Effects of thickness and cycle parameters on fretting wear behavior of CVD diamond coatings on steel substrates
Diamond films have been grown on carbon steel substrates by hot filament chemical vapour deposition (CVD) methods. A Co-containing tungsten-carbide coating prepared by high velocity oxy-fuel spraying was used as an intermediate layer on the steel substrates to minimize the early formation of graphit...
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Published in | Surface & coatings technology Vol. 205; no. 1; pp. 158 - 167 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
Amsterdam
Elsevier B.V
01.09.2010
Elsevier |
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Abstract | Diamond films have been grown on carbon steel substrates by hot filament chemical vapour deposition (CVD) methods. A Co-containing tungsten-carbide coating prepared by high velocity oxy-fuel spraying was used as an intermediate layer on the steel substrates to minimize the early formation of graphite (and thus growth of low quality diamond films) and to enhance the diamond film adhesion. The effects of thickness and cycle parameters on adhesion, tribological behaviour and electrochemical treatment of the diamond film were investigated. The diamond films exhibit excellent adhesion under Rockwell indentation testing (1500
N load) and in high-speed, high-load, long-time reciprocating dry sliding ball-on-flat wear tests against a Si
3N
4 counterface in ambient air (500
rpm, 200
N, 300000 cycles). Time modulated CVD (wherein the CH
4 fraction in the process gas mixture is cycled in time) is shown to yield diamond films offering an exceptional combination of low friction, high hardness, high wear resistance, as well as promising corrosion resistance. |
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AbstractList | Diamond films have been grown on carbon steel substrates by hot filament chemical vapour deposition (CVD) methods. A Co-containing tungsten-carbide coating prepared by high velocity oxy-fuel spraying was used as an intermediate layer on the steel substrates to minimize the early formation of graphite (and thus growth of low quality diamond films) and to enhance the diamond film adhesion. The effects of thickness and cycle parameters on adhesion, tribological behaviour and electrochemical treatment of the diamond film were investigated. The diamond films exhibit excellent adhesion under Rockwell indentation testing (1500N load) and in high-speed, high-load, long-time reciprocating dry sliding ball-on-flat wear tests against a Si3N4 counterface in ambient air (500rpm, 200N, 300000 cycles). Time modulated CVD (wherein the CH4 fraction in the process gas mixture is cycled in time) is shown to yield diamond films offering an exceptional combination of low friction, high hardness, high wear resistance, as well as promising corrosion resistance. Diamond films have been grown on carbon steel substrates by hot filament chemical vapour deposition (CVD) methods. A Co-containing tungsten-carbide coating prepared by high velocity oxy-fuel spraying was used as an intermediate layer on the steel substrates to minimize the early formation of graphite (and thus growth of low quality diamond films) and to enhance the diamond film adhesion. The effects of thickness and cycle parameters on adhesion, tribological behaviour and electrochemical treatment of the diamond film were investigated. The diamond films exhibit excellent adhesion under Rockwell indentation testing (1500 N load) and in high-speed, high-load, long-time reciprocating dry sliding ball-on-flat wear tests against a Si 3N 4 counterface in ambient air (500 rpm, 200 N, 300000 cycles). Time modulated CVD (wherein the CH 4 fraction in the process gas mixture is cycled in time) is shown to yield diamond films offering an exceptional combination of low friction, high hardness, high wear resistance, as well as promising corrosion resistance. |
Author | Ashfold, Michael N.R. Ma, L. Chen, Z. Wei, Qiuping Yu, Z.M. Wang, L. |
Author_xml | – sequence: 1 givenname: Qiuping surname: Wei fullname: Wei, Qiuping organization: School of Materials Science and Engineering, Central South University, Changsha, 410083, PR China – sequence: 2 givenname: Z.M. surname: Yu fullname: Yu, Z.M. email: zhiming@mail.csu.edu.cn organization: School of Materials Science and Engineering, Central South University, Changsha, 410083, PR China – sequence: 3 givenname: Michael N.R. surname: Ashfold fullname: Ashfold, Michael N.R. organization: School of Chemistry, University of Bristol, Bristol BS8 1TS, United Kingdom – sequence: 4 givenname: Z. surname: Chen fullname: Chen, Z. organization: School of Materials Science and Engineering, Central South University, Changsha, 410083, PR China – sequence: 5 givenname: L. surname: Wang fullname: Wang, L. organization: School of Materials Science and Engineering, Central South University, Changsha, 410083, PR China – sequence: 6 givenname: L. surname: Ma fullname: Ma, L. organization: State Key Laboratory of Powder Metallurgy, Central South University, Changsha, 410083, PR China |
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Keywords | CVD diamond films Steel substrates Interlayer Fretting wear Interfacial layer Diamonds Mechanical properties Surface treatments Non metal coating Thin films CVD Thickness Wear Steels Tribology |
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Snippet | Diamond films have been grown on carbon steel substrates by hot filament chemical vapour deposition (CVD) methods. A Co-containing tungsten-carbide coating... |
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SubjectTerms | Adhesive wear Applied sciences Chemical vapor deposition Coatings Contact of materials. Friction. Wear Cross-disciplinary physics: materials science; rheology CVD diamond films Diamond films Exact sciences and technology Filaments Fretting Fretting wear Interlayer Materials science Mechanical properties and methods of testing. Rheology. Fracture mechanics. Tribology Metals. Metallurgy Methods of deposition of films and coatings; film growth and epitaxy Nonmetallic coatings Physics Production techniques Reciprocating Steel substrates Steels Surface treatment Surface treatments Wear tests |
Title | Effects of thickness and cycle parameters on fretting wear behavior of CVD diamond coatings on steel substrates |
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