Mechanochromic, Shape‐Programmable and Self‐Healable Cholesteric Liquid Crystal Elastomers Enabled by Dynamic Covalent Boronic Ester Bonds
Endowing a cholesteric liquid crystal elastomer (CLCE) exhibiting a helicoidal nanostructure with dynamically tailorable functionalities is of paramount significance for its emerging applications in diverse fields such as adaptive optics and soft robotics. Here, a mechanochromic, shape‐programmable...
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| Published in | Angewandte Chemie International Edition Vol. 61; no. 9; pp. e202116219 - n/a |
|---|---|
| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Germany
Wiley Subscription Services, Inc
21.02.2022
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| Edition | International ed. in English |
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| Abstract | Endowing a cholesteric liquid crystal elastomer (CLCE) exhibiting a helicoidal nanostructure with dynamically tailorable functionalities is of paramount significance for its emerging applications in diverse fields such as adaptive optics and soft robotics. Here, a mechanochromic, shape‐programmable and self‐healable CLCE is judiciously designed and synthesized through integrating dynamic covalent boronic ester bonds into the main‐chain CLCE polymer network. The circularly polarized reflection of CLCEs can be reversibly and dynamically tuned across the entire visible spectrum by mechanical stretching. Thanks to the introduction of dynamic boronic ester bonds, the CLCEs were found to show robust reprogrammable and self‐healing capabilities. The research disclosed herein can provide new insights into the development of 4D (color and 3D shape) programmable photonic actuators towards bioinspired camouflage, adaptive optical systems, and next‐generation intelligent machines.
Cholesteric liquid crystal elastomers (CLCEs) exhibiting mechanochromic, shape‐programmable and self‐healable properties were synthesized by introducing dynamic covalent boronic ester bonds into the main‐chain CLCE polymer networks. This research shines new light onto the development of dynamic covalent polymers for emerging applications in areas of bioinspired camouflage, adaptive optics and smart soft robotics. |
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| AbstractList | Endowing a cholesteric liquid crystal elastomer (CLCE) exhibiting a helicoidal nanostructure with dynamically tailorable functionalities is of paramount significance for its emerging applications in diverse fields such as adaptive optics and soft robotics. Here, a mechanochromic, shape‐programmable and self‐healable CLCE is judiciously designed and synthesized through integrating dynamic covalent boronic ester bonds into the main‐chain CLCE polymer network. The circularly polarized reflection of CLCEs can be reversibly and dynamically tuned across the entire visible spectrum by mechanical stretching. Thanks to the introduction of dynamic boronic ester bonds, the CLCEs were found to show robust reprogrammable and self‐healing capabilities. The research disclosed herein can provide new insights into the development of 4D (color and 3D shape) programmable photonic actuators towards bioinspired camouflage, adaptive optical systems, and next‐generation intelligent machines.
Cholesteric liquid crystal elastomers (CLCEs) exhibiting mechanochromic, shape‐programmable and self‐healable properties were synthesized by introducing dynamic covalent boronic ester bonds into the main‐chain CLCE polymer networks. This research shines new light onto the development of dynamic covalent polymers for emerging applications in areas of bioinspired camouflage, adaptive optics and smart soft robotics. Endowing a cholesteric liquid crystal elastomer (CLCE) exhibiting a helicoidal nanostructure with dynamically tailorable functionalities is of paramount significance for its emerging applications in diverse fields such as adaptive optics and soft robotics. Here, a mechanochromic, shape‐programmable and self‐healable CLCE is judiciously designed and synthesized through integrating dynamic covalent boronic ester bonds into the main‐chain CLCE polymer network. The circularly polarized reflection of CLCEs can be reversibly and dynamically tuned across the entire visible spectrum by mechanical stretching. Thanks to the introduction of dynamic boronic ester bonds, the CLCEs were found to show robust reprogrammable and self‐healing capabilities. The research disclosed herein can provide new insights into the development of 4D (color and 3D shape) programmable photonic actuators towards bioinspired camouflage, adaptive optical systems, and next‐generation intelligent machines. Endowing a cholesteric liquid crystal elastomer (CLCE) exhibiting a helicoidal nanostructure with dynamically tailorable functionalities is of paramount significance for its emerging applications in diverse fields such as adaptive optics and soft robotics. Here, a mechanochromic, shape-programmable and self-healable CLCE is judiciously designed and synthesized through integrating dynamic covalent boronic ester bonds into the main-chain CLCE polymer network. The circularly polarized reflection of CLCEs can be reversibly and dynamically tuned across the entire visible spectrum by mechanical stretching. Thanks to the introduction of dynamic boronic ester bonds, the CLCEs were found to show robust reprogrammable and self-healing capabilities. The research disclosed herein can provide new insights into the development of 4D (color and 3D shape) programmable photonic actuators towards bioinspired camouflage, adaptive optical systems, and next-generation intelligent machines.Endowing a cholesteric liquid crystal elastomer (CLCE) exhibiting a helicoidal nanostructure with dynamically tailorable functionalities is of paramount significance for its emerging applications in diverse fields such as adaptive optics and soft robotics. Here, a mechanochromic, shape-programmable and self-healable CLCE is judiciously designed and synthesized through integrating dynamic covalent boronic ester bonds into the main-chain CLCE polymer network. The circularly polarized reflection of CLCEs can be reversibly and dynamically tuned across the entire visible spectrum by mechanical stretching. Thanks to the introduction of dynamic boronic ester bonds, the CLCEs were found to show robust reprogrammable and self-healing capabilities. The research disclosed herein can provide new insights into the development of 4D (color and 3D shape) programmable photonic actuators towards bioinspired camouflage, adaptive optical systems, and next-generation intelligent machines. |
| Author | Ma, Jiazhe Valenzuela, Cristian Yang, Yanzhao Zhang, Xuan Feng, Wei Wang, Ling |
| Author_xml | – sequence: 1 givenname: Jiazhe surname: Ma fullname: Ma, Jiazhe organization: Tianjin University – sequence: 2 givenname: Yanzhao surname: Yang fullname: Yang, Yanzhao organization: Tianjin University – sequence: 3 givenname: Cristian surname: Valenzuela fullname: Valenzuela, Cristian organization: Tianjin University – sequence: 4 givenname: Xuan surname: Zhang fullname: Zhang, Xuan organization: Tianjin University – sequence: 5 givenname: Ling orcidid: 0000-0003-1035-5633 surname: Wang fullname: Wang, Ling email: lwang17@tju.edu.cn organization: Tianjin University – sequence: 6 givenname: Wei orcidid: 0000-0002-5816-7343 surname: Feng fullname: Feng, Wei email: weifeng@tju.edu.cn organization: Tianjin Key Laboratory of Composite and Functional Materials |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/34962037$$D View this record in MEDLINE/PubMed |
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| Snippet | Endowing a cholesteric liquid crystal elastomer (CLCE) exhibiting a helicoidal nanostructure with dynamically tailorable functionalities is of paramount... |
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| SubjectTerms | Actuators Adaptive optics Adaptive systems Bonding Camouflage Cholesteric Liquid Crystal Elastomer Cholesteric liquid crystals Circular polarization Dynamic Covalent Bond Elastomers Mechanochromism Optics Polymers Reprogrammable Robotics Self-Healing Visible spectrum |
| Title | Mechanochromic, Shape‐Programmable and Self‐Healable Cholesteric Liquid Crystal Elastomers Enabled by Dynamic Covalent Boronic Ester Bonds |
| URI | https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fanie.202116219 https://www.ncbi.nlm.nih.gov/pubmed/34962037 https://www.proquest.com/docview/2628922512 https://www.proquest.com/docview/2615108734 |
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