Loss of superhydrophobicity of hydrophobic micro/nano structures during condensation

Condensed liquid behavior on hydrophobic micro/nano-structured surfaces is a subject with multiple practical applications, but remains poorly understood. In particular, the loss of superhydrophobicity of hydrophobic micro/nanostructures during condensation, even when the same surface shows water-rep...

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Published inScientific reports Vol. 5; no. 1; p. 9901
Main Authors Jo, HangJin, Hwang, Kyung Won, Kim, DongHyun, Kiyofumi, Moriyama, Park, Hyun Sun, Kim, Moo Hwan, Ahn, Ho Seon
Format Journal Article
LanguageEnglish
Published London Nature Publishing Group UK 23.04.2015
Nature Publishing Group
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Abstract Condensed liquid behavior on hydrophobic micro/nano-structured surfaces is a subject with multiple practical applications, but remains poorly understood. In particular, the loss of superhydrophobicity of hydrophobic micro/nanostructures during condensation, even when the same surface shows water-repellant characteristics when exposed to air, requires intensive investigation to improve and apply our understanding of the fundamental physics of condensation. Here, we postulate the criterion required for condensation to form from inside the surface structures by examining the grand potentials of a condensation system, including the properties of the condensed liquid and the conditions required for condensation. The results imply that the same hydrophobic micro/nano-structured surface could exhibit different liquid droplet behavior depending on the conditions. Our findings are supported by the observed phenomena: the initiation of a condensed droplet from inside a hydrophobic cavity, the apparent wetted state changes and the presence of sticky condensed droplets on the hydrophobic micro/nano-structured surface.
AbstractList Condensed liquid behavior on hydrophobic micro/nano-structured surfaces is a subject with multiple practical applications, but remains poorly understood. In particular, the loss of superhydrophobicity of hydrophobic micro/nanostructures during condensation, even when the same surface shows water-repellant characteristics when exposed to air, requires intensive investigation to improve and apply our understanding of the fundamental physics of condensation. Here, we postulate the criterion required for condensation to form from inside the surface structures by examining the grand potentials of a condensation system, including the properties of the condensed liquid and the conditions required for condensation. The results imply that the same hydrophobic micro/nano-structured surface could exhibit different liquid droplet behavior depending on the conditions. Our findings are supported by the observed phenomena: the initiation of a condensed droplet from inside a hydrophobic cavity, the apparent wetted state changes, and the presence of sticky condensed droplets on the hydrophobic micro/nano-structured surface.
ArticleNumber 9901
Author Ahn, Ho Seon
Hwang, Kyung Won
Kim, DongHyun
Jo, HangJin
Kim, Moo Hwan
Kiyofumi, Moriyama
Park, Hyun Sun
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  fullname: Hwang, Kyung Won
  organization: Department of Mechanical Engineering, POSTECH
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  givenname: DongHyun
  surname: Kim
  fullname: Kim, DongHyun
  organization: Division of Advanced Nuclear Engineering, POSTECH
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  givenname: Moriyama
  surname: Kiyofumi
  fullname: Kiyofumi, Moriyama
  organization: Division of Advanced Nuclear Engineering, POSTECH
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  givenname: Hyun Sun
  surname: Park
  fullname: Park, Hyun Sun
  organization: Division of Advanced Nuclear Engineering, POSTECH
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  surname: Ahn
  fullname: Ahn, Ho Seon
  organization: Division of Mechanical System Engineering, Incheon National University
BackLink https://www.ncbi.nlm.nih.gov/pubmed/25905817$$D View this record in MEDLINE/PubMed
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Snippet Condensed liquid behavior on hydrophobic micro/nano-structured surfaces is a subject with multiple practical applications, but remains poorly understood. In...
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SubjectTerms 147/135
639/166/988
639/925/357/537
Condensation
Humanities and Social Sciences
Hydrophobic surfaces
Hydrophobicity
multidisciplinary
Science
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Title Loss of superhydrophobicity of hydrophobic micro/nano structures during condensation
URI https://link.springer.com/article/10.1038/srep09901
https://www.ncbi.nlm.nih.gov/pubmed/25905817
https://www.proquest.com/docview/1899539321
https://pubmed.ncbi.nlm.nih.gov/PMC5386109
Volume 5
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