Adsorptive separations of alkylphenols using ion-exchange resins
Separation of close boiling point mixtures of alkylphenols, such as p-cresol/2,6-xylenol, m-cresol/2,6-xylenol and p-cresol/ m-cresol has been attempted using commercially available ion-exchange resins. The basic resins selectively adsorb the cresol isomers from their mixtures with 2,6-xylenol. The...
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| Published in | Reactive & functional polymers Vol. 39; no. 3; pp. 227 - 237 |
|---|---|
| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
Amsterdam
Elsevier B.V
15.03.1999
Elsevier Science |
| Subjects | |
| Online Access | Get full text |
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| Abstract | Separation of close boiling point mixtures of alkylphenols, such as
p-cresol/2,6-xylenol,
m-cresol/2,6-xylenol and
p-cresol/
m-cresol has been attempted using commercially available ion-exchange resins. The basic resins selectively adsorb the cresol isomers from their mixtures with 2,6-xylenol. The separation seems to be decided by the thermodynamic selectivity in the ion-exchange resin framework with diffusional selectivity also contributing to the separation. |
|---|---|
| AbstractList | Separation of close boiling point mixtures of alkylphenols, such as
p-cresol/2,6-xylenol,
m-cresol/2,6-xylenol and
p-cresol/
m-cresol has been attempted using commercially available ion-exchange resins. The basic resins selectively adsorb the cresol isomers from their mixtures with 2,6-xylenol. The separation seems to be decided by the thermodynamic selectivity in the ion-exchange resin framework with diffusional selectivity also contributing to the separation. |
| Author | Anasthas, H.M Gaikar, V.G |
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| Cites_doi | 10.1021/ie50541a029 10.1515/9783110862430 10.1016/1381-5148(96)00054-5 10.1021/es60002a006 10.1021/ie50554a039 10.1080/03602548908050922 10.1039/f19726801045 10.1016/S0167-2991(09)60921-6 10.1039/TF9646001803 10.1016/0956-9618(94)80029-4 10.1080/07366298608917896 10.1039/jr9520001518 10.1021/ie50474a027 10.1080/01496398808060714 10.1016/0956-9618(95)00110-R |
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| Keywords | Diffusional selectivity Separation Thermodynamic selectivity Cresols 2,6-Xylenol Ion-exchange resins Solid state Separation capacity Liquid solid adsorption Cresol derivatives Anionic resin Selective adsorption Adsorption isotherm Phenols Experimental study |
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| Snippet | Separation of close boiling point mixtures of alkylphenols, such as
p-cresol/2,6-xylenol,
m-cresol/2,6-xylenol and
p-cresol/
m-cresol has been attempted using... |
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| SubjectTerms | 2,6-Xylenol Applied sciences Cresols Diffusional selectivity Exact sciences and technology Exchange resins and membranes Forms of application and semi-finished materials Ion-exchange resins Polymer industry, paints, wood Separation Technology of polymers Thermodynamic selectivity |
| Title | Adsorptive separations of alkylphenols using ion-exchange resins |
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