Nanostructures, Optical Properties, and Imaging Application of Lead-Sulfide Nanocomposite Coatings

Lead‐sulfide (PbS) nanocrystals were precipitated in nanocomposite coatings after a pre‐photo‐polymerization followed by a reaction with H2S gas at 25°C for 1 hr. PbS nanocrystalline size and optical absorption increased with decreasing UV energy for pre‐photo‐polymerization and increasing concentra...

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Published inInternational journal of applied ceramic technology Vol. 1; no. 2; pp. 119 - 128
Main Authors Lu, Song Wei, Schmidt, Helmut K.
Format Journal Article
LanguageEnglish
Published Oxford, UK Blackwell Publishing Ltd 01.04.2004
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Abstract Lead‐sulfide (PbS) nanocrystals were precipitated in nanocomposite coatings after a pre‐photo‐polymerization followed by a reaction with H2S gas at 25°C for 1 hr. PbS nanocrystalline size and optical absorption increased with decreasing UV energy for pre‐photo‐polymerization and increasing concentration. The absorption onset has a large blue shift from 0.41 eV of the corresponding bulk crystal, resulting from the quantum confinement effect. As a result, coating color changes significantly from deep brown to light yellow depending on coating processing conditions. Partially masking the coatings during pre‐photo‐polymerization gives rise to different colors, leading to imaging applications of PbS nanocomposite coatings.
AbstractList Lead‐sulfide (PbS) nanocrystals were precipitated in nanocomposite coatings after a pre‐photo‐polymerization followed by a reaction with H 2 S gas at 25°C for 1 hr. PbS nanocrystalline size and optical absorption increased with decreasing UV energy for pre‐photo‐polymerization and increasing concentration. The absorption onset has a large blue shift from 0.41 eV of the corresponding bulk crystal, resulting from the quantum confinement effect. As a result, coating color changes significantly from deep brown to light yellow depending on coating processing conditions. Partially masking the coatings during pre‐photo‐polymerization gives rise to different colors, leading to imaging applications of PbS nanocomposite coatings.
Lead-sulfide (PbS) nanocrystals were precipitated in nanocomposite coatings after a pre-photo-polymerization followed by a reaction with HS gas at 25 deg C for 1 hr. PbS nanocrystalline size and optical absorption increased with decreasing UV energy for prephotopolymerization and increasing concentration. The absorption onset has a large blue shift from 0.41 eV of the corresponding bulk crystal, resulting from the quantum confinement effect. As a result, coating color changes significantly from deep brown to light yellow depending on coating processing conditions. Partially masking the coatings during pre-photo-polymerization gives rise to different colors, leading to imaging applications of PbS nanocomposite coatings.
Lead‐sulfide (PbS) nanocrystals were precipitated in nanocomposite coatings after a pre‐photo‐polymerization followed by a reaction with H2S gas at 25°C for 1 hr. PbS nanocrystalline size and optical absorption increased with decreasing UV energy for pre‐photo‐polymerization and increasing concentration. The absorption onset has a large blue shift from 0.41 eV of the corresponding bulk crystal, resulting from the quantum confinement effect. As a result, coating color changes significantly from deep brown to light yellow depending on coating processing conditions. Partially masking the coatings during pre‐photo‐polymerization gives rise to different colors, leading to imaging applications of PbS nanocomposite coatings.
Author Schmidt, Helmut K.
Lu, Song Wei
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Partially supported by the Ministry for Research and Culture of the State of Saarland, Germany
PPG Industries, Inc., Glass Technology Center, P.O. Box 11472, Pittsburgh, PA 15238‐0472, USA. E‐mail
songweilu@hotmail.com
Member, American Ceramic Society
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Snippet Lead‐sulfide (PbS) nanocrystals were precipitated in nanocomposite coatings after a pre‐photo‐polymerization followed by a reaction with H2S gas at 25°C for 1...
Lead‐sulfide (PbS) nanocrystals were precipitated in nanocomposite coatings after a pre‐photo‐polymerization followed by a reaction with H 2 S gas at 25°C for...
Lead-sulfide (PbS) nanocrystals were precipitated in nanocomposite coatings after a pre-photo-polymerization followed by a reaction with HS gas at 25 deg C for...
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Title Nanostructures, Optical Properties, and Imaging Application of Lead-Sulfide Nanocomposite Coatings
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