A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions
Two mixed‐metal gallium iodate fluorides, namely, α‐ and β‐Ba2[GaF4(IO3)2](IO3) (1 and 2), have been designed by the aliovalent substitutions of α‐ and β‐Ba2[VO2F2(IO3)2](IO3) (3 and 4) involving one cationic and two anionic sites. Both 1 and 2 display large second‐harmonic generation responses (≈6×...
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| Published in | Angewandte Chemie International Edition Vol. 58; no. 7; pp. 2098 - 2102 |
|---|---|
| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Germany
Wiley Subscription Services, Inc
11.02.2019
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| Edition | International ed. in English |
| Subjects | |
| Online Access | Get full text |
| ISSN | 1433-7851 1521-3773 1521-3773 |
| DOI | 10.1002/anie.201813968 |
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| Abstract | Two mixed‐metal gallium iodate fluorides, namely, α‐ and β‐Ba2[GaF4(IO3)2](IO3) (1 and 2), have been designed by the aliovalent substitutions of α‐ and β‐Ba2[VO2F2(IO3)2](IO3) (3 and 4) involving one cationic and two anionic sites. Both 1 and 2 display large second‐harmonic generation responses (≈6×KH2PO4 (KDP)), large energy band gaps (4.61 and 4.35 eV), wide transmittance ranges (≈0.27–12.5 μm), and high relevant laser‐induced damage thresholds (29.7× and 28.3×AgGaS2, respectively), which indicates that 1 and 2 are potential second‐order nonlinear optical materials in the ultraviolet to mid‐infrared. Our studies propose that three‐site aliovalent substitution is a facile route for the discovery of good NLO materials.
Trading places: Two new nonlinear optical materials, α‐ and β‐Ba2[GaF4(IO3)2](IO3) (1 and 2), were designed via three‐site aliovalent substitution of VO4F2 in α‐ and β‐Ba2[VO2F2(IO3)2](IO3) by GaO2F4. The new materials display large second‐harmonic generation responses (≈6×KH2PO4 (KDP)), wide energy band gaps (4.61 and 4.35 eV), and high laser damage thresholds (29.7× and 28.3× relative to that of AgGaS2). |
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| AbstractList | Two mixed‐metal gallium iodate fluorides, namely, α‐ and β‐Ba2[GaF4(IO3)2](IO3) (1 and 2), have been designed by the aliovalent substitutions of α‐ and β‐Ba2[VO2F2(IO3)2](IO3) (3 and 4) involving one cationic and two anionic sites. Both 1 and 2 display large second‐harmonic generation responses (≈6×KH2PO4 (KDP)), large energy band gaps (4.61 and 4.35 eV), wide transmittance ranges (≈0.27–12.5 μm), and high relevant laser‐induced damage thresholds (29.7× and 28.3×AgGaS2, respectively), which indicates that 1 and 2 are potential second‐order nonlinear optical materials in the ultraviolet to mid‐infrared. Our studies propose that three‐site aliovalent substitution is a facile route for the discovery of good NLO materials. Two mixed‐metal gallium iodate fluorides, namely, α‐ and β‐Ba2[GaF4(IO3)2](IO3) (1 and 2), have been designed by the aliovalent substitutions of α‐ and β‐Ba2[VO2F2(IO3)2](IO3) (3 and 4) involving one cationic and two anionic sites. Both 1 and 2 display large second‐harmonic generation responses (≈6×KH2PO4 (KDP)), large energy band gaps (4.61 and 4.35 eV), wide transmittance ranges (≈0.27–12.5 μm), and high relevant laser‐induced damage thresholds (29.7× and 28.3×AgGaS2, respectively), which indicates that 1 and 2 are potential second‐order nonlinear optical materials in the ultraviolet to mid‐infrared. Our studies propose that three‐site aliovalent substitution is a facile route for the discovery of good NLO materials. Trading places: Two new nonlinear optical materials, α‐ and β‐Ba2[GaF4(IO3)2](IO3) (1 and 2), were designed via three‐site aliovalent substitution of VO4F2 in α‐ and β‐Ba2[VO2F2(IO3)2](IO3) by GaO2F4. The new materials display large second‐harmonic generation responses (≈6×KH2PO4 (KDP)), wide energy band gaps (4.61 and 4.35 eV), and high laser damage thresholds (29.7× and 28.3× relative to that of AgGaS2). Two mixed‐metal gallium iodate fluorides, namely, α‐ and β‐Ba 2 [GaF 4 (IO 3 ) 2 ](IO 3 ) ( 1 and 2 ), have been designed by the aliovalent substitutions of α‐ and β‐Ba 2 [VO 2 F 2 (IO 3 ) 2 ](IO 3 ) ( 3 and 4 ) involving one cationic and two anionic sites. Both 1 and 2 display large second‐harmonic generation responses (≈6×KH 2 PO 4 (KDP)), large energy band gaps (4.61 and 4.35 eV), wide transmittance ranges (≈0.27–12.5 μm), and high relevant laser‐induced damage thresholds (29.7× and 28.3×AgGaS 2 , respectively), which indicates that 1 and 2 are potential second‐order nonlinear optical materials in the ultraviolet to mid‐infrared. Our studies propose that three‐site aliovalent substitution is a facile route for the discovery of good NLO materials. Two mixed-metal gallium iodate fluorides, namely, α- and β-Ba [GaF (IO ) ](IO ) (1 and 2), have been designed by the aliovalent substitutions of α- and β-Ba [VO F (IO ) ](IO ) (3 and 4) involving one cationic and two anionic sites. Both 1 and 2 display large second-harmonic generation responses (≈6×KH PO (KDP)), large energy band gaps (4.61 and 4.35 eV), wide transmittance ranges (≈0.27-12.5 μm), and high relevant laser-induced damage thresholds (29.7× and 28.3×AgGaS , respectively), which indicates that 1 and 2 are potential second-order nonlinear optical materials in the ultraviolet to mid-infrared. Our studies propose that three-site aliovalent substitution is a facile route for the discovery of good NLO materials. Two mixed-metal gallium iodate fluorides, namely, α- and β-Ba2 [GaF4 (IO3 )2 ](IO3 ) (1 and 2), have been designed by the aliovalent substitutions of α- and β-Ba2 [VO2 F2 (IO3 )2 ](IO3 ) (3 and 4) involving one cationic and two anionic sites. Both 1 and 2 display large second-harmonic generation responses (≈6×KH2 PO4 (KDP)), large energy band gaps (4.61 and 4.35 eV), wide transmittance ranges (≈0.27-12.5 μm), and high relevant laser-induced damage thresholds (29.7× and 28.3×AgGaS2 , respectively), which indicates that 1 and 2 are potential second-order nonlinear optical materials in the ultraviolet to mid-infrared. Our studies propose that three-site aliovalent substitution is a facile route for the discovery of good NLO materials.Two mixed-metal gallium iodate fluorides, namely, α- and β-Ba2 [GaF4 (IO3 )2 ](IO3 ) (1 and 2), have been designed by the aliovalent substitutions of α- and β-Ba2 [VO2 F2 (IO3 )2 ](IO3 ) (3 and 4) involving one cationic and two anionic sites. Both 1 and 2 display large second-harmonic generation responses (≈6×KH2 PO4 (KDP)), large energy band gaps (4.61 and 4.35 eV), wide transmittance ranges (≈0.27-12.5 μm), and high relevant laser-induced damage thresholds (29.7× and 28.3×AgGaS2 , respectively), which indicates that 1 and 2 are potential second-order nonlinear optical materials in the ultraviolet to mid-infrared. Our studies propose that three-site aliovalent substitution is a facile route for the discovery of good NLO materials. |
| Author | Mao, Jiang‐Gao Feng, Jiang‐He Chen, Jin Mao, Fei‐Fei Hu, Chun‐Li |
| Author_xml | – sequence: 1 givenname: Jin surname: Chen fullname: Chen, Jin organization: University of the Chinese Academy of Sciences – sequence: 2 givenname: Chun‐Li surname: Hu fullname: Hu, Chun‐Li organization: Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences – sequence: 3 givenname: Fei‐Fei surname: Mao fullname: Mao, Fei‐Fei organization: Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences – sequence: 4 givenname: Jiang‐He surname: Feng fullname: Feng, Jiang‐He organization: Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences – sequence: 5 givenname: Jiang‐Gao surname: Mao fullname: Mao, Jiang‐Gao email: mjg@fjirsm.ac.cn organization: Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/30589189$$D View this record in MEDLINE/PubMed |
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| Copyright | 2019 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. |
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| Keywords | aliovalent substitution theoretical studies hydrothermal synthesis nonlinear optical materials |
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| Snippet | Two mixed‐metal gallium iodate fluorides, namely, α‐ and β‐Ba2[GaF4(IO3)2](IO3) (1 and 2), have been designed by the aliovalent substitutions of α‐ and... Two mixed‐metal gallium iodate fluorides, namely, α‐ and β‐Ba 2 [GaF 4 (IO 3 ) 2 ](IO 3 ) ( 1 and 2 ), have been designed by the aliovalent substitutions of α‐... Two mixed-metal gallium iodate fluorides, namely, α- and β-Ba [GaF (IO ) ](IO ) (1 and 2), have been designed by the aliovalent substitutions of α- and β-Ba... Two mixed-metal gallium iodate fluorides, namely, α- and β-Ba2 [GaF4 (IO3 )2 ](IO3 ) (1 and 2), have been designed by the aliovalent substitutions of α- and... |
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| SubjectTerms | aliovalent substitution Anions Cations Energy gap Fluorides Gallium Harmonic generations hydrothermal synthesis Laser damage nonlinear optical materials Nonlinear optics Optical materials Optics Potassium phosphate Potassium phosphates Silver gallium sulfide Substitutes theoretical studies |
| Title | A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions |
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