Defect‐Free Metal–Organic Framework Membrane for Precise Ion/Solvent Separation toward Highly Stable Magnesium Metal Anode

• Published in: Advanced materials (Weinheim) Vol. 34; no. 6; pp. e2108114 - n/a
• Main Authors: Zhang, Yijie, Li, Jiang, Zhao, Wanyu, Dou, Huanglin, Zhao, Xiaoli, Liu, Yuan, Zhang, Bowen, Yang, Xiaowei
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 01.02.2022
• Subjects: Anodes; Electrolytes; electro‐deposition; Energy storage; Lithium-ion batteries; Magnesium; Materials science; Membrane separation; Membranes; Metal-organic frameworks; Mg‐ion batteries; Separation; solid‐electrolyte interphase; Solvents; Storage systems; electro-deposition; Mg-ion batteries; solid-electrolyte interphase; membrane separation; metal-organic frameworks

Metallic magnesium batteries are promising candidates beyond lithium‐ion batteries; however, a passive interfacial layer because of the electro‐reduction of solvents on Mg surfaces usually leads to ultrahigh overpotential for the reversible Mg chemistry. Inspired by the excellent separation effect o...