Gold()-doped films: new routes for efficient room temperature phosphorescent materials

• Published in: Dalton transactions : an international journal of inorganic chemistry Vol. 5; no. 11; pp. 386 - 3815
• Main Authors: de Aquino, Araceli, Caparrós, Francisco J, Truong, Khai-Nghi, Rissanen, Kari, Ferrer, Montserrat, Jung, Yongsik, Choi, Hyeonho, Lima, João Carlos, Rodríguez, Laura
• Format: Journal Article
• Language: English
• Published: England Royal Society of Chemistry 21.03.2021
• Subjects: Acetylene; Chromophores; Crystal structure; Crystallography; Doped films; Emission; Fluorescence; Gold; Phenanthrene; Phosphorescence; Room temperature

The synthesis of four novel gold( i )-phosphane complexes coordinated to 9-phenanthrene chromophore has been carried out through the reaction of 9-phenanthreneboronic acid and the corresponding AuClPR 3 (PR 3 = PPh 3 for triphenylphosphane ( 1a ); 1,4-bis(diphenylphosphanyl)butane or dppb ( 2b ); bi...