Silicon‐Stereogenic Monohydrosilane: Synthesis and Applications

• Published in: Angewandte Chemie International Edition Vol. 61; no. 36; pp. e202205382 - n/a
• Main Authors: Wu, Yichen, Wang, Peng
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 05.09.2022
• Edition: International ed. in English
• Subjects: Asymmetric Catalysis; Asymmetric synthesis; Chemical synthesis; Chirality; Hydrogen bonds; Monohydrosilanes; Optical activity; Optoelectronics; Organic chemistry; Reagents; Silicon; Silylation; Transition Metals; asymmetric catalysis, chirality, monohydrosilane, silylation, transition metal

Optically active organosilanes have been demonstrated to be versatile chiral reagents in synthetic chemistry since the early seminal contributions by Sommer and Corriu. Among these silicon‐containing chiral architectures, monohydrosilanes, which bear a Si−H bond, hold a unique position because of th...