Low-cost adsorbents from bio-waste for the removal of dyes from aqueous solution

Activated carbons (ACs) were developed from bio-waste materials like rice husk and peanut shell (PS) by various physicochemical activation methods. PS char digested in nitric acid followed by treatment at 673 K resulted in high surface area up to ∼585 m 2 /g. The novelty of the present study is the...

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Published inEnvironmental science and pollution research international Vol. 20; no. 6; pp. 4111 - 4124
Main Authors Manoj Kumar Reddy, P., Mahammadunnisa, Sk, Ramaraju, B., Sreedhar, B., Subrahmanyam, Ch
Format Journal Article
LanguageEnglish
Published Berlin/Heidelberg Springer-Verlag 01.06.2013
Springer Nature B.V
Subjects
Activated carbon
Activation
Adsorbents
Adsorption
Aquatic Pollution
Aqueous solutions
Atmospheric Protection/Air Quality Control/Air Pollution
Bioremediation
Carbon - chemistry
Color removal
Coloring Agents - chemistry
Coloring Agents - isolation & purification
Dyes
Earth and Environmental Science
Ecotoxicology
Environment
Environmental Chemistry
Environmental Health
Fourier transforms
Functional groups
Hydrogen Peroxide
Hydrogen-Ion Concentration
Industrial wastes
Infrared spectroscopy
Kinetics
Methylene blue
Methylene Blue - chemistry
Methylene Blue - isolation & purification
Nitric acid
Photoelectron Spectroscopy
Pollutants
Polystyrene resins
Research Article
Rice
Solutions
Studies
Surface chemistry
Temperature
Textiles
Thermodynamics
Waste materials
Waste Water Technology
Water Management
Water Pollutants, Chemical
Water Pollution Control
Water Purification - economics
Water Purification - methods
India
Rice husk
Adsorption
Surface analysis
Activated carbon
Peanut shell
Methylene blue
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Abstract Activated carbons (ACs) were developed from bio-waste materials like rice husk and peanut shell (PS) by various physicochemical activation methods. PS char digested in nitric acid followed by treatment at 673 K resulted in high surface area up to ∼585 m 2 /g. The novelty of the present study is the identification of oxygen functional groups formed on the surface of activated carbons by infrared and X-ray photoelectron spectroscopy and quantification by using temperature programmed decomposition (TPD). Typical TPD data indicated that each activation method may lead to varying amounts of acidic and basic functional groups on the surface of the adsorbent, which may be a crucial factor in determining the adsorption capacity. It was shown that ACs developed during the present study are good adsorbents, especially for the removal of a model textile dye methylene blue (MB) from aqueous solution. As MB is a basic dye, H 2 O 2 -treated rice husk showed the best adsorption capacity, which is in agreement with the acidic groups present on the surface. Removal of the dye followed Langmuir isotherm model, whereas MB adsorption on ACs followed pseudo-second-order kinetics.
AbstractList Activated carbons (AC) were developed from bio-waste materials like rice husk and peanut shell (PS) by various physicochemical activation methods. PS char digested in nitric acid followed by treatment at 673 K resulted in high surface area up to 585 m2/g. The novelty of the present study is the identification of oxygen functional groups formed on the surface of activated carbons by infrared and X-ray photoelectron spectroscopy and quantification by using temperature programmed decomposition (TPD). Typical TPD data indicated that each activation method may lead to varying amounts of acidic and basic functional groups on the surface of the adsorbent, which may be a crucial factor in determining the adsorption capacity. It was shown that ACs developed during the present study are good adsorbents, especially for the removal of a model textile dye methylene blue (MB) from aqueous solution. As MB is a basic dye, H2O2-treated rice husk showed the best adsorption capacity, which is in agreement with the acidic groups present on the surface. Removal of the dye followed Langmuir isotherm model, whereas MB adsorption on ACs followed pseudo-second-order kinetics. [PUBLICATION ABSTRACT]
Activated carbons (ACs) were developed from bio-waste materials like rice husk and peanut shell (PS) by various physicochemical activation methods. PS char digested in nitric acid followed by treatment at 673 K resulted in high surface area up to ∼585 m 2 /g. The novelty of the present study is the identification of oxygen functional groups formed on the surface of activated carbons by infrared and X-ray photoelectron spectroscopy and quantification by using temperature programmed decomposition (TPD). Typical TPD data indicated that each activation method may lead to varying amounts of acidic and basic functional groups on the surface of the adsorbent, which may be a crucial factor in determining the adsorption capacity. It was shown that ACs developed during the present study are good adsorbents, especially for the removal of a model textile dye methylene blue (MB) from aqueous solution. As MB is a basic dye, H 2 O 2 -treated rice husk showed the best adsorption capacity, which is in agreement with the acidic groups present on the surface. Removal of the dye followed Langmuir isotherm model, whereas MB adsorption on ACs followed pseudo-second-order kinetics.
Activated carbons (ACs) were developed from bio-waste materials like rice husk and peanut shell (PS) by various physicochemical activation methods. PS char digested in nitric acid followed by treatment at 673 K resulted in high surface area up to 585 m super(2)/g. The novelty of the present study is the identification of oxygen functional groups formed on the surface of activated carbons by infrared and X-ray photoelectron spectroscopy and quantification by using temperature programmed decomposition (TPD). Typical TPD data indicated that each activation method may lead to varying amounts of acidic and basic functional groups on the surface of the adsorbent, which may be a crucial factor in determining the adsorption capacity. It was shown that ACs developed during the present study are good adsorbents, especially for the removal of a model textile dye methylene blue (MB) from aqueous solution. As MB is a basic dye, H sub(2)O sub(2)-treated rice husk showed the best adsorption capacity, which is in agreement with the acidic groups present on the surface. Removal of the dye followed Langmuir isotherm model, whereas MB adsorption on ACs followed pseudo-second-order kinetics.
Activated carbons (ACs) were developed from bio-waste materials like rice husk and peanut shell (PS) by various physicochemical activation methods. PS char digested in nitric acid followed by treatment at 673 K resulted in high surface area up to ∼585 m(2)/g. The novelty of the present study is the identification of oxygen functional groups formed on the surface of activated carbons by infrared and X-ray photoelectron spectroscopy and quantification by using temperature programmed decomposition (TPD). Typical TPD data indicated that each activation method may lead to varying amounts of acidic and basic functional groups on the surface of the adsorbent, which may be a crucial factor in determining the adsorption capacity. It was shown that ACs developed during the present study are good adsorbents, especially for the removal of a model textile dye methylene blue (MB) from aqueous solution. As MB is a basic dye, H(2)O(2)-treated rice husk showed the best adsorption capacity, which is in agreement with the acidic groups present on the surface. Removal of the dye followed Langmuir isotherm model, whereas MB adsorption on ACs followed pseudo-second-order kinetics.
Author Mahammadunnisa, Sk
Sreedhar, B.
Manoj Kumar Reddy, P.
Ramaraju, B.
Subrahmanyam, Ch
Author_xml – sequence: 1
  givenname: P.
  surname: Manoj Kumar Reddy
  fullname: Manoj Kumar Reddy, P.
  organization: Department of Chemistry, Indian Institute of Technology
– sequence: 2
  givenname: Sk
  surname: Mahammadunnisa
  fullname: Mahammadunnisa, Sk
  organization: Department of Chemistry, Indian Institute of Technology
– sequence: 3
  givenname: B.
  surname: Ramaraju
  fullname: Ramaraju, B.
  organization: Department of Chemistry, Indian Institute of Technology
– sequence: 4
  givenname: B.
  surname: Sreedhar
  fullname: Sreedhar, B.
  organization: Inorganic Chemistry Division, Indian Institute of Chemical Technology
– sequence: 5
  givenname: Ch
  surname: Subrahmanyam
  fullname: Subrahmanyam, Ch
  email: csubbu@iith.ac.in
  organization: Department of Chemistry, Indian Institute of Technology
BackLink https://www.ncbi.nlm.nih.gov/pubmed/23233187$$D View this record in MEDLINE/PubMed
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IEDL.DBID U2A
ISSN 0944-1344
IngestDate Fri Oct 25 08:25:48 EDT 2024
Fri Oct 25 07:24:52 EDT 2024
Thu Oct 10 21:10:34 EDT 2024
Thu Sep 12 19:50:07 EDT 2024
Tue Oct 15 23:43:27 EDT 2024
Sat Dec 16 12:04:25 EST 2023
IsPeerReviewed true
IsScholarly true
Issue 6
Keywords Rice husk
Adsorption
Surface analysis
Activated carbon
Peanut shell
Methylene blue
Language English
LinkModel DirectLink
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crossref_primary_10_1007_s11356_012_1360_8
pubmed_primary_23233187
springer_journals_10_1007_s11356_012_1360_8
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PublicationPlace Berlin/Heidelberg
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PublicationTitle Environmental science and pollution research international
PublicationTitleAbbrev Environ Sci Pollut Res
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Publisher Springer-Verlag
Springer Nature B.V
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Snippet Activated carbons (ACs) were developed from bio-waste materials like rice husk and peanut shell (PS) by various physicochemical activation methods. PS char...
Activated carbons (AC) were developed from bio-waste materials like rice husk and peanut shell (PS) by various physicochemical activation methods. PS char...
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SubjectTerms Activated carbon
Activation
Adsorbents
Adsorption
Aquatic Pollution
Aqueous solutions
Atmospheric Protection/Air Quality Control/Air Pollution
Bioremediation
Carbon - chemistry
Color removal
Coloring Agents - chemistry
Coloring Agents - isolation & purification
Dyes
Earth and Environmental Science
Ecotoxicology
Environment
Environmental Chemistry
Environmental Health
Fourier transforms
Functional groups
Hydrogen Peroxide
Hydrogen-Ion Concentration
Industrial wastes
Infrared spectroscopy
Kinetics
Methylene blue
Methylene Blue - chemistry
Methylene Blue - isolation & purification
Nitric acid
Photoelectron Spectroscopy
Pollutants
Polystyrene resins
Research Article
Rice
Solutions
Studies
Surface chemistry
Temperature
Textiles
Thermodynamics
Waste materials
Waste Water Technology
Water Management
Water Pollutants, Chemical
Water Pollution Control
Water Purification - economics
Water Purification - methods
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Title Low-cost adsorbents from bio-waste for the removal of dyes from aqueous solution
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