Heteroatom coordination induces electric field polarization of single Pt sites to promote hydrogen evolution activity
Herein, we reported a kind of single Pt site (Pt-SA) stabilized on an MXene support (Pt-SA/MXene) via the formation of Pt-O and Pt-Ti bonds to effectively catalyze the hydrogen evolution reaction (HER). Due to the local electric field polarization derived from its unique asymmetric coordination, Pt-...
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| Published in | Nanoscale Vol. 13; no. 15; pp. 7134 - 7139 |
|---|---|
| Main Authors | , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
England
Royal Society of Chemistry
21.04.2021
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| Subjects | |
| Online Access | Get full text |
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| Abstract | Herein, we reported a kind of single Pt site (Pt-SA) stabilized on an MXene support (Pt-SA/MXene)
via
the formation of Pt-O and Pt-Ti bonds to effectively catalyze the hydrogen evolution reaction (HER). Due to the local electric field polarization derived from its unique asymmetric coordination, Pt-SA/MXene displays remarkably higher catalytic HER activity in an alkaline electrolyte. In detail, the Pt-SA/MXene electrocatalyst only needs a low overpotential of 33 mV to reach a current density of 10 mA cm
−2
and maintains the performance over 27 h. Besides, Pt-SA/MXene also has a competitive mass activity, 23.5 A mg
Pt
−1
, at an overpotential of 100 mV, which is 29.4 times greater than that of the commercial Pt/C counterpart. Density functional theory (DFT) calculations revealed that the polarized electric field could efficiently tailor the electronic structure of Pt-SA/MXene and reduce the energy barrier of adsorption/desorption of the H* intermediate step, further improving its HER catalytic activity.
Single Pt atomic sites are stabilized on MXene support
via
the formation of Pt-O and Pt-Ti bonds. The unique asymmetric coordination environment of single Pt sites induces local electric field polarization, which remarkably enhances HER activity. |
|---|---|
| AbstractList | Herein, we reported a kind of single Pt site (Pt-SA) stabilized on an MXene support (Pt-SA/MXene) via the formation of Pt–O and Pt–Ti bonds to effectively catalyze the hydrogen evolution reaction (HER). Due to the local electric field polarization derived from its unique asymmetric coordination, Pt-SA/MXene displays remarkably higher catalytic HER activity in an alkaline electrolyte. In detail, the Pt-SA/MXene electrocatalyst only needs a low overpotential of 33 mV to reach a current density of 10 mA cm−2 and maintains the performance over 27 h. Besides, Pt-SA/MXene also has a competitive mass activity, 23.5 A mgPt−1, at an overpotential of 100 mV, which is 29.4 times greater than that of the commercial Pt/C counterpart. Density functional theory (DFT) calculations revealed that the polarized electric field could efficiently tailor the electronic structure of Pt-SA/MXene and reduce the energy barrier of adsorption/desorption of the H* intermediate step, further improving its HER catalytic activity. Herein, we reported a kind of single Pt site (Pt-SA) stabilized on an MXene support (Pt-SA/MXene) via the formation of Pt-O and Pt-Ti bonds to effectively catalyze the hydrogen evolution reaction (HER). Due to the local electric field polarization derived from its unique asymmetric coordination, Pt-SA/MXene displays remarkably higher catalytic HER activity in an alkaline electrolyte. In detail, the Pt-SA/MXene electrocatalyst only needs a low overpotential of 33 mV to reach a current density of 10 mA cm-2 and maintains the performance over 27 h. Besides, Pt-SA/MXene also has a competitive mass activity, 23.5 A mgPt-1, at an overpotential of 100 mV, which is 29.4 times greater than that of the commercial Pt/C counterpart. Density functional theory (DFT) calculations revealed that the polarized electric field could efficiently tailor the electronic structure of Pt-SA/MXene and reduce the energy barrier of adsorption/desorption of the H* intermediate step, further improving its HER catalytic activity.Herein, we reported a kind of single Pt site (Pt-SA) stabilized on an MXene support (Pt-SA/MXene) via the formation of Pt-O and Pt-Ti bonds to effectively catalyze the hydrogen evolution reaction (HER). Due to the local electric field polarization derived from its unique asymmetric coordination, Pt-SA/MXene displays remarkably higher catalytic HER activity in an alkaline electrolyte. In detail, the Pt-SA/MXene electrocatalyst only needs a low overpotential of 33 mV to reach a current density of 10 mA cm-2 and maintains the performance over 27 h. Besides, Pt-SA/MXene also has a competitive mass activity, 23.5 A mgPt-1, at an overpotential of 100 mV, which is 29.4 times greater than that of the commercial Pt/C counterpart. Density functional theory (DFT) calculations revealed that the polarized electric field could efficiently tailor the electronic structure of Pt-SA/MXene and reduce the energy barrier of adsorption/desorption of the H* intermediate step, further improving its HER catalytic activity. Herein, we reported a kind of single Pt site (Pt-SA) stabilized on an MXene support (Pt-SA/MXene) via the formation of Pt-O and Pt-Ti bonds to effectively catalyze the hydrogen evolution reaction (HER). Due to the local electric field polarization derived from its unique asymmetric coordination, Pt-SA/MXene displays remarkably higher catalytic HER activity in an alkaline electrolyte. In detail, the Pt-SA/MXene electrocatalyst only needs a low overpotential of 33 mV to reach a current density of 10 mA cm −2 and maintains the performance over 27 h. Besides, Pt-SA/MXene also has a competitive mass activity, 23.5 A mg Pt −1 , at an overpotential of 100 mV, which is 29.4 times greater than that of the commercial Pt/C counterpart. Density functional theory (DFT) calculations revealed that the polarized electric field could efficiently tailor the electronic structure of Pt-SA/MXene and reduce the energy barrier of adsorption/desorption of the H* intermediate step, further improving its HER catalytic activity. Single Pt atomic sites are stabilized on MXene support via the formation of Pt-O and Pt-Ti bonds. The unique asymmetric coordination environment of single Pt sites induces local electric field polarization, which remarkably enhances HER activity. Herein, we reported a kind of single Pt site (Pt-SA) stabilized on an MXene support (Pt-SA/MXene) via the formation of Pt–O and Pt–Ti bonds to effectively catalyze the hydrogen evolution reaction (HER). Due to the local electric field polarization derived from its unique asymmetric coordination, Pt-SA/MXene displays remarkably higher catalytic HER activity in an alkaline electrolyte. In detail, the Pt-SA/MXene electrocatalyst only needs a low overpotential of 33 mV to reach a current density of 10 mA cm −2 and maintains the performance over 27 h. Besides, Pt-SA/MXene also has a competitive mass activity, 23.5 A mg Pt −1 , at an overpotential of 100 mV, which is 29.4 times greater than that of the commercial Pt/C counterpart. Density functional theory (DFT) calculations revealed that the polarized electric field could efficiently tailor the electronic structure of Pt-SA/MXene and reduce the energy barrier of adsorption/desorption of the H* intermediate step, further improving its HER catalytic activity. Herein, we reported a kind of single Pt site (Pt-SA) stabilized on an MXene support (Pt-SA/MXene) via the formation of Pt-O and Pt-Ti bonds to effectively catalyze the hydrogen evolution reaction (HER). Due to the local electric field polarization derived from its unique asymmetric coordination, Pt-SA/MXene displays remarkably higher catalytic HER activity in an alkaline electrolyte. In detail, the Pt-SA/MXene electrocatalyst only needs a low overpotential of 33 mV to reach a current density of 10 mA cm and maintains the performance over 27 h. Besides, Pt-SA/MXene also has a competitive mass activity, 23.5 A mg , at an overpotential of 100 mV, which is 29.4 times greater than that of the commercial Pt/C counterpart. Density functional theory (DFT) calculations revealed that the polarized electric field could efficiently tailor the electronic structure of Pt-SA/MXene and reduce the energy barrier of adsorption/desorption of the H* intermediate step, further improving its HER catalytic activity. |
| Author | Luo, Jun Sun, Jiaqiang Zhang, Shusheng Qiu, Yuan Bao, Haihong Liu, Xijun Mao, Zhiyong Peng, Xianyun Zhuo, Longchao Mo, Zhaojun |
| AuthorAffiliation | Institute for New Energy Materials and Low-Carbon Technologies and Tianjin Key Lab for Photoelectric Materials & Devices State Key Laboratory of Coal Conversion Chinese Academy of Sciences School of Materials Science and Engineering Civil Aviation University of China College of Chemistry Tianjin University of Technology Xi'an University of Technology Key Laboratory of Civil Aviation Thermal Hazards Prevention and Emergency Response Institute of Coal Chemistry Ganjiang Innovation Academy Zhengzhou University |
| AuthorAffiliation_xml | – name: Zhengzhou University – name: Tianjin University of Technology – name: Chinese Academy of Sciences – name: Key Laboratory of Civil Aviation Thermal Hazards Prevention and Emergency Response – name: School of Materials Science and Engineering – name: Civil Aviation University of China – name: Xi'an University of Technology – name: Institute for New Energy Materials and Low-Carbon Technologies and Tianjin Key Lab for Photoelectric Materials & Devices – name: Institute of Coal Chemistry – name: State Key Laboratory of Coal Conversion – name: College of Chemistry – name: Ganjiang Innovation Academy |
| Author_xml | – sequence: 1 givenname: Xianyun surname: Peng fullname: Peng, Xianyun – sequence: 2 givenname: Haihong surname: Bao fullname: Bao, Haihong – sequence: 3 givenname: Jiaqiang surname: Sun fullname: Sun, Jiaqiang – sequence: 4 givenname: Zhiyong surname: Mao fullname: Mao, Zhiyong – sequence: 5 givenname: Yuan surname: Qiu fullname: Qiu, Yuan – sequence: 6 givenname: Zhaojun surname: Mo fullname: Mo, Zhaojun – sequence: 7 givenname: Longchao surname: Zhuo fullname: Zhuo, Longchao – sequence: 8 givenname: Shusheng surname: Zhang fullname: Zhang, Shusheng – sequence: 9 givenname: Jun surname: Luo fullname: Luo, Jun – sequence: 10 givenname: Xijun surname: Liu fullname: Liu, Xijun |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/33889881$$D View this record in MEDLINE/PubMed |
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| Cites_doi | 10.1021/cr500486u 10.1038/s41467-019-12459-0 10.1038/s41467-020-20336-4 10.1021/jacs.9b12111 10.1021/acs.jpcc.5b11887 10.1038/s41467-020-14848-2 10.1002/aenm.202000882 10.1002/smtd.202000208 10.1038/s41467-019-09765-y 10.1038/ncomms16100 10.1016/j.apcatb.2018.08.075 10.1021/acs.jpcc.7b05270 10.1002/celc.201800507 10.1016/j.apsusc.2015.11.089 10.1126/sciadv.aaw3072 10.1002/anie.201600750 10.1016/j.nanoen.2018.11.034 10.1002/anie.201706921 10.1038/s41557-018-0092-x 10.1039/C9CC04481G 10.1021/acsaem.8b00817 10.1021/acsnano.9b02579 10.1002/anie.201913080 10.1002/anie.201911696 10.1016/j.nanoen.2020.104529 10.1002/asia.201901100 10.1038/s41586-019-1649-6 10.1038/s41467-017-00643-z 10.1038/ncomms13638 |
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| References | Li (D1NR00795E-(cit13)/*[position()=1]) 2020; 13 Zhou (D1NR00795E-(cit17)/*[position()=1]) 2018; 10 Zhang (D1NR00795E-(cit20)/*[position()=1]) 2017; 56 Wang (D1NR00795E-(cit32)/*[position()=1]) 2019; 58 Bao (D1NR00795E-(cit5)/*[position()=1]) 2021; 12 Gao (D1NR00795E-(cit31)/*[position()=1]) 2019; 575 Zhang (D1NR00795E-(cit4)/*[position()=1]) 2019; 55 Huang (D1NR00795E-(cit16)/*[position()=1]) 2019; 5 Cheng (D1NR00795E-(cit8)/*[position()=1]) 2016; 7 Wang (D1NR00795E-(cit21)/*[position()=1]) 2018; 1 Xu (D1NR00795E-(cit2)/*[position()=1]) 2020; 70 Halim (D1NR00795E-(cit23)/*[position()=1]) 2016; 362 Ren (D1NR00795E-(cit14)/*[position()=1]) 2019; 10 Hong (D1NR00795E-(cit22)/*[position()=1]) 2019; 13 Liu (D1NR00795E-(cit18)/*[position()=1]) 2016; 537 Jiang (D1NR00795E-(cit11)/*[position()=1]) 2019; 10 Shen (D1NR00795E-(cit15)/*[position()=1]) 2020; 59 Zhang (D1NR00795E-(cit19)/*[position()=1]) 2020; 10 Zhang (D1NR00795E-(cit3)/*[position()=1]) 2020; 4 Han (D1NR00795E-(cit12)/*[position()=1]) 2020; 142 Pan (D1NR00795E-(cit33)/*[position()=1]) 2019; 56 Pandey (D1NR00795E-(cit29)/*[position()=1]) 2017; 121 Geng (D1NR00795E-(cit10)/*[position()=1]) 2019; 240 Spronsen (D1NR00795E-(cit24)/*[position()=1]) 2017; 8 Huang (D1NR00795E-(cit25)/*[position()=1]) 2013; 6 Li (D1NR00795E-(cit6)/*[position()=1]) 2016; 55 Munnik (D1NR00795E-(cit1)/*[position()=1]) 2015; 115 Jiang (D1NR00795E-(cit30)/*[position()=1]) 2019; 10 Fang (D1NR00795E-(cit26)/*[position()=1]) 2020; 11 Zhang (D1NR00795E-(cit27)/*[position()=1]) 2017; 8 Liu (D1NR00795E-(cit7)/*[position()=1]) 2018; 5 Qiu (D1NR00795E-(cit9)/*[position()=1]) 2019; 14 Ashton (D1NR00795E-(cit28)/*[position()=1]) 2016; 120 |
| References_xml | – volume: 115 start-page: 6687 year: 2015 ident: D1NR00795E-(cit1)/*[position()=1] publication-title: Chem. Rev. doi: 10.1021/cr500486u – volume: 10 start-page: 4500 year: 2019 ident: D1NR00795E-(cit14)/*[position()=1] publication-title: Nat. Commun. doi: 10.1038/s41467-019-12459-0 – volume: 12 start-page: 238 year: 2021 ident: D1NR00795E-(cit5)/*[position()=1] publication-title: Nat. Commun. doi: 10.1038/s41467-020-20336-4 – volume: 142 start-page: 12563 year: 2020 ident: D1NR00795E-(cit12)/*[position()=1] publication-title: J. Am. Chem. Soc. doi: 10.1021/jacs.9b12111 – volume: 120 start-page: 3550 year: 2016 ident: D1NR00795E-(cit28)/*[position()=1] publication-title: J. Phys. Chem. C doi: 10.1021/acs.jpcc.5b11887 – volume: 11 start-page: 1029 year: 2020 ident: D1NR00795E-(cit26)/*[position()=1] publication-title: Nat. Commun. doi: 10.1038/s41467-020-14848-2 – volume: 10 start-page: 2000882 year: 2020 ident: D1NR00795E-(cit19)/*[position()=1] publication-title: Adv. Energy Mater. doi: 10.1002/aenm.202000882 – volume: 4 start-page: 2000208 year: 2020 ident: D1NR00795E-(cit3)/*[position()=1] publication-title: Small Methods doi: 10.1002/smtd.202000208 – volume: 10 start-page: 1743 year: 2019 ident: D1NR00795E-(cit11)/*[position()=1] publication-title: Nat. Commun. doi: 10.1038/s41467-019-09765-y – volume: 8 start-page: 16100 year: 2017 ident: D1NR00795E-(cit27)/*[position()=1] publication-title: Nat. Commun. doi: 10.1038/ncomms16100 – volume: 240 start-page: 234 year: 2019 ident: D1NR00795E-(cit10)/*[position()=1] publication-title: Appl. Catal., B doi: 10.1016/j.apcatb.2018.08.075 – volume: 121 start-page: 13593 year: 2017 ident: D1NR00795E-(cit29)/*[position()=1] publication-title: J. Phys. Chem. C doi: 10.1021/acs.jpcc.7b05270 – volume: 5 start-page: 2963 year: 2018 ident: D1NR00795E-(cit7)/*[position()=1] publication-title: ChemElectroChem doi: 10.1002/celc.201800507 – volume: 362 start-page: 406 year: 2016 ident: D1NR00795E-(cit23)/*[position()=1] publication-title: Appl. Surf. Sci. doi: 10.1016/j.apsusc.2015.11.089 – volume: 5 start-page: 3072 year: 2019 ident: D1NR00795E-(cit16)/*[position()=1] publication-title: Sci. Adv. doi: 10.1126/sciadv.aaw3072 – volume: 55 start-page: 4977 year: 2016 ident: D1NR00795E-(cit6)/*[position()=1] publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.201600750 – volume: 56 start-page: 411 year: 2019 ident: D1NR00795E-(cit33)/*[position()=1] publication-title: Nano Energy doi: 10.1016/j.nanoen.2018.11.034 – volume: 56 start-page: 13694 year: 2017 ident: D1NR00795E-(cit20)/*[position()=1] publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.201706921 – volume: 10 start-page: 974 year: 2018 ident: D1NR00795E-(cit17)/*[position()=1] publication-title: Nat. Chem. doi: 10.1038/s41557-018-0092-x – volume: 10 start-page: 1743 year: 2019 ident: D1NR00795E-(cit30)/*[position()=1] publication-title: Nat. Commun. doi: 10.1038/s41467-019-09765-y – volume: 55 start-page: 10511 year: 2019 ident: D1NR00795E-(cit4)/*[position()=1] publication-title: Chem. Commun. doi: 10.1039/C9CC04481G – volume: 13 start-page: 1482 year: 2020 ident: D1NR00795E-(cit13)/*[position()=1] publication-title: Nano Res. – volume: 1 start-page: 6781 year: 2018 ident: D1NR00795E-(cit21)/*[position()=1] publication-title: ACS Appl. Energy Mater. doi: 10.1021/acsaem.8b00817 – volume: 13 start-page: 8917 year: 2019 ident: D1NR00795E-(cit22)/*[position()=1] publication-title: ACS Nano doi: 10.1021/acsnano.9b02579 – volume: 59 start-page: 2313 year: 2020 ident: D1NR00795E-(cit15)/*[position()=1] publication-title: Angew. Chem. doi: 10.1002/anie.201913080 – volume: 58 start-page: 19060 year: 2019 ident: D1NR00795E-(cit32)/*[position()=1] publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.201911696 – volume: 70 start-page: 104529 year: 2020 ident: D1NR00795E-(cit2)/*[position()=1] publication-title: Nano Energy doi: 10.1016/j.nanoen.2020.104529 – volume: 6 start-page: 350570 year: 2013 ident: D1NR00795E-(cit25)/*[position()=1] publication-title: Int. J. Photoenergy – volume: 14 start-page: 2770 year: 2019 ident: D1NR00795E-(cit9)/*[position()=1] publication-title: Chem. – Asian J. doi: 10.1002/asia.201901100 – volume: 537 start-page: 7620 year: 2016 ident: D1NR00795E-(cit18)/*[position()=1] publication-title: Nature – volume: 575 start-page: 480 year: 2019 ident: D1NR00795E-(cit31)/*[position()=1] publication-title: Nature doi: 10.1038/s41586-019-1649-6 – volume: 8 start-page: 429 year: 2017 ident: D1NR00795E-(cit24)/*[position()=1] publication-title: Nat. Commun. doi: 10.1038/s41467-017-00643-z – volume: 7 start-page: 13638 year: 2016 ident: D1NR00795E-(cit8)/*[position()=1] publication-title: Nat. Commun. doi: 10.1038/ncomms13638 |
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| Snippet | Herein, we reported a kind of single Pt site (Pt-SA) stabilized on an MXene support (Pt-SA/MXene)
via
the formation of Pt-O and Pt-Ti bonds to effectively... Herein, we reported a kind of single Pt site (Pt-SA) stabilized on an MXene support (Pt-SA/MXene) via the formation of Pt–O and Pt–Ti bonds to effectively... Herein, we reported a kind of single Pt site (Pt-SA) stabilized on an MXene support (Pt-SA/MXene) via the formation of Pt-O and Pt-Ti bonds to effectively... Herein, we reported a kind of single Pt site (Pt-SA) stabilized on an MXene support (Pt-SA/MXene) via the formation of Pt–O and Pt–Ti bonds to effectively... |
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| SubjectTerms | Catalytic activity Coordination Density functional theory Electric fields Electrocatalysts Electronic structure Hydrogen evolution reactions Polarization |
| Title | Heteroatom coordination induces electric field polarization of single Pt sites to promote hydrogen evolution activity |
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