Ink-jet printing of organic semiconductor for fabricating organic thin-film transistors: Film uniformity control by ink composition

We have investigated the influence of solvent chemistry on ink-jet printed semiconductor patterns. Our research focuses on improving the uniformity of an ink-jet printed single dot semiconductor by adjusting the solvent mixture combination. Use of a solvent mixture with one solvent of a lower boilin...

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Published inSynthetic metals Vol. 159; no. 13; pp. 1381 - 1385
Main Authors Kim, Dongjo, Jeong, Sunho, Lee, Seong Hui, Moon, Jooho, Song, Jun Kwang
Format Journal Article
LanguageEnglish
Published Amsterdam Elsevier B.V 01.07.2009
Elsevier
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Abstract We have investigated the influence of solvent chemistry on ink-jet printed semiconductor patterns. Our research focuses on improving the uniformity of an ink-jet printed single dot semiconductor by adjusting the solvent mixture combination. Use of a solvent mixture with one solvent of a lower boiling point and a higher solubility with respect to the semiconductor molecules and another of a higher boiling point and a lower solubility allows us to produce a uniform single dot pattern by ink-jet printing. It was observed that the film uniformity of the semiconductor layer plays an important role in determining the electrical parameters of the transistor. In comparison with uncontrolled ink composition, the OTFT fabricated from the well-controlled ink exhibited better device performance, including a carrier mobility of 8.5 × 10 −3 cm 2 V −1 s −1 in the saturation regime, an on/off current ratio of 10 3, and a threshold voltage of 0.39 V with subthreshold slopes of 0.95 V dec −1.
AbstractList We have investigated the influence of solvent chemistry on ink-jet printed semiconductor patterns. Our research focuses on improving the uniformity of an ink-jet printed single dot semiconductor by adjusting the solvent mixture combination. Use of a solvent mixture with one solvent of a lower boiling point and a higher solubility with respect to the semiconductor molecules and another of a higher boiling point and a lower solubility allows us to produce a uniform single dot pattern by ink-jet printing. It was observed that the film uniformity of the semiconductor layer plays an important role in determining the electrical parameters of the transistor. In comparison with uncontrolled ink composition, the OTFT fabricated from the well-controlled ink exhibited better device performance, including a carrier mobility of 8.5 × 10 −3 cm 2 V −1 s −1 in the saturation regime, an on/off current ratio of 10 3, and a threshold voltage of 0.39 V with subthreshold slopes of 0.95 V dec −1.
We have investigated the influence of solvent chemistry on ink-jet printed semiconductor patterns. Our research focuses on improving the uniformity of an ink-jet printed single dot semiconductor by adjusting the solvent mixture combination. Use of a solvent mixture with one solvent of a lower boiling point and a higher solubility with respect to the semiconductor molecules and another of a higher boiling point and a lower solubility allows us to produce a uniform single dot pattern by ink-jet printing. It was observed that the film uniformity of the semiconductor layer plays an important role in determining the electrical parameters of the transistor. In comparison with uncontrolled ink composition, the OTFT fabricated from the well-controlled ink exhibited better device performance, including a carrier mobility of 8.5x10(-(3cm(2)V(-(1s(-(1 in the saturation regime, an on/off current ratio of 10(3), and a threshold voltage of 0.39V with subthreshold slopes of 0.95Vdec(-(1.
Author Jeong, Sunho
Kim, Dongjo
Song, Jun Kwang
Lee, Seong Hui
Moon, Jooho
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Issue 13
Keywords 68.55.am
Ink-jet printing
Organic thin-film transistor
Ink
61.25.he
72.80.Le
Organic semiconductor
Solvent effect
Voltage current curve
Surface topography
Oligomer
Experimental study
Property processing relationship
Structure processing relationship
Conjugated polymer
Mixed solvent
Tetramer
Silicon
Thiophene polymer
Thin film transistor
Ink jet printing
Growth from solution
Language English
License CC BY 4.0
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Snippet We have investigated the influence of solvent chemistry on ink-jet printed semiconductor patterns. Our research focuses on improving the uniformity of an...
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SubjectTerms Application fields
Applied sciences
Electronics
Exact sciences and technology
Ink
Ink-jet printing
Organic semiconductor
Organic thin-film transistor
Polymer industry, paints, wood
Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices
Technology of polymers
Transistors
Title Ink-jet printing of organic semiconductor for fabricating organic thin-film transistors: Film uniformity control by ink composition
URI https://dx.doi.org/10.1016/j.synthmet.2009.02.025
https://search.proquest.com/docview/34637820
Volume 159
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