Controlling disorder in self-assembled colloidal monolayers via evaporative processes

Monolayers of assembled nano-objects with a controlled degree of disorder hold interest in many optical applications, including photovoltaics, light emission, sensing, and structural coloration. Controlled disorder can be achieved through either top-down or bottom-up approaches, but the latter is mo...

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Published inNanoscale Vol. 14; no. 9; pp. 3324 - 3345
Main Authors Roach, Lucien, Hereu, Adrian, Lalanne, Philippe, Duguet, Etienne, Tréguer-Delapierre, Mona, Vynck, Kevin, Drisko, Glenna L
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 07.03.2022
The Royal Society of Chemistry
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Abstract Monolayers of assembled nano-objects with a controlled degree of disorder hold interest in many optical applications, including photovoltaics, light emission, sensing, and structural coloration. Controlled disorder can be achieved through either top-down or bottom-up approaches, but the latter is more suited to large-scale, low-cost fabrication. Disordered colloidal monolayers can be assembled through evaporatively driven convective assembly, a bottom-up process with a wide range of parameters impacting particle placement. Motivated by the photonic applications of such monolayers, in this review we discuss the quantification of monolayer disorder, and the assembly methods that have been used to produce them. We review the impact of particle and solvent properties, as well as the use of substrate patterning, to create the desired spatial distributions of particles.
AbstractList Monolayers of assembled nano-objects with a controlled degree of disorder hold interest in many optical applications, including photovoltaics, light emission, sensing, and structural coloration. Controlled disorder can be achieved through either top-down or bottom-up approaches, but the latter is more suited to large-scale, low-cost fabrication. Disordered colloidal monolayers can be assembled through evaporatively driven convective assembly, a bottom-up process with a wide range of parameters impacting particle placement. Motivated by the photonic applications of such monolayers, in this review we discuss the quantification of monolayer disorder, and the assembly methods that have been used to produce them. We review the impact of particle and solvent properties, as well as the use of substrate patterning, to create the desired spatial distributions of particles.
Monolayers of assembled nano-objects with a controlled degree of disorder hold interest in many optical applications, including photovoltaics, light emission, sensing, and structural coloration. Controlled disorder can be achieved through either top-down or bottom-up approaches, but the latter is more suited to large-scale, low-cost fabrication. Disordered colloidal monolayers can be assembled through evaporatively driven convective assembly, a bottom-up process with a wide range of parameters impacting particle placement. Motivated by the photonic applications of such monolayers, in this review we discuss the quantification of monolayer disorder, and the assembly methods that have been used to produce them. We review the impact of particle and solvent properties, as well as the use of substrate patterning, to create the desired spatial distributions of particles. Monolayers of assembled nano-objects with a controlled degree of disorder hold interest in many optical applications, including photovoltaics, light emission, sensing, and structural coloration.
Author Roach, Lucien
Drisko, Glenna L
Hereu, Adrian
Duguet, Etienne
Lalanne, Philippe
Tréguer-Delapierre, Mona
Vynck, Kevin
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  fullname: Roach, Lucien
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  organization: CNRS, Univ. Bordeaux, Bordeaux INP, ICMCB, UMR 5026, F-33600 Pessac, France. glenna.drisko@icmcb.cnrs.fr
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  orcidid: 0000-0002-6193-0629
  surname: Hereu
  fullname: Hereu, Adrian
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  givenname: Philippe
  orcidid: 0000-0003-1979-2290
  surname: Lalanne
  fullname: Lalanne, Philippe
  organization: IOGS, Univ. Bordeaux, CNRS, LP2N, UMR 5298, F-33400 Talence, France
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  orcidid: 0000-0002-0675-5987
  surname: Duguet
  fullname: Duguet, Etienne
  email: glenna.drisko@icmcb.cnrs.fr
  organization: CNRS, Univ. Bordeaux, Bordeaux INP, ICMCB, UMR 5026, F-33600 Pessac, France. glenna.drisko@icmcb.cnrs.fr
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  givenname: Mona
  orcidid: 0000-0002-3096-6645
  surname: Tréguer-Delapierre
  fullname: Tréguer-Delapierre, Mona
  email: glenna.drisko@icmcb.cnrs.fr
  organization: CNRS, Univ. Bordeaux, Bordeaux INP, ICMCB, UMR 5026, F-33600 Pessac, France. glenna.drisko@icmcb.cnrs.fr
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  givenname: Kevin
  orcidid: 0000-0002-1119-2808
  surname: Vynck
  fullname: Vynck, Kevin
  email: kevin.vynck@univ-lyon1.fr
  organization: Univ. Claude Bernard Lyon 1, CNRS, iLM, UMR 5306, F-69622 Villeurbanne, France. kevin.vynck@univ-lyon1.fr
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  givenname: Glenna L
  orcidid: 0000-0001-6469-9736
  surname: Drisko
  fullname: Drisko, Glenna L
  email: glenna.drisko@icmcb.cnrs.fr
  organization: CNRS, Univ. Bordeaux, Bordeaux INP, ICMCB, UMR 5026, F-33600 Pessac, France. glenna.drisko@icmcb.cnrs.fr
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Snippet Monolayers of assembled nano-objects with a controlled degree of disorder hold interest in many optical applications, including photovoltaics, light emission,...
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SubjectTerms Chemical Sciences
Chemistry
Colloiding
Engineering Sciences
Light emission
Monolayers
Photovoltaic cells
Physics
Self-assembly
Spatial distribution
Substrates
Title Controlling disorder in self-assembled colloidal monolayers via evaporative processes
URI https://www.ncbi.nlm.nih.gov/pubmed/35174843
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https://search.proquest.com/docview/2629858974
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https://pubmed.ncbi.nlm.nih.gov/PMC8900142
Volume 14
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