The nickel–carbon asymmetric supercapacitor—Performance, energy density and electrode mass ratios

The performance of nickel hydroxide/carbon asymmetric supercapacitors has been studied with a range of positive and negative active material ratios. The utilisation of the nickel hydroxide electrode in asymmetric supercapacitors was found to be a function of the mass ratio of the positive and negati...

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Published inElectrochimica acta Vol. 54; no. 2; pp. 535 - 539
Main Authors Duffy, N.W., Baldsing, W., Pandolfo, A.G.
Format Journal Article
LanguageEnglish
Published Kidlington Elsevier Ltd 30.12.2008
Elsevier
Subjects
Applied sciences
Asymmetric supercapacitor
Capacitors. Resistors. Filters
Electrical engineering. Electrical power engineering
Energy density
Exact sciences and technology
Nickel hydroxide
Utilisation
Various equipment and components
Asymmetric supercapacitor
Energy density
Nickel hydroxide
Utilisation
Nickel Hydroxides
Transition metal
Electrolytic capacitor
Carbon
Electrodes
Mass ratio
Supercapacitor
Performance
Specific capacity
Electrical characteristic
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Abstract The performance of nickel hydroxide/carbon asymmetric supercapacitors has been studied with a range of positive and negative active material ratios. The utilisation of the nickel hydroxide electrode in asymmetric supercapacitors was found to be a function of the mass ratio of the positive and negative electrode materials and not independent as previously assumed. Previous models describing the behaviour of asymmetric supercapacitors assumed that the voltage swing was entirely due to the polarisable electrode. These models were found to be inadequate for describing the rate dependant charge/discharge behaviour of asymmetric supercapacitors. The mass ratio of the active materials was determined to be an important factor in predicting the observed behaviour and has been incorporated into an improved model.
AbstractList The performance of nickel hydroxide/carbon asymmetric supercapacitors has been studied with a range of positive and negative active material ratios. The utilisation of the nickel hydroxide electrode in asymmetric supercapacitors was found to be a function of the mass ratio of the positive and negative electrode materials and not independent as previously assumed. Previous models describing the behaviour of asymmetric supercapacitors assumed that the voltage swing was entirely due to the polarisable electrode. These models were found to be inadequate for describing the rate dependant charge/discharge behaviour of asymmetric supercapacitors. The mass ratio of the active materials was determined to be an important factor in predicting the observed behaviour and has been incorporated into an improved model.
Author Baldsing, W.
Duffy, N.W.
Pandolfo, A.G.
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Issue 2
Keywords Asymmetric supercapacitor
Energy density
Nickel hydroxide
Utilisation
Nickel Hydroxides
Transition metal
Electrolytic capacitor
Carbon
Electrodes
Mass ratio
Supercapacitor
Performance
Specific capacity
Electrical characteristic
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Snippet The performance of nickel hydroxide/carbon asymmetric supercapacitors has been studied with a range of positive and negative active material ratios. The...
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StartPage 535
SubjectTerms Applied sciences
Asymmetric supercapacitor
Capacitors. Resistors. Filters
Electrical engineering. Electrical power engineering
Energy density
Exact sciences and technology
Nickel hydroxide
Utilisation
Various equipment and components
Title The nickel–carbon asymmetric supercapacitor—Performance, energy density and electrode mass ratios
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