Electrical and dielectric properties of co-precipitated nanocrystalline tin oxide

• Published in: Journal of alloys and compounds Vol. 505; no. 2; pp. 743 - 749
• Main Authors: Babar, A.R., Shinde, S.S., Moholkar, A.V., Rajpure, K.Y.
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier B.V 03.09.2010; Elsevier
• Subjects: Chemical co-precipitation; Condensed matter: electronic structure, electrical, magnetic, and optical properties; Condensed matter: structure, mechanical and thermal properties; Cross-disciplinary physics: materials science; rheology; Crystal structure; Crystallite size; Dielectric properties; Dielectric properties of solids and liquids; Dielectrics, piezoelectrics, and ferroelectrics and their properties; Electrical and dielectric properties; Exact sciences and technology; FTIR; Materials science; Materials synthesis; materials processing; Nanocrystalline materials; Nanocrystals; Nanoscale materials and structures: fabrication and characterization; Permittivity (dielectric function); Physics; SEM; Sintering; Sintering (powder metallurgy); Structure of solids and liquids; crystallography; Structure of specific crystalline solids; Tin; Tin dioxide; Tin oxide; Tin oxides; XPS studies; XRD; Tin oxide; FTIR; Electrical and dielectric properties; XPS studies; Crystallite size; SEM; Chemical co-precipitation; XRD; Fourier transform spectroscopy; Electrical conductivity; Ground states; Chemical method; Tetragonal crystals; Nanostructures; Chernical co-precipitation; Precursor; Thin films; Nanoparticles; Crystallites; Temperature effects; Chlorides; Permittivity; Coprecipitation; Nanocrystal; Crystal structure; Grain size; Scanning electron microscopy; Electrical properties; Chemical precipitation; Tetragonal lattices; Dielectric properties; Crystallinity; Excited states; Electrical measurement; Sintering; Nanostructured materials; X-ray photoelectron spectra
• DOI: 10.1016/j.jallcom.2010.06.131
• ISSN: 0925-8388

Nanocrystalline tin oxide (SnO 2) powders were synthesized by chemical co-precipitation method using stannic chloride pentahydrate (SnCl 4·5H 2O) precursor in aqueous medium. The influence of sintering temperatures on the crystalline structure, morphological, electrical, dielectric and XPS properties has been studied. X-ray diffraction study reveals that sintered powder which exhibits tetragonal crystal structure and both crystallinity as well as crystal size increase with increase in temperature. The nature of species of various absorption bonds viz. Sn–O, O–Sn–O and O–H involved in sintered SnO 2 samples has been studied using FTIR technique. The morphological studies reveal randomly arranged grains with compact nature and grain size increases with sintering temperature. Measurements of electrical properties show relatively lower resistivity (≈10 2–10 3 Ω cm) and higher dielectric constant at 400 °C than other sintering temperatures. The compositional analysis and electronic behavior of SnO 2 nanoparticles is studied using X-ray photoelectron spectroscopy. The symmetric spin orbit splitting of Sn 3d 5/2 ground state and Sn 3d 3/2 excited states is observed with sintering temperature while O 1s is recognized with O 2 − state.