Ph.D. (2004) in chemical engineering from the National University of Singapore. He worked as a research fellow in the Singapore-Massachusetts Institute of Technology Alliance from 2004 to 2006. He is currently a Professor and the Head of the Department of Chemical Engineering of Shanghai University. His current research interests focus on nanomaterials for energy storage and environmental applications.
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Snippet Graphene-based nanocomposites have been demonstrated to be promising high-capacity anodes for lithium ion batteries to satisfy the ever-growing demands for...
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Title Graphene-based nanocomposite anodes for lithium-ion batteries
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