Characterization of canola oil based polyurethane wood adhesives
A novel bio-based poly (ether ester) polyol containing both primary and secondary functional groups was synthesized from canola oil using a low cost and efficient procedure. In this work, use of the new canola oil derived polyol for the production of polyurethane (PU) adhesives was demonstrated. The...
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Published in | International journal of adhesion and adhesives Vol. 31; no. 6; pp. 559 - 564 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
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01.09.2011
Elsevier |
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Abstract | A novel bio-based poly (ether ester) polyol containing both primary and secondary functional groups was synthesized from canola oil using a low cost and efficient procedure. In this work, use of the new canola oil derived polyol for the production of polyurethane (PU) adhesives was demonstrated. The canola oil based PU adhesives had similar or better adhesive properties in terms of lap shear strength than three commercial PU adhesives. The effect of NCO/OH ratio and temperature on adhesive characteristics on wood bonding was also evaluated by lap shear tests. It was found that the use of an elevated curing temperature (i.e. 100
°C), as well as optimized NCO/OH molar ratio (higher than 1.5/1.0), improved the wood adhesive properties. The overall chemical resistance of bio-based PU adhesives to cold water, acid and alkali was comparable to that of commercial PU adhesives whilst its resistance to hot water was superior. |
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AbstractList | A novel bio-based poly (ether ester) polyol containing both primary and secondary functional groups was synthesized from canola oil using a low cost and efficient procedure. In this work, use of the new canola oil derived polyol for the production of polyurethane (PU) adhesives was demonstrated. The canola oil based PU adhesives had similar or better adhesive properties in terms of lap shear strength than three commercial PU adhesives. The effect of NCO/OH ratio and temperature on adhesive characteristics on wood bonding was also evaluated by lap shear tests. It was found that the use of an elevated curing temperature (i.e. 100
°C), as well as optimized NCO/OH molar ratio (higher than 1.5/1.0), improved the wood adhesive properties. The overall chemical resistance of bio-based PU adhesives to cold water, acid and alkali was comparable to that of commercial PU adhesives whilst its resistance to hot water was superior. A novel bio-based poly (ether ester) polyol containing both primary and secondary functional groups was synthesized from canola oil using a low cost and efficient procedure. In this work, use of the new canola oil derived polyol for the production of polyurethane (PU) adhesives was demonstrated. The canola oil based PU adhesives had similar or better adhesive properties in terms of lap shear strength than three commercial PU adhesives. The effect of NCO/OH ratio and temperature on adhesive characteristics on wood bonding was also evaluated by lap shear tests. It was found that the use of an elevated curing temperature (i.e. 100 degree C), as well as optimized NCO/OH molar ratio (higher than 1.5/1.0), improved the wood adhesive properties. The overall chemical resistance of bio-based PU adhesives to cold water, acid and alkali was comparable to that of commercial PU adhesives whilst its resistance to hot water was superior. |
Author | Liu, Guoguang Curtis, Jonathan M. Kong, Xiaohua |
Author_xml | – sequence: 1 givenname: Xiaohua surname: Kong fullname: Kong, Xiaohua – sequence: 2 givenname: Guoguang surname: Liu fullname: Liu, Guoguang – sequence: 3 givenname: Jonathan M. surname: Curtis fullname: Curtis, Jonathan M. email: jcurtis1@ualberta.ca |
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Keywords | Curing Canola oil based polyurethane Wood adhesive Chemical resistance Lap shearing strength Adhesivity Wood Property composition relationship Mechanical properties Shear strength Vegetable oil Experimental study Polyaddition Rapeseed oil Waterproofness Preparation Polyurethane Crosslinked polymer Surface properties Polyol Chemical properties Monomer Adhesive |
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Snippet | A novel bio-based poly (ether ester) polyol containing both primary and secondary functional groups was synthesized from canola oil using a low cost and... |
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SubjectTerms | Adhesives Applied sciences Canola oil Canola oil based polyurethane Chemical resistance Curing Ethers Exact sciences and technology Lap shearing strength Organic polymers Physicochemistry of polymers Polymers with particular properties Polyols Polyurethane resins Preparation, kinetics, thermodynamics, mechanism and catalysts Shear strength Wood Wood adhesive |
Title | Characterization of canola oil based polyurethane wood adhesives |
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