A Janus Nickel Cobalt Phosphide Catalyst for High‐Efficiency Neutral‐pH Water Splitting
Transition‐metal phosphides have stimulated great interest as catalysts to drive the hydrogen evolution reaction (HER), but their use as bifunctional catalytic electrodes that enable efficient neutral‐pH water splitting has rarely been achieved. Herein, we report the synthesis of ternary Ni0.1Co0.9P...
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| Published in | Angewandte Chemie International Edition Vol. 57; no. 47; pp. 15445 - 15449 |
|---|---|
| Main Authors | , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Germany
Wiley Subscription Services, Inc
19.11.2018
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| Edition | International ed. in English |
| Subjects | |
| Online Access | Get full text |
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| Abstract | Transition‐metal phosphides have stimulated great interest as catalysts to drive the hydrogen evolution reaction (HER), but their use as bifunctional catalytic electrodes that enable efficient neutral‐pH water splitting has rarely been achieved. Herein, we report the synthesis of ternary Ni0.1Co0.9P porous nanosheets onto conductive carbon fiber paper that can efficiently and robustly catalyze both the HER and water oxidation in 1 m phosphate buffer (PBS; pH 7) electrolyte under ambient conditions. A water electrolysis cell comprising the Ni0.1Co0.9P electrodes demonstrates remarkable activity and stability for the electrochemical splitting of neutral‐pH water. We attribute this performance to the new ternary Ni0.1Co0.9P structure with porous surfaces and favorable electronic states resulting from the synergistic interplay between nickel and cobalt. Ternary metal phosphides hold promise as efficient and low‐cost catalysts for neutral‐pH water splitting devices.
Sheets and paper: Ternary Ni0.1Co0.9P porous nanosheets anchored onto conductive carbon fiber paper, can be used as a bifunctional catalytic material for driving both water reduction and oxidation reactions efficiently in neutral‐pH electrolyte under ambient conditions. |
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| AbstractList | Transition‐metal phosphides have stimulated great interest as catalysts to drive the hydrogen evolution reaction (HER), but their use as bifunctional catalytic electrodes that enable efficient neutral‐pH water splitting has rarely been achieved. Herein, we report the synthesis of ternary Ni0.1Co0.9P porous nanosheets onto conductive carbon fiber paper that can efficiently and robustly catalyze both the HER and water oxidation in 1 m phosphate buffer (PBS; pH 7) electrolyte under ambient conditions. A water electrolysis cell comprising the Ni0.1Co0.9P electrodes demonstrates remarkable activity and stability for the electrochemical splitting of neutral‐pH water. We attribute this performance to the new ternary Ni0.1Co0.9P structure with porous surfaces and favorable electronic states resulting from the synergistic interplay between nickel and cobalt. Ternary metal phosphides hold promise as efficient and low‐cost catalysts for neutral‐pH water splitting devices. Transition‐metal phosphides have stimulated great interest as catalysts to drive the hydrogen evolution reaction (HER), but their use as bifunctional catalytic electrodes that enable efficient neutral‐pH water splitting has rarely been achieved. Herein, we report the synthesis of ternary Ni 0.1 Co 0.9 P porous nanosheets onto conductive carbon fiber paper that can efficiently and robustly catalyze both the HER and water oxidation in 1 m phosphate buffer (PBS; pH 7) electrolyte under ambient conditions. A water electrolysis cell comprising the Ni 0.1 Co 0.9 P electrodes demonstrates remarkable activity and stability for the electrochemical splitting of neutral‐pH water. We attribute this performance to the new ternary Ni 0.1 Co 0.9 P structure with porous surfaces and favorable electronic states resulting from the synergistic interplay between nickel and cobalt. Ternary metal phosphides hold promise as efficient and low‐cost catalysts for neutral‐pH water splitting devices. Transition-metal phosphides have stimulated great interest as catalysts to drive the hydrogen evolution reaction (HER), but their use as bifunctional catalytic electrodes that enable efficient neutral-pH water splitting has rarely been achieved. Herein, we report the synthesis of ternary Ni Co P porous nanosheets onto conductive carbon fiber paper that can efficiently and robustly catalyze both the HER and water oxidation in 1 m phosphate buffer (PBS; pH 7) electrolyte under ambient conditions. A water electrolysis cell comprising the Ni Co P electrodes demonstrates remarkable activity and stability for the electrochemical splitting of neutral-pH water. We attribute this performance to the new ternary Ni Co P structure with porous surfaces and favorable electronic states resulting from the synergistic interplay between nickel and cobalt. Ternary metal phosphides hold promise as efficient and low-cost catalysts for neutral-pH water splitting devices. Transition-metal phosphides have stimulated great interest as catalysts to drive the hydrogen evolution reaction (HER), but their use as bifunctional catalytic electrodes that enable efficient neutral-pH water splitting has rarely been achieved. Herein, we report the synthesis of ternary Ni0.1 Co0.9 P porous nanosheets onto conductive carbon fiber paper that can efficiently and robustly catalyze both the HER and water oxidation in 1 m phosphate buffer (PBS; pH 7) electrolyte under ambient conditions. A water electrolysis cell comprising the Ni0.1 Co0.9 P electrodes demonstrates remarkable activity and stability for the electrochemical splitting of neutral-pH water. We attribute this performance to the new ternary Ni0.1 Co0.9 P structure with porous surfaces and favorable electronic states resulting from the synergistic interplay between nickel and cobalt. Ternary metal phosphides hold promise as efficient and low-cost catalysts for neutral-pH water splitting devices.Transition-metal phosphides have stimulated great interest as catalysts to drive the hydrogen evolution reaction (HER), but their use as bifunctional catalytic electrodes that enable efficient neutral-pH water splitting has rarely been achieved. Herein, we report the synthesis of ternary Ni0.1 Co0.9 P porous nanosheets onto conductive carbon fiber paper that can efficiently and robustly catalyze both the HER and water oxidation in 1 m phosphate buffer (PBS; pH 7) electrolyte under ambient conditions. A water electrolysis cell comprising the Ni0.1 Co0.9 P electrodes demonstrates remarkable activity and stability for the electrochemical splitting of neutral-pH water. We attribute this performance to the new ternary Ni0.1 Co0.9 P structure with porous surfaces and favorable electronic states resulting from the synergistic interplay between nickel and cobalt. Ternary metal phosphides hold promise as efficient and low-cost catalysts for neutral-pH water splitting devices. Transition‐metal phosphides have stimulated great interest as catalysts to drive the hydrogen evolution reaction (HER), but their use as bifunctional catalytic electrodes that enable efficient neutral‐pH water splitting has rarely been achieved. Herein, we report the synthesis of ternary Ni0.1Co0.9P porous nanosheets onto conductive carbon fiber paper that can efficiently and robustly catalyze both the HER and water oxidation in 1 m phosphate buffer (PBS; pH 7) electrolyte under ambient conditions. A water electrolysis cell comprising the Ni0.1Co0.9P electrodes demonstrates remarkable activity and stability for the electrochemical splitting of neutral‐pH water. We attribute this performance to the new ternary Ni0.1Co0.9P structure with porous surfaces and favorable electronic states resulting from the synergistic interplay between nickel and cobalt. Ternary metal phosphides hold promise as efficient and low‐cost catalysts for neutral‐pH water splitting devices. Sheets and paper: Ternary Ni0.1Co0.9P porous nanosheets anchored onto conductive carbon fiber paper, can be used as a bifunctional catalytic material for driving both water reduction and oxidation reactions efficiently in neutral‐pH electrolyte under ambient conditions. |
| Author | Zheng, Xu‐Sheng Zhu, Jun‐Fa Gao, Min‐Rui Wu, Rui Zheng, Ya‐Rong Yu, Shu‐Hong Gao, Qiang Xiao, Bing |
| Author_xml | – sequence: 1 givenname: Rui surname: Wu fullname: Wu, Rui organization: University of Science and Technology of China – sequence: 2 givenname: Bing surname: Xiao fullname: Xiao, Bing organization: Xi'an Jiaotong University – sequence: 3 givenname: Qiang surname: Gao fullname: Gao, Qiang organization: University of Science and Technology of China – sequence: 4 givenname: Ya‐Rong surname: Zheng fullname: Zheng, Ya‐Rong organization: University of Science and Technology of China – sequence: 5 givenname: Xu‐Sheng surname: Zheng fullname: Zheng, Xu‐Sheng organization: University of Science and Technology of China – sequence: 6 givenname: Jun‐Fa surname: Zhu fullname: Zhu, Jun‐Fa organization: University of Science and Technology of China – sequence: 7 givenname: Min‐Rui orcidid: 0000-0002-7805-803X surname: Gao fullname: Gao, Min‐Rui email: mgao@ustc.edu.cn organization: University of Science and Technology of China – sequence: 8 givenname: Shu‐Hong orcidid: 0000-0003-3732-1011 surname: Yu fullname: Yu, Shu‐Hong email: shyu@ustc.edu.cn organization: University of Science and Technology of China |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/30281194$$D View this record in MEDLINE/PubMed |
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| Copyright | 2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. |
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| Keywords | phosphides overall water splitting hydrogen and oxygen evolution transition metals nanosheets |
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| Snippet | Transition‐metal phosphides have stimulated great interest as catalysts to drive the hydrogen evolution reaction (HER), but their use as bifunctional catalytic... Transition-metal phosphides have stimulated great interest as catalysts to drive the hydrogen evolution reaction (HER), but their use as bifunctional catalytic... |
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| SubjectTerms | Carbon fibers Catalysis Catalysts Cobalt Electrochemistry Electrodes Electrolysis Electron states hydrogen and oxygen evolution Hydrogen evolution reactions nanosheets Nickel overall water splitting Oxidation pH effects Phosphides Splitting transition metals Water splitting |
| Title | A Janus Nickel Cobalt Phosphide Catalyst for High‐Efficiency Neutral‐pH Water Splitting |
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