Dynamic Migration of Surface Fluorine Anions on Cobalt‐Based Materials to Achieve Enhanced Oxygen Evolution Catalysis
Fluorine‐anion surface engineering has now been used to activate catalytic active species, representing a completely new way of reconstruction toward oxygen evolution reaction (OER) active species. The electronegativity of the fluorine anion is the strongest so that it will be much easier to form we...
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| Published in | Angewandte Chemie International Edition Vol. 57; no. 47; pp. 15471 - 15475 |
|---|---|
| Main Authors | , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Germany
Wiley Subscription Services, Inc
19.11.2018
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| Edition | International ed. in English |
| Subjects | |
| Online Access | Get full text |
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| Abstract | Fluorine‐anion surface engineering has now been used to activate catalytic active species, representing a completely new way of reconstruction toward oxygen evolution reaction (OER) active species. The electronegativity of the fluorine anion is the strongest so that it will be much easier to form weak metal–fluorine bonds with stronger ionicity, contributing to the dynamic migration of fluorine anions and finally enriching on the surface of both cobalt‐based oxide/oxyhydroxide. Surface enrichment of fluorine anions endows more hydrophilic surface character for accelerating the key process of oxygen‐related intermediate adsorption. Combining with an obviously improved electron transfer capacity, the F‐CoOOH/NF catalyst exhibits a greatly enhanced OER activity (270 mV at 10 mA cm−2) and reaction kinetics (54 mV dec−1) in alkaline medium. Surface anion engineering introduces a new concept for rational design advanced OER catalysts for energy conversion system.
Surface engineering by using fluoride ions was used to activate the catalytically active species of Co‐based materials. This is a completely new way of reconstruction toward OER‐active species. OER=oxygen evolution reaction; F green, Co purple. |
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| AbstractList | Fluorine‐anion surface engineering has now been used to activate catalytic active species, representing a completely new way of reconstruction toward oxygen evolution reaction (OER) active species. The electronegativity of the fluorine anion is the strongest so that it will be much easier to form weak metal–fluorine bonds with stronger ionicity, contributing to the dynamic migration of fluorine anions and finally enriching on the surface of both cobalt‐based oxide/oxyhydroxide. Surface enrichment of fluorine anions endows more hydrophilic surface character for accelerating the key process of oxygen‐related intermediate adsorption. Combining with an obviously improved electron transfer capacity, the F‐CoOOH/NF catalyst exhibits a greatly enhanced OER activity (270 mV at 10 mA cm
−2
) and reaction kinetics (54 mV dec
−1
) in alkaline medium. Surface anion engineering introduces a new concept for rational design advanced OER catalysts for energy conversion system. Fluorine‐anion surface engineering has now been used to activate catalytic active species, representing a completely new way of reconstruction toward oxygen evolution reaction (OER) active species. The electronegativity of the fluorine anion is the strongest so that it will be much easier to form weak metal–fluorine bonds with stronger ionicity, contributing to the dynamic migration of fluorine anions and finally enriching on the surface of both cobalt‐based oxide/oxyhydroxide. Surface enrichment of fluorine anions endows more hydrophilic surface character for accelerating the key process of oxygen‐related intermediate adsorption. Combining with an obviously improved electron transfer capacity, the F‐CoOOH/NF catalyst exhibits a greatly enhanced OER activity (270 mV at 10 mA cm−2) and reaction kinetics (54 mV dec−1) in alkaline medium. Surface anion engineering introduces a new concept for rational design advanced OER catalysts for energy conversion system. Surface engineering by using fluoride ions was used to activate the catalytically active species of Co‐based materials. This is a completely new way of reconstruction toward OER‐active species. OER=oxygen evolution reaction; F green, Co purple. Fluorine-anion surface engineering has now been used to activate catalytic active species, representing a completely new way of reconstruction toward oxygen evolution reaction (OER) active species. The electronegativity of the fluorine anion is the strongest so that it will be much easier to form weak metal-fluorine bonds with stronger ionicity, contributing to the dynamic migration of fluorine anions and finally enriching on the surface of both cobalt-based oxide/oxyhydroxide. Surface enrichment of fluorine anions endows more hydrophilic surface character for accelerating the key process of oxygen-related intermediate adsorption. Combining with an obviously improved electron transfer capacity, the F-CoOOH/NF catalyst exhibits a greatly enhanced OER activity (270 mV at 10 mA cm ) and reaction kinetics (54 mV dec ) in alkaline medium. Surface anion engineering introduces a new concept for rational design advanced OER catalysts for energy conversion system. Fluorine‐anion surface engineering has now been used to activate catalytic active species, representing a completely new way of reconstruction toward oxygen evolution reaction (OER) active species. The electronegativity of the fluorine anion is the strongest so that it will be much easier to form weak metal–fluorine bonds with stronger ionicity, contributing to the dynamic migration of fluorine anions and finally enriching on the surface of both cobalt‐based oxide/oxyhydroxide. Surface enrichment of fluorine anions endows more hydrophilic surface character for accelerating the key process of oxygen‐related intermediate adsorption. Combining with an obviously improved electron transfer capacity, the F‐CoOOH/NF catalyst exhibits a greatly enhanced OER activity (270 mV at 10 mA cm−2) and reaction kinetics (54 mV dec−1) in alkaline medium. Surface anion engineering introduces a new concept for rational design advanced OER catalysts for energy conversion system. Fluorine-anion surface engineering has now been used to activate catalytic active species, representing a completely new way of reconstruction toward oxygen evolution reaction (OER) active species. The electronegativity of the fluorine anion is the strongest so that it will be much easier to form weak metal-fluorine bonds with stronger ionicity, contributing to the dynamic migration of fluorine anions and finally enriching on the surface of both cobalt-based oxide/oxyhydroxide. Surface enrichment of fluorine anions endows more hydrophilic surface character for accelerating the key process of oxygen-related intermediate adsorption. Combining with an obviously improved electron transfer capacity, the F-CoOOH/NF catalyst exhibits a greatly enhanced OER activity (270 mV at 10 mA cm-2 ) and reaction kinetics (54 mV dec-1 ) in alkaline medium. Surface anion engineering introduces a new concept for rational design advanced OER catalysts for energy conversion system.Fluorine-anion surface engineering has now been used to activate catalytic active species, representing a completely new way of reconstruction toward oxygen evolution reaction (OER) active species. The electronegativity of the fluorine anion is the strongest so that it will be much easier to form weak metal-fluorine bonds with stronger ionicity, contributing to the dynamic migration of fluorine anions and finally enriching on the surface of both cobalt-based oxide/oxyhydroxide. Surface enrichment of fluorine anions endows more hydrophilic surface character for accelerating the key process of oxygen-related intermediate adsorption. Combining with an obviously improved electron transfer capacity, the F-CoOOH/NF catalyst exhibits a greatly enhanced OER activity (270 mV at 10 mA cm-2 ) and reaction kinetics (54 mV dec-1 ) in alkaline medium. Surface anion engineering introduces a new concept for rational design advanced OER catalysts for energy conversion system. |
| Author | Ju, Huanxin Chen, Pengzuo Zhang, Nan Tong, Yun Zhou, Tianpei Wang, Sibo Wu, Changzheng Xie, Yi Chu, Wangsheng |
| Author_xml | – sequence: 1 givenname: Pengzuo surname: Chen fullname: Chen, Pengzuo organization: University of Science and Technology of China – sequence: 2 givenname: Tianpei surname: Zhou fullname: Zhou, Tianpei organization: University of Science and Technology of China – sequence: 3 givenname: Sibo surname: Wang fullname: Wang, Sibo organization: University of Science and Technology of China – sequence: 4 givenname: Nan surname: Zhang fullname: Zhang, Nan organization: University of Science and Technology of China – sequence: 5 givenname: Yun surname: Tong fullname: Tong, Yun organization: University of Science and Technology of China – sequence: 6 givenname: Huanxin surname: Ju fullname: Ju, Huanxin organization: University of Science and Technology of China – sequence: 7 givenname: Wangsheng surname: Chu fullname: Chu, Wangsheng organization: University of Science and Technology of China – sequence: 8 givenname: Changzheng orcidid: 0000-0002-4416-6358 surname: Wu fullname: Wu, Changzheng email: czwu@ustc.edu.cn organization: University of Science and Technology of China – sequence: 9 givenname: Yi surname: Xie fullname: Xie, Yi organization: University of Science and Technology of China |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/30216619$$D View this record in MEDLINE/PubMed |
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| Cites_doi | 10.1002/ange.201610119 10.1002/ange.201306166 10.1021/ja504099w 10.1002/adma.201602868 10.1002/adma.201704681 10.1002/adma.201701584 10.1002/ange.201506480 10.1002/adma.201502696 10.1038/nmat3313 10.1002/anie.201612635 10.1002/anie.201702430 10.1002/ange.201702430 10.1039/C5QI00197H 10.1002/cjoc.201600229 10.1002/anie.201304481 10.1002/anie.201511032 10.1021/acs.accounts.8b00002 10.1002/adma.201601663 10.1002/anie.201610119 10.1002/anie.201411072 10.1039/C6CS00328A 10.1021/jacs.7b03507 10.1021/acs.accounts.6b00635 10.1002/aenm.201700242 10.1002/anie.201506480 10.1021/acscatal.7b02218 10.1002/ange.201612635 10.1021/jacs.5b08186 10.1039/C7TA03305B 10.1002/aenm.201602086 10.1002/ange.201511032 10.1002/ange.201411072 10.1016/j.nanoen.2016.04.006 10.1021/ja5119495 10.1002/smll.201502106 |
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| Copyright | 2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. |
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| Issue | 47 |
| Keywords | cobalt oxides oxygen evolution reaction fluoride surface reconstruction dynamic migration |
| Language | English |
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| References_xml | – volume: 46 start-page: 337 year: 2017 end-page: 365 publication-title: Chem. Soc. Rev. – volume: 29 start-page: 1704681 year: 2017 publication-title: Adv. Mater. – volume: 7 start-page: 7405 year: 2017 end-page: 7411 publication-title: ACS Catal. – volume: 56 129 start-page: 7121 7227 year: 2017 2017 end-page: 7125 7231 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 28 start-page: 7527 year: 2016 end-page: 7532 publication-title: Adv. Mater. – volume: 29 start-page: 1602868 year: 2017 publication-title: Adv. Mater. – volume: 50 start-page: 915 year: 2017 end-page: 923 publication-title: Acc. Chem. Res. – volume: 28 start-page: 215 year: 2016 end-page: 230 publication-title: Adv. Mater. – volume: 56 129 start-page: 610 625 year: 2017 2017 end-page: 614 629 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 7 start-page: 1602086 year: 2017 publication-title: Adv. Energy Mater. – volume: 24 start-page: 103 year: 2016 end-page: 110 publication-title: Nano Energy – volume: 136 start-page: 10053 year: 2014 end-page: 10061 publication-title: J. Am. Chem. Soc. – volume: 7 start-page: 1700242 year: 2017 publication-title: Adv. Energy Mater. – volume: 54 127 start-page: 14710 14923 year: 2015 2015 end-page: 14714 14927 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 3 start-page: 236 year: 2016 end-page: 242 publication-title: Inorg. Chem. Front. – volume: 51 start-page: 1571 year: 2018 publication-title: Acc. Chem. Res. – volume: 29 start-page: 1701584 year: 2017 publication-title: Adv. Mater. – volume: 139 start-page: 8320 year: 2017 end-page: 8328 publication-title: J. Am. Chem. Soc. – volume: 52 125 start-page: 13567 13812 year: 2013 2013 end-page: 13570 13815 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 11 start-page: 6278 year: 2015 publication-title: Small – volume: 56 129 start-page: 3897 3955 year: 2017 2017 end-page: 3900 3958 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 55 128 start-page: 2488 2534 year: 2016 2016 end-page: 2492 2538 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 5 start-page: 12043 year: 2017 end-page: 12047 publication-title: J. Mater. Chem. A – volume: 137 start-page: 4119 year: 2015 end-page: 4125 publication-title: J. Am. Chem. Soc. – volume: 137 start-page: 14023 year: 2015 end-page: 14026 publication-title: J. Am. Chem. Soc. – volume: 35 start-page: 48 year: 2017 end-page: 54 publication-title: Chin. J. Chem. – volume: 54 127 start-page: 2975 3018 year: 2015 2015 end-page: 2979 3022 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 11 start-page: 550 year: 2012 publication-title: Nat. Mater. – ident: e_1_2_2_8_3 doi: 10.1002/ange.201610119 – ident: e_1_2_2_1_1 – ident: e_1_2_2_35_3 doi: 10.1002/ange.201306166 – ident: e_1_2_2_33_2 doi: 10.1021/ja504099w – ident: e_1_2_2_28_1 doi: 10.1002/adma.201602868 – ident: e_1_2_2_15_2 doi: 10.1002/adma.201704681 – ident: e_1_2_2_17_2 doi: 10.1002/adma.201701584 – ident: e_1_2_2_20_3 doi: 10.1002/ange.201506480 – ident: e_1_2_2_23_1 doi: 10.1002/adma.201502696 – ident: e_1_2_2_2_2 doi: 10.1038/nmat3313 – ident: e_1_2_2_22_1 doi: 10.1002/anie.201612635 – ident: e_1_2_2_11_2 doi: 10.1002/anie.201702430 – ident: e_1_2_2_11_3 doi: 10.1002/ange.201702430 – ident: e_1_2_2_21_2 doi: 10.1039/C5QI00197H – ident: e_1_2_2_30_1 doi: 10.1002/cjoc.201600229 – ident: e_1_2_2_31_1 – ident: e_1_2_2_35_2 doi: 10.1002/anie.201304481 – ident: e_1_2_2_12_2 doi: 10.1002/anie.201511032 – ident: e_1_2_2_3_2 doi: 10.1021/acs.accounts.8b00002 – ident: e_1_2_2_4_2 doi: 10.1002/adma.201601663 – ident: e_1_2_2_8_2 doi: 10.1002/anie.201610119 – ident: e_1_2_2_9_1 doi: 10.1002/anie.201411072 – ident: e_1_2_2_7_2 doi: 10.1039/C6CS00328A – ident: e_1_2_2_34_1 – ident: e_1_2_2_13_1 doi: 10.1021/jacs.7b03507 – ident: e_1_2_2_18_1 – ident: e_1_2_2_6_2 doi: 10.1021/acs.accounts.6b00635 – ident: e_1_2_2_29_1 doi: 10.1002/aenm.201700242 – ident: e_1_2_2_20_2 doi: 10.1002/anie.201506480 – ident: e_1_2_2_27_2 doi: 10.1021/acscatal.7b02218 – ident: e_1_2_2_14_1 – ident: e_1_2_2_22_2 doi: 10.1002/ange.201612635 – ident: e_1_2_2_16_2 doi: 10.1021/jacs.5b08186 – ident: e_1_2_2_26_2 doi: 10.1039/C7TA03305B – ident: e_1_2_2_25_2 doi: 10.1002/aenm.201602086 – ident: e_1_2_2_5_1 – ident: e_1_2_2_12_3 doi: 10.1002/ange.201511032 – ident: e_1_2_2_24_1 – ident: e_1_2_2_9_2 doi: 10.1002/ange.201411072 – ident: e_1_2_2_36_2 doi: 10.1016/j.nanoen.2016.04.006 – ident: e_1_2_2_10_1 – ident: e_1_2_2_19_2 doi: 10.1021/ja5119495 – ident: e_1_2_2_32_2 doi: 10.1002/smll.201502106 |
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| Snippet | Fluorine‐anion surface engineering has now been used to activate catalytic active species, representing a completely new way of reconstruction toward oxygen... Fluorine-anion surface engineering has now been used to activate catalytic active species, representing a completely new way of reconstruction toward oxygen... |
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| SubjectTerms | Anions Bonding strength Catalysis Catalysts Cobalt cobalt oxides Design engineering dynamic migration Electron transfer Electronegativity Energy conversion fluoride Fluorine Migration Oxygen oxygen evolution reaction Oxygen evolution reactions Reaction kinetics surface reconstruction |
| Title | Dynamic Migration of Surface Fluorine Anions on Cobalt‐Based Materials to Achieve Enhanced Oxygen Evolution Catalysis |
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