Nanostructures, Optical Properties, and Imaging Application of Lead-Sulfide Nanocomposite Coatings
Lead‐sulfide (PbS) nanocrystals were precipitated in nanocomposite coatings after a pre‐photo‐polymerization followed by a reaction with H2S gas at 25°C for 1 hr. PbS nanocrystalline size and optical absorption increased with decreasing UV energy for pre‐photo‐polymerization and increasing concentra...
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Published in | International journal of applied ceramic technology Vol. 1; no. 2; pp. 119 - 128 |
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Main Authors | , |
Format | Journal Article |
Language | English |
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Oxford, UK
Blackwell Publishing Ltd
01.04.2004
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Abstract | Lead‐sulfide (PbS) nanocrystals were precipitated in nanocomposite coatings after a pre‐photo‐polymerization followed by a reaction with H2S gas at 25°C for 1 hr. PbS nanocrystalline size and optical absorption increased with decreasing UV energy for pre‐photo‐polymerization and increasing concentration. The absorption onset has a large blue shift from 0.41 eV of the corresponding bulk crystal, resulting from the quantum confinement effect. As a result, coating color changes significantly from deep brown to light yellow depending on coating processing conditions. Partially masking the coatings during pre‐photo‐polymerization gives rise to different colors, leading to imaging applications of PbS nanocomposite coatings. |
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AbstractList | Lead‐sulfide (PbS) nanocrystals were precipitated in nanocomposite coatings after a pre‐photo‐polymerization followed by a reaction with H
2
S gas at 25°C for 1 hr. PbS nanocrystalline size and optical absorption increased with decreasing UV energy for pre‐photo‐polymerization and increasing concentration. The absorption onset has a large blue shift from 0.41 eV of the corresponding bulk crystal, resulting from the quantum confinement effect. As a result, coating color changes significantly from deep brown to light yellow depending on coating processing conditions. Partially masking the coatings during pre‐photo‐polymerization gives rise to different colors, leading to imaging applications of PbS nanocomposite coatings. Lead-sulfide (PbS) nanocrystals were precipitated in nanocomposite coatings after a pre-photo-polymerization followed by a reaction with HS gas at 25 deg C for 1 hr. PbS nanocrystalline size and optical absorption increased with decreasing UV energy for prephotopolymerization and increasing concentration. The absorption onset has a large blue shift from 0.41 eV of the corresponding bulk crystal, resulting from the quantum confinement effect. As a result, coating color changes significantly from deep brown to light yellow depending on coating processing conditions. Partially masking the coatings during pre-photo-polymerization gives rise to different colors, leading to imaging applications of PbS nanocomposite coatings. Lead‐sulfide (PbS) nanocrystals were precipitated in nanocomposite coatings after a pre‐photo‐polymerization followed by a reaction with H2S gas at 25°C for 1 hr. PbS nanocrystalline size and optical absorption increased with decreasing UV energy for pre‐photo‐polymerization and increasing concentration. The absorption onset has a large blue shift from 0.41 eV of the corresponding bulk crystal, resulting from the quantum confinement effect. As a result, coating color changes significantly from deep brown to light yellow depending on coating processing conditions. Partially masking the coatings during pre‐photo‐polymerization gives rise to different colors, leading to imaging applications of PbS nanocomposite coatings. |
Author | Schmidt, Helmut K. Lu, Song Wei |
Author_xml | – sequence: 1 givenname: Song Wei surname: Lu fullname: Lu, Song Wei organization: Institut für Neue Materialien, gem. GmbH, Gebäude 43, Im Stadtwald, D-66123, Saarbrücken, Germany – sequence: 2 givenname: Helmut K. surname: Schmidt fullname: Schmidt, Helmut K. organization: Institut für Neue Materialien, gem. GmbH, Gebäude 43, Im Stadtwald, D-66123, Saarbrücken, Germany |
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Notes | ArticleID:IJAC119 istex:68486DED3CD61B5E54F9088DC61817E5B86C2275 ark:/67375/WNG-K9RQHZN5-K Partially supported by the Ministry for Research and Culture of the State of Saarland, Germany PPG Industries, Inc., Glass Technology Center, P.O. Box 11472, Pittsburgh, PA 15238‐0472, USA. E‐mail songweilu@hotmail.com Member, American Ceramic Society . ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 23 |
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Snippet | Lead‐sulfide (PbS) nanocrystals were precipitated in nanocomposite coatings after a pre‐photo‐polymerization followed by a reaction with H2S gas at 25°C for 1... Lead‐sulfide (PbS) nanocrystals were precipitated in nanocomposite coatings after a pre‐photo‐polymerization followed by a reaction with H 2 S gas at 25°C for... Lead-sulfide (PbS) nanocrystals were precipitated in nanocomposite coatings after a pre-photo-polymerization followed by a reaction with HS gas at 25 deg C for... |
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