Characterization of canola oil based polyurethane wood adhesives

A novel bio-based poly (ether ester) polyol containing both primary and secondary functional groups was synthesized from canola oil using a low cost and efficient procedure. In this work, use of the new canola oil derived polyol for the production of polyurethane (PU) adhesives was demonstrated. The...

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Published inInternational journal of adhesion and adhesives Vol. 31; no. 6; pp. 559 - 564
Main Authors Kong, Xiaohua, Liu, Guoguang, Curtis, Jonathan M.
Format Journal Article
LanguageEnglish
Published Kidlington Elsevier Ltd 01.09.2011
Elsevier
Subjects
Adhesives
Applied sciences
Canola oil
Canola oil based polyurethane
Chemical resistance
Curing
Ethers
Exact sciences and technology
Lap shearing strength
Organic polymers
Physicochemistry of polymers
Polymers with particular properties
Polyols
Polyurethane resins
Preparation, kinetics, thermodynamics, mechanism and catalysts
Shear strength
Wood
Wood adhesive
Curing
Canola oil based polyurethane
Wood adhesive
Chemical resistance
Lap shearing strength
Adhesivity
Wood
Property composition relationship
Mechanical properties
Shear strength
Vegetable oil
Experimental study
Polyaddition
Rapeseed oil
Waterproofness
Preparation
Polyurethane
Crosslinked polymer
Surface properties
Polyol
Chemical properties
Monomer
Adhesive
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Abstract A novel bio-based poly (ether ester) polyol containing both primary and secondary functional groups was synthesized from canola oil using a low cost and efficient procedure. In this work, use of the new canola oil derived polyol for the production of polyurethane (PU) adhesives was demonstrated. The canola oil based PU adhesives had similar or better adhesive properties in terms of lap shear strength than three commercial PU adhesives. The effect of NCO/OH ratio and temperature on adhesive characteristics on wood bonding was also evaluated by lap shear tests. It was found that the use of an elevated curing temperature (i.e. 100 °C), as well as optimized NCO/OH molar ratio (higher than 1.5/1.0), improved the wood adhesive properties. The overall chemical resistance of bio-based PU adhesives to cold water, acid and alkali was comparable to that of commercial PU adhesives whilst its resistance to hot water was superior.
AbstractList A novel bio-based poly (ether ester) polyol containing both primary and secondary functional groups was synthesized from canola oil using a low cost and efficient procedure. In this work, use of the new canola oil derived polyol for the production of polyurethane (PU) adhesives was demonstrated. The canola oil based PU adhesives had similar or better adhesive properties in terms of lap shear strength than three commercial PU adhesives. The effect of NCO/OH ratio and temperature on adhesive characteristics on wood bonding was also evaluated by lap shear tests. It was found that the use of an elevated curing temperature (i.e. 100 °C), as well as optimized NCO/OH molar ratio (higher than 1.5/1.0), improved the wood adhesive properties. The overall chemical resistance of bio-based PU adhesives to cold water, acid and alkali was comparable to that of commercial PU adhesives whilst its resistance to hot water was superior.
A novel bio-based poly (ether ester) polyol containing both primary and secondary functional groups was synthesized from canola oil using a low cost and efficient procedure. In this work, use of the new canola oil derived polyol for the production of polyurethane (PU) adhesives was demonstrated. The canola oil based PU adhesives had similar or better adhesive properties in terms of lap shear strength than three commercial PU adhesives. The effect of NCO/OH ratio and temperature on adhesive characteristics on wood bonding was also evaluated by lap shear tests. It was found that the use of an elevated curing temperature (i.e. 100 degree C), as well as optimized NCO/OH molar ratio (higher than 1.5/1.0), improved the wood adhesive properties. The overall chemical resistance of bio-based PU adhesives to cold water, acid and alkali was comparable to that of commercial PU adhesives whilst its resistance to hot water was superior.
Author Liu, Guoguang
Curtis, Jonathan M.
Kong, Xiaohua
Author_xml – sequence: 1
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  givenname: Jonathan M.
  surname: Curtis
  fullname: Curtis, Jonathan M.
  email: jcurtis1@ualberta.ca
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Issue 6
Keywords Curing
Canola oil based polyurethane
Wood adhesive
Chemical resistance
Lap shearing strength
Adhesivity
Wood
Property composition relationship
Mechanical properties
Shear strength
Vegetable oil
Experimental study
Polyaddition
Rapeseed oil
Waterproofness
Preparation
Polyurethane
Crosslinked polymer
Surface properties
Polyol
Chemical properties
Monomer
Adhesive
Language English
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Snippet A novel bio-based poly (ether ester) polyol containing both primary and secondary functional groups was synthesized from canola oil using a low cost and...
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SubjectTerms Adhesives
Applied sciences
Canola oil
Canola oil based polyurethane
Chemical resistance
Curing
Ethers
Exact sciences and technology
Lap shearing strength
Organic polymers
Physicochemistry of polymers
Polymers with particular properties
Polyols
Polyurethane resins
Preparation, kinetics, thermodynamics, mechanism and catalysts
Shear strength
Wood
Wood adhesive
Title Characterization of canola oil based polyurethane wood adhesives
URI https://dx.doi.org/10.1016/j.ijadhadh.2011.05.004
https://search.proquest.com/docview/901670424
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